Authors:
Cheng-Li Jiao Materials and Thermochemistry Laboratory, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian 116023, People's Republic of China
Graduate School of the Chinese Academy of Sciences, Beijing 100049, People's Republic of China

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Li-Fang Song Materials and Thermochemistry Laboratory, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian 116023, People's Republic of China
Graduate School of the Chinese Academy of Sciences, Beijing 100049, People's Republic of China

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Chun-Hong Jiang Materials and Thermochemistry Laboratory, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian 116023, People's Republic of China
Graduate School of the Chinese Academy of Sciences, Beijing 100049, People's Republic of China

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Jian Zhang Materials and Thermochemistry Laboratory, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian 116023, People's Republic of China

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Xiao-Liang Si Materials and Thermochemistry Laboratory, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian 116023, People's Republic of China
Graduate School of the Chinese Academy of Sciences, Beijing 100049, People's Republic of China

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Shu-Jun Qiu Materials and Thermochemistry Laboratory, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian 116023, People's Republic of China
Graduate School of the Chinese Academy of Sciences, Beijing 100049, People's Republic of China

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Shuang Wang Materials and Thermochemistry Laboratory, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian 116023, People's Republic of China
Graduate School of the Chinese Academy of Sciences, Beijing 100049, People's Republic of China

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Li-Xian Sun Materials and Thermochemistry Laboratory, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian 116023, People's Republic of China

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Fen Xu Faculty of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian 116029, People's Republic of China

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Fen Li Materials and Thermochemistry Laboratory, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian 116023, People's Republic of China

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Ji-Jun Zhao Laboratory of Materials Modification by Laser, Electron, and Ion Beams, Dalian University of Technology, Dalian 116024, China

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Abstract

The low-temperature molar heat capacity of crystalline Mn3(HEDTA)2·10H2O was measured by temperature-modulated differential scanning calorimetry (TMDSC) for the first time. The thermodynamic parameters such as entropy and enthalpy relative to 298.15 K were calculated based on the above molar heat capacity data. The compound was characterized by powder XRD, FT-IR spectrum. Moreover, the thermal decomposition characteristics of Mn3(HEDTA)2·10H2O were investigated by thermogravimetry–mass spectrometer (TG–MS). The experimental result through TG measurement shows that a three-step mass loss process exists. H2O, CO2, NO, and NO2 were observed as products for oxidative degradation of Mn3(HEDTA)2·10H2O from the MS curves.

  • 1. Zubkowski, JD, Perry, DL, Valente, EJ, Lott, S 1996 A seven coordinate co-EDTA complex. Crystal and molecular structure of aquo(ethylenediaminetriacetatoacetic acid)cobalt(III) dihydrate. Inorg Chem 35:6352 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 2. Zasurskaya LA , Polyakova IN, Poznyak AL, Polynova TN, Sergienko. Crystal structure of strontium aqua(ethylenediaminetetraacetato)cobaltate(II) tetrahydrate Sr[CoEdta(H2O)]·4H2O. Crystallogr Rep. 2001;46: 37782.

    • Search Google Scholar
    • Export Citation
  • 3. Davidovich, RL, Gerasimenko, AV, Logvinova, VB 2004 Synthesis and crystal structure of manganese(II) ethylenediaminetetraacetatoplumbate(II) tetrahydrate. Russ J Inorg Chem 49:694699.

    • Search Google Scholar
    • Export Citation
  • 4. Wang, J, Wang, Y, Zhang, ZH, Zhang, XD, Tong, J, Liu, XZ et al. 2005 Syntheses, characterization, and structure determination of nine-coordinate Na[Y-III(edta)(H2O)3]·5H2O and eight-coordinate Na[Y-III(cydta)(H2O)2]·5H2O complexes. J Struct Chem 46:895905 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 5. Antsyshkina, AS, Sadikov, GG, Sergienko, VS, Poznyak, AL 2007 The crystal structure of [Mg(H2O)6][VO(edta)]·3.5H2O. Russ J Inorg Chem 52:510517 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 6. Huang, HM, Yang, HB, Li, XY, Ren, FF 2009 Diammonium aqua(ethylenediaminetetraacetato) iron(II) trihydrate. Acta Crystallogr Sect E Struct Rep Online 65:m87m88 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 7. Liu, B, Gao, J, Wang, J, Wang, YF, Xu, R, Hu, P et al. 2009 Synthesis and structures of nine-coordinate K[Dy(Edta)(H2O)3]·3.5H2O, (NH4)3[Dy(Ttha)]·5H2O, and eight-coordinate NH4[Dy(Cydta)(H2O)2]·4.5H2O complexes. Russ J Coord Chem 35:422428 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 8. Wang, XF, Gao, J, Wang, J, Zhang, ZH, Wang, YF, Chen, LJ et al. 2008 Crystal structures of seven-coordinate (NH4)2[Mn-II(edta)(H2O)]·3H2O, (NH4)2[Mn-II(cydta)(H2O)]·4H2O and K-2[MNII(Hdtpa)]·3.5H2O complexes. J Struct Chem 49:724731 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 9. Polyakova, IN, Poznyak, AL, Sergienko, VS, Stopolyanskaya, LV 2001 Crystal structures of acid ethylenediaminetetraacetates [Cd(H2Edta)(H2O)]·2H2O and [Mn(H2O)4][Mn(HEdta)(H2O)]2 ·4H2O. Crystallogr Rep 46:4045 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 10. Yi, T, Gao, S, Li, BG 1998 Edta-linked 4f–3d heterometallic two dimensional sheet in Ln2M3(edta)3(H2O)11·12H2O (Ln = Nd, Gd; M = Mn, Co). Polyhedron 17:22432248 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 11. Richards, S, Pedersen, B, Silverton, JV, Hoard, JL 1964 Stereochemistry of ethylenediamine tetraacetato complexes. I. The structure of crystalline Mn3(HY)10H2O and the configuration of the seven-coordinate Mn (OH2)Y−2 ion. Inorg Chem 3:2733 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 12. Judzentiene, A, Jagminas, A, Padarauskas, A 1997 Application of ion interaction chromatography in the electroplating industry. Chem Anal (Warsaw) 42:527534.

