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  • 1 Materials and Thermochemistry Laboratory, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian 116023, People's Republic of China
  • | 2 Faculty of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian 116029, People's Republic of China
  • | 3 Graduate School of the Chinese Academy of Sciences, Beijing 100049, People's Republic of China
  • | 4 Laboratory of Materials Modification by Laser, Electron, and Ion Beams, Dalian University of Technology, Dalian 116024, China
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Abstract

The low-temperature molar heat capacity of crystalline Mn3(HEDTA)2·10H2O was measured by temperature-modulated differential scanning calorimetry (TMDSC) for the first time. The thermodynamic parameters such as entropy and enthalpy relative to 298.15 K were calculated based on the above molar heat capacity data. The compound was characterized by powder XRD, FT-IR spectrum. Moreover, the thermal decomposition characteristics of Mn3(HEDTA)2·10H2O were investigated by thermogravimetry–mass spectrometer (TG–MS). The experimental result through TG measurement shows that a three-step mass loss process exists. H2O, CO2, NO, and NO2 were observed as products for oxidative degradation of Mn3(HEDTA)2·10H2O from the MS curves.

  • 1. Zubkowski, JD, Perry, DL, Valente, EJ, Lott, S 1996 A seven coordinate co-EDTA complex. Crystal and molecular structure of aquo(ethylenediaminetriacetatoacetic acid)cobalt(III) dihydrate. Inorg Chem 35:6352 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 2. Zasurskaya LA , Polyakova IN, Poznyak AL, Polynova TN, Sergienko. Crystal structure of strontium aqua(ethylenediaminetetraacetato)cobaltate(II) tetrahydrate Sr[CoEdta(H2O)]·4H2O. Crystallogr Rep. 2001;46: 37782.

    • Search Google Scholar
    • Export Citation
  • 3. Davidovich, RL, Gerasimenko, AV, Logvinova, VB 2004 Synthesis and crystal structure of manganese(II) ethylenediaminetetraacetatoplumbate(II) tetrahydrate. Russ J Inorg Chem 49:694699.

    • Search Google Scholar
    • Export Citation
  • 4. Wang, J, Wang, Y, Zhang, ZH, Zhang, XD, Tong, J, Liu, XZ et al. 2005 Syntheses, characterization, and structure determination of nine-coordinate Na[Y-III(edta)(H2O)3]·5H2O and eight-coordinate Na[Y-III(cydta)(H2O)2]·5H2O complexes. J Struct Chem 46:895905 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 5. Antsyshkina, AS, Sadikov, GG, Sergienko, VS, Poznyak, AL 2007 The crystal structure of [Mg(H2O)6][VO(edta)]·3.5H2O. Russ J Inorg Chem 52:510517 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 6. Huang, HM, Yang, HB, Li, XY, Ren, FF 2009 Diammonium aqua(ethylenediaminetetraacetato) iron(II) trihydrate. Acta Crystallogr Sect E Struct Rep Online 65:m87m88 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 7. Liu, B, Gao, J, Wang, J, Wang, YF, Xu, R, Hu, P et al. 2009 Synthesis and structures of nine-coordinate K[Dy(Edta)(H2O)3]·3.5H2O, (NH4)3[Dy(Ttha)]·5H2O, and eight-coordinate NH4[Dy(Cydta)(H2O)2]·4.5H2O complexes. Russ J Coord Chem 35:422428 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 8. Wang, XF, Gao, J, Wang, J, Zhang, ZH, Wang, YF, Chen, LJ et al. 2008 Crystal structures of seven-coordinate (NH4)2[Mn-II(edta)(H2O)]·3H2O, (NH4)2[Mn-II(cydta)(H2O)]·4H2O and K-2[MNII(Hdtpa)]·3.5H2O complexes. J Struct Chem 49:724731 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 9. Polyakova, IN, Poznyak, AL, Sergienko, VS, Stopolyanskaya, LV 2001 Crystal structures of acid ethylenediaminetetraacetates [Cd(H2Edta)(H2O)]·2H2O and [Mn(H2O)4][Mn(HEdta)(H2O)]2 ·4H2O. Crystallogr Rep 46:4045 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 10. Yi, T, Gao, S, Li, BG 1998 Edta-linked 4f–3d heterometallic two dimensional sheet in Ln2M3(edta)3(H2O)11·12H2O (Ln = Nd, Gd; M = Mn, Co). Polyhedron 17:22432248 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 11. Richards, S, Pedersen, B, Silverton, JV, Hoard, JL 1964 Stereochemistry of ethylenediamine tetraacetato complexes. I. The structure of crystalline Mn3(HY)10H2O and the configuration of the seven-coordinate Mn (OH2)Y−2 ion. Inorg Chem 3:2733 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 12. Judzentiene, A, Jagminas, A, Padarauskas, A 1997 Application of ion interaction chromatography in the electroplating industry. Chem Anal (Warsaw) 42:527534.

