Authors:
Li-Fang Song Materials and Thermochemistry Laboratory, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 116023, Dalian, People's Republic of China
Graduate School of the Chinese Academy of Sciences, 100049, Beijing, People's Republic of China

Search for other papers by Li-Fang Song in
Current site
Google Scholar
PubMed
Close
,
Chun-Hong Jiang Materials and Thermochemistry Laboratory, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 116023, Dalian, People's Republic of China
Graduate School of the Chinese Academy of Sciences, 100049, Beijing, People's Republic of China

Search for other papers by Chun-Hong Jiang in
Current site
Google Scholar
PubMed
Close
,
Cheng-Li Jiao Materials and Thermochemistry Laboratory, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 116023, Dalian, People's Republic of China
Graduate School of the Chinese Academy of Sciences, 100049, Beijing, People's Republic of China

Search for other papers by Cheng-Li Jiao in
Current site
Google Scholar
PubMed
Close
,
Jian Zhang Materials and Thermochemistry Laboratory, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 116023, Dalian, People's Republic of China

Search for other papers by Jian Zhang in
Current site
Google Scholar
PubMed
Close
,
Li-Xian Sun Materials and Thermochemistry Laboratory, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 116023, Dalian, People's Republic of China

Search for other papers by Li-Xian Sun in
Current site
Google Scholar
PubMed
Close
,
Fen Xu Faculty of Chemistry and Chemical Engineering, Liaoning Normal University, 116029, Dalian, People's Republic of China

Search for other papers by Fen Xu in
Current site
Google Scholar
PubMed
Close
,
Qing-Zhu Jiao Faculty of Chemistry and Chemical Engineering, Liaoning Normal University, 116029, Dalian, People's Republic of China

Search for other papers by Qing-Zhu Jiao in
Current site
Google Scholar
PubMed
Close
,
Yong-Heng Xing Faculty of Chemistry and Chemical Engineering, Liaoning Normal University, 116029, Dalian, People's Republic of China

Search for other papers by Yong-Heng Xing in
Current site
Google Scholar
PubMed
Close
,
Yong Du State Key Laboratory of Powder Metallurgy, Central South University, 410083, Changsha, People's Republic of China

Search for other papers by Yong Du in
Current site
Google Scholar
PubMed
Close
,
Zhong Cao College of Chemistry and Biological Engineering, Changsha University of Science and Technology, 410076, Changsha, People's Republic of China

Search for other papers by Zhong Cao in
Current site
Google Scholar
PubMed
Close
, and
Feng-Lei Huang State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, 100081, Beijing, People's Republic of China

Search for other papers by Feng-Lei Huang in
Current site
Google Scholar
PubMed
Close
Restricted access

Abstract

A metal-organic framework [Mn(4,4′-bipy)(1,3-BDC)]n (MnMOF, 1,3-BDC = 1,3-benzene dicarboxylate, 4,4′-bipy = 4,4′-bipyridine) has been synthesized hydrothermally and characterized by single crystal XRD and FT-IR spectrum. The low-temperature molar heat capacities of MnMOF were measured by temperature-modulated differential scanning calorimetry for the first time. The thermodynamic parameters such as entropy and enthalpy relative to reference temperature 298.15 K were derived based on the above molar heat capacity data. Moreover, the thermal stability and the decomposition mechanism of MnMOF were investigated by thermogravimetry analysis-mass spectrometer. A two-stage mass loss was observed in air flow. MS curves indicated that the gas products of oxidative degradation were H2O, CO2, NO, and NO2.

  • 1. Murray, LJ, Dinca, M, Long, JR 2009 Hydrogen storage in metal-organic frameworks. Chem Soc Rev 38:12941314 .

  • 2. Lee, J, Farha, OK, Roberts, J, Scheidt, KA, Nguyen, ST, Hupp, JT 2009 Metal-organic framework materials as catalysts. Chem Soc Rev 38:14501459 .

  • 3. Liu, YY, Zhang, J, Xu, F, Sun, LX, Zhang, T, You, WS et al. 2008 Lithium-based 3D coordination polymer with hydrophilic structure for sensing of solvent molecules. Cryst Growth Des 8:31273129 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 4. Bae, YS, Mulfort, KL, Frost, H, Ryan, P, Punnathanam, S, Broadbelt, LJ et al. 2008 Separation of CO2 from CH4 using mixed-ligand metal-organic frameworks. Langmuir. 24:85928598 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 5. Contreras, R, Flores-Parra, A, Mijangos, E, Tellez, F, Lopez-Sandoval, H, Barba-Behrens, N 2009 From mono to polydentate azole and benzazole derivatives, versatile ligands for main group and transition metal atoms. Coordin Chem Rev 253:19791999 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 6. Kumar, DK, Das, A, Dastidar, P 2006 One-dimensional chains, two-dimensional corrugated sheets having a cross-linked helix in metal-organic frameworks: exploring hydrogen-bond capable backbones and ligating topologies in mixed ligand systems. Cryst Growth Des 6:19031909 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 7. Reading, M, Luget, A, Wilson, R 1994 Modulated differential scanning calorimetry. Thermochim Acta 238:295307 .

  • 8. Wunderlich, B, Jin, YM, Boller, A 1994 Mathematical-description of differential scanning calorimetry based on periodic temperature modulation. Thermochim Acta 238:277293 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 9. Wunderlich, B 2006 The contributions of MDSC to the understanding of the thermodynamics of polymers. J Therm Anal Calorim 85:179187 .

  • 10. Danley, RL New modulated DSC measurement technique. Thermochim Acta 2003 402:9198.

  • 11. Qiu, SJ, Chu, HL, Zhang, J, Qi, YN, Sun, LX, Xu, F 2008 Heat capacities and thermodynamic properties of CoPc and CoTMPP. J Therm Anal Calorim 91:841848 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 12. Zhang, J, Liu, YY, Zeng, JL, Xu, F, Sun, LX, You, WS et al. 2008 Thermodynamic properties and thermal stability of the synthetic zinc formate dihydrate. J Therm Anal Calorim 91:861866 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 13. Archer, DG Thermodynamic properties of synthetic sapphire (Alpha-Al2O3), standard reference material 720 and the effect of temperature-scale differences on thermodynamic properties. J Phys Chem Ref Data 1993 22:14411453 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 14. Ginnings, DC, Furukawa, GT 1953 Heat capacity standards for the range 14-Degrees-K to 1200-Degrees-K. J Am Chem Soc 75:522527 .

  • 15. Sheldrick, GM 1997 SHELX97, Program for crystal structure refinement Göttingen University Germany.

  • Collapse
  • Expand

To see the editorial board, please visit the website of Springer Nature.

Manuscript Submission: HERE

For subscription options, please visit the website of Springer Nature.

Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
1
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

Monthly Content Usage

Abstract Views Full Text Views PDF Downloads
Jan 2024 43 2 0
Feb 2024 12 2 1
Mar 2024 7 1 0
Apr 2024 53 0 0
May 2024 9 0 0
Jun 2024 14 0 0
Jul 2024 12 0 0