    • Search Google Scholar
    • Export Citation
  • 13. AlMasri, MS, Hamwi, A, Mikhlallaty, H 1997 Radiochemical determination of lead-210 in environmental water samples using Cerenkov counting. J Radioanal Nucl Chem 219:7375 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 14. Chen, L, Li, YQ, Huang, XJ, Zhou, MY 2009 One-pot synthesis of 2-amino-2-chromenes catalyzed by tetrasodium ethylenediaminetetraacetate. Chin J Org Chem 29:437440.

    • Search Google Scholar
    • Export Citation
  • 15. Bhor, MD, Panda, AG, Jagtap, SR, Bhanage, BM 2008 Hydrogenation of alpha, beta-unsaturated carbonyl compounds using recyclable water-soluble Fe-II/EDTA complex catalyst. Catal Lett 124:157164 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 16. Ahmed, MJ, Haque, ME 2002 A rapid spectrophotometric method for the determination of molybdenum in industrial, environmental, biological and soil samples using 5, 7-dibromo-8-hydroxyquinoline. Anal Sci 18:433439 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 17. Wunderlich, B 2004 The tribulations and successes on the road from DSC to TMDSC in the 20th century the prospects for the 21st century. J Therm Anal Calorim 78 1 731 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 18. Qi, YN, Zhang, J, Qiu, SJ, Sun, LX, Xu, F, Zhu, M et al. 2009 Thermal stability, decomposition and glass transition behavior of PANI/NiO composites. J Therm Anal Calorim 98:533537 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 19. Androsch, R 2000 Heat capacity measurements using temperature-modulated heat flux DSC with close control of the heater temperature. J Therm Anal Calorim 61 1 7589 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 20. Reading M , Elliot D, Hill VL, Some aspects of the theory and practise of modulated differential scanning calorimetry. In: Proceedings of the 21st North American Thermal Analysis Society Conference, Atlanta, Georgia; 1992. p. 145150.

    • Search Google Scholar
    • Export Citation
  • 21. Chau, J, Garlicka, I, Wolf, C, Teh, J 2007 Modulated DSC as a tool for polyethylene structure characterization. J Therm Anal Calorim 90:713719 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 22. Ishida, H, Rimdusit, S 1999 Heat capacity measurement of boron nitride-filled polybenzoxazine—The composite structure-insensitive property. J Therm Anal Calorim 58 3 497507 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 23. Zhang, J, Zeng, JL, Liu, YY, Sun, LX, Xu, F, You, WS et al. 2008 Thermal decomposition kinetics of the synthetic complex Pb(1, 4-BDC)·(DMF)(H2O). J Therm Anal Calorim 91:189193 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 24. Wunderlich, B, Jin, YM, Boller, A 1994 Mathematical-description of differential scanning calorimetry based on periodic temperature modulation. Thermochim Acta 238:277293 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 25. Danley, RL New modulated DSC measurement technique. Thermochim Acta 2003 402:9198.

  • 26. Wunderlich, B 2006 The contributions of MDSC to the understanding of the thermodynamics of polymers. J Therm Anal Calorim 85:179187 .

  • 27. Archer, DG Thermodynamic properties of synthetic sapphire (Alpha-Al2O3), standard reference material 720 and the effect of temperature-scale differences on thermodynamic properties. J Phys Chem Ref Data 1993 22:14411453 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 28. Ginnings, DC, Furukawa, GT 1953 Heat capacity standards for the range 14°K to 1200°K. J Am Chem Soc 75:522527 .

  • 29. Stavila, V, Gulea, A, Popa, N, Shova, S, Merbach, A, Simonov, YA et al. 2004 A novel 3D Nd(III)-Bi(III) coordination polymer generated from EDTA ligand. Inorg Chem Commun 7 5 634637 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 30. Qiu, SJ, Chu, HL, Zhang, J, Qi, YN, Sun, LX, Xu, F 2008 Heat capacities and thermodynamic properties of CoPc and CoTMPP. J Therm Anal Calorim 91:841848 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 31. Zhang, J, Liu, YY, Zeng, JL, Xu, F, Sun, LX, You, WS et al. 2008 Thermodynamic properties and thermal stability of the synthetic zinc formate dihydrate. J Therm Anal Calorim 91:861866 .

    • Crossref
    • Search Google Scholar
    • Export Citation
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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
1
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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