Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 102: Issue 3
Thermal behavior of 3,4,5-triamino-1,2,4-triazole dinitramide
Authors:
Liang Xue School of Chemistry and Materials Science, Shaanxi Normal University, 710062, Xi'an, Shaanxi, People's Republic of China
Propellant and Explosive Combustion Key Lab of Science and Technology for National Defence, Xi'an Modern Chemistry Research Institute, 710065, Xi'an, Shaanxi, People's Republic of China

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Feng-Qi Zhao Propellant and Explosive Combustion Key Lab of Science and Technology for National Defence, Xi'an Modern Chemistry Research Institute, 710065, Xi'an, Shaanxi, People's Republic of China

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Xiao-Ling Xing Propellant and Explosive Combustion Key Lab of Science and Technology for National Defence, Xi'an Modern Chemistry Research Institute, 710065, Xi'an, Shaanxi, People's Republic of China

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Zhi-Ming Zhou School of Chemical Engineering and Environment, Beijing Institute of Technology, 100081, Beijing, People's Republic of China

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Kai Wang School of Chemical Engineering and Environment, Beijing Institute of Technology, 100081, Beijing, People's Republic of China

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Hong-Xu Gao Propellant and Explosive Combustion Key Lab of Science and Technology for National Defence, Xi'an Modern Chemistry Research Institute, 710065, Xi'an, Shaanxi, People's Republic of China

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Jian-Hua Yi Propellant and Explosive Combustion Key Lab of Science and Technology for National Defence, Xi'an Modern Chemistry Research Institute, 710065, Xi'an, Shaanxi, People's Republic of China

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Rong-Zu Hu Propellant and Explosive Combustion Key Lab of Science and Technology for National Defence, Xi'an Modern Chemistry Research Institute, 710065, Xi'an, Shaanxi, People's Republic of China

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Pages:
989–992
Online Publication Date:
17 Jun 2010
Publication Date:
01 Dec 2010
Article Category:
Research Article
DOI:
https://doi.org/10.1007/s10973-010-0752-6
Keywords:
3,4,5-Triamino-1,2,4-triazole dinitramide; Thermal behavior; Specific heat capacity; Adiabatic time-to-explosion
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Abstract

The thermal decomposition behavior of 3,4,5-triamino-1,2,4-triazole dinitramide was measured using a C-500 type Calvet microcalorimeter at four different temperatures under atmospheric pressure. The apparent activation energy and pre-exponential factor of the exothermic decomposition reaction are 165.57 kJ mol−1 and 1018.04s−1, respectively. The critical temperature of thermal explosion is 431.71 K. The entropy of activation (ΔS≠), enthalpy of activation (ΔH≠), and free energy of activation (ΔG≠) are 97.19 J mol−1K−1, 161.90 kJ mol−1, and 118.98 kJ mol−1, respectively. The self-accelerating decomposition temperature (TSADT) is 422.28 K. The specific heat capacity of 3,4,5-triamino-1,2,4-triazole dinitramide was determined with a micro-DSC method and a theoretical calculation method. Specific heat capacity (J g−1K−1) equation is Cp = 0.252 + 3.131 × 10−3T (283.1 K < T < 353.2 K). The molar heat capacity of 3,4,5-triamino-1,2,4-triazole dinitramide is 264.52 J mol−1 K−1 at 298.15 K. The adiabatic time-to-explosion of 3,4,5-triamino-1,2,4-triazole dinitramide is calculated to be a certain value between 123.36 and 128.56 s.

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Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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