The results of calorimetric investigations of liquid In–Sn alloys using Oelsen calorimetry are presented in this article. Based on obtained enthalpy space diagram and enthalpy isotherm diagram, thermodynamic parameters for the liquid In–Sn alloys, including mixing and excess integral and partial molar quantities at temperature of 600 K, have been determined and compared with available literature data.
2. Speckbrock G , Kamitz S, Alt M, Schmitt H. Low melting gallium, indium, and tin eutectic alloys, United States Patent 6019509; 2000.
3. White CET , Okamoto H, editors. Phase diagrams of indium alloys and their engineering applications. Utica, NY: Indium Corporation of America, Ohio: Materials Information Soc., Materials Park; 1992.
5. Vicentini, M, Paoletti, A 1959 Self diffusion in liquid In-Sn alloys. Phys Astron 14:1373–1380.
6. Swarnalata, N, Padmini, ARKL 1984 Ultrasonic velocities and elastic constants in tin–indium alloys. Patrmana 23:155–163 .
7. Maciejewski S . Band structure and fermi surface on In3Sn alloys in the β-phase. Phys Status Solidi B. 2006;66: 633–38.
8. Degtyareva, VF 2009 The fcc-bcc bain path in In-Sn and related alloys at ambient and high pressure. J Phys 21:95702–95706.
9. Terpilowski, J, Przedziecka-Mycielska, E 1960 EMF measurements of In-Sn alloys. Arch Hutn 5:281–289.
10. Cakir, O, Alpaut, O 1988 Thermodynamic properties of solid In-Sn alloys. J Less-Common Met 141:11–27 .
11. Kleppa, OJ Calorimetric investigation of the In-Sn system. J Phys Chem 1956 60:842–850 .
12. Wittig, FE, Scheidt, P 1961 Direct reaction calorimetry of In-Sn alloys. Z Phys Chem 28:120–126.
13. Yazawa, A, Kawashima, T, Itagaki, K 1968 Thermodynamics of the In-Sn system. J Jpn Inst Met Sendai 32:1281–1287.
14. Brunetti, B, Gozzi, D, Iervolino, M, Piacente, V, Zanicchi, G, Parodi, N, Borzone, G 2006 Bismuth activity in lead-free solder Bi-In-Sn-alloys. Calphad 30:431–442 .
15. Hultgren, R, Desai, PD, Hawkins, DT, Gleiser, M, Kelley, KK 1973 Selected values of thermodynamic properties of binary alloys American Society of Metals Metals Park, OH.
16. Dinsdale AT , Watson A, Kroupa A, Zemanova A, Vrestal J, Vizdal J. COST531 thermodynamic database, Ver. 2.2; 2006.
17. Oelsen, W, Zuhlke, P 1956 Zur thermodynamischen Analyse VIII. Arch Eisenhuttenwes 27:743–752.
18. Oelsen, W, Johannsen, F, Podgornik, A 1956 Kalorimetrie und Thermodynamik der Blei-Antimon-legierungen. Zeitsch Erzbergbau Metallhüttenwes 9:1–11.
19. Oelsen, W, Schürmann, E, Weigt, HJ, Oelsen, O 1956 Zur thermodynamischen Analyse IV. Arch Eisenhuttenwes 27:487–511.
20. Pool, MJ, Predel, B, Schulheiss, E 1979 Application of the Setaram high temperature calorimeter for determination of mixing enthalpies of liquid alloys. Thermochim Acta 28:349–358 .
21. Zivkovic, D, Manasijevic, D, Zivković, Z 2004 Thermodynamic and phase diagram investigation of Pb-BiIn section in Pb-Bi-In ternary system. Thermochim Acta 417:119–125 .
22. Sorai M , editors. Comprehensive handbook of calorimetry and thermal analysis. Chichester: Wiley; 2004. p 297.
23. Zivkovic, D, Katayama, I, Gomidzelovic, L, Manasijevic, D, Novakovic, R 2007 Comparative thermodynamic study and phase equilibria of the Bi-Ga-Sn ternary system. Int J Mater Res 98:1025–1030.
24. Gomidzelovic, L, Zivkovic, D 2009 Thermodynamic analysis of AuIn-Sb system using Oelsen calorimetry and predicting methods. J Therm Anal Calorim 98:743–748 .
25. Saunders N , Miodownik AP. CALPHAD calculation of phase diagrams—a comprehensive guide. Amsterdam: Elsevier; 1998.