    • Search Google Scholar
    • Export Citation
  • 13. AlMasri, MS, Hamwi, A, Mikhlallaty, H 1997 Radiochemical determination of lead-210 in environmental water samples using Cerenkov counting. J Radioanal Nucl Chem 219:7375 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 14. Chen, L, Li, YQ, Huang, XJ, Zhou, MY 2009 One-pot synthesis of 2-amino-2-chromenes catalyzed by tetrasodium ethylenediaminetetraacetate. Chin J Org Chem 29:437440.

    • Search Google Scholar
    • Export Citation
  • 15. Bhor, MD, Panda, AG, Jagtap, SR, Bhanage, BM 2008 Hydrogenation of alpha, beta-unsaturated carbonyl compounds using recyclable water-soluble Fe-II/EDTA complex catalyst. Catal Lett 124:157164 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 16. Ahmed, MJ, Haque, ME 2002 A rapid spectrophotometric method for the determination of molybdenum in industrial, environmental, biological and soil samples using 5, 7-dibromo-8-hydroxyquinoline. Anal Sci 18:433439 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 17. Wunderlich, B 2004 The tribulations and successes on the road from DSC to TMDSC in the 20th century the prospects for the 21st century. J Therm Anal Calorim 78 1 731 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 18. Qi, YN, Zhang, J, Qiu, SJ, Sun, LX, Xu, F, Zhu, M et al. 2009 Thermal stability, decomposition and glass transition behavior of PANI/NiO composites. J Therm Anal Calorim 98:533537 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 19. Androsch, R 2000 Heat capacity measurements using temperature-modulated heat flux DSC with close control of the heater temperature. J Therm Anal Calorim 61 1 7589 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 20. Reading M , Elliot D, Hill VL, Some aspects of the theory and practise of modulated differential scanning calorimetry. In: Proceedings of the 21st North American Thermal Analysis Society Conference, Atlanta, Georgia; 1992. p. 145150.

    • Search Google Scholar
    • Export Citation
  • 21. Chau, J, Garlicka, I, Wolf, C, Teh, J 2007 Modulated DSC as a tool for polyethylene structure characterization. J Therm Anal Calorim 90:713719 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 22. Ishida, H, Rimdusit, S 1999 Heat capacity measurement of boron nitride-filled polybenzoxazine—The composite structure-insensitive property. J Therm Anal Calorim 58 3 497507 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 23. Zhang, J, Zeng, JL, Liu, YY, Sun, LX, Xu, F, You, WS et al. 2008 Thermal decomposition kinetics of the synthetic complex Pb(1, 4-BDC)·(DMF)(H2O). J Therm Anal Calorim 91:189193 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 24. Wunderlich, B, Jin, YM, Boller, A 1994 Mathematical-description of differential scanning calorimetry based on periodic temperature modulation. Thermochim Acta 238:277293 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 25. Danley, RL New modulated DSC measurement technique. Thermochim Acta 2003 402:9198.

  • 26. Wunderlich, B 2006 The contributions of MDSC to the understanding of the thermodynamics of polymers. J Therm Anal Calorim 85:179187 .

  • 27. Archer, DG Thermodynamic properties of synthetic sapphire (Alpha-Al2O3), standard reference material 720 and the effect of temperature-scale differences on thermodynamic properties. J Phys Chem Ref Data 1993 22:14411453 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 28. Ginnings, DC, Furukawa, GT 1953 Heat capacity standards for the range 14°K to 1200°K. J Am Chem Soc 75:522527 .

  • 29. Stavila, V, Gulea, A, Popa, N, Shova, S, Merbach, A, Simonov, YA et al. 2004 A novel 3D Nd(III)-Bi(III) coordination polymer generated from EDTA ligand. Inorg Chem Commun 7 5 634637 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 30. Qiu, SJ, Chu, HL, Zhang, J, Qi, YN, Sun, LX, Xu, F 2008 Heat capacities and thermodynamic properties of CoPc and CoTMPP. J Therm Anal Calorim 91:841848 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 31. Zhang, J, Liu, YY, Zeng, JL, Xu, F, Sun, LX, You, WS et al. 2008 Thermodynamic properties and thermal stability of the synthetic zinc formate dihydrate. J Therm Anal Calorim 91:861866 .

    • Crossref
    • Search Google Scholar
    • Export Citation

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  • Impact Factor (2019): 2.731
  • Scimago Journal Rank (2019): 0.415
  • SJR Hirsch-Index (2019): 87
  • SJR Quartile Score (2019): Q3 Condensed Matter Physics
  • SJR Quartile Score (2019): Q3 Physical and Theoretical Chemistry
  • Impact Factor (2018): 2.471
  • Scimago Journal Rank (2018): 0.634
  • SJR Hirsch-Index (2018): 78
  • SJR Quartile Score (2018): Q2 Condensed Matter Physics
  • SJR Quartile Score (2018): Q2 Physical and Theoretical Chemistry

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
4
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)