Geopolymers
Inorganic polymeric new materials
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V. P. Korolev
V. P. Korolev
Institute of Solution Chemistry, Russian Academy of Sciences, 1, Academicheskaya str, 153045, Ivanovo, Russia
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O. A. Antonova
O. A. Antonova
Institute of Solution Chemistry, Russian Academy of Sciences, 1, Academicheskaya str, 153045, Ivanovo, Russia
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N. L. Smirnova
N. L. Smirnova
Institute of Solution Chemistry, Russian Academy of Sciences, 1, Academicheskaya str, 153045, Ivanovo, Russia
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A. V. Kustov
A. V. Kustov
Institute of Solution Chemistry, Russian Academy of Sciences, 1, Academicheskaya str, 153045, Ivanovo, Russia
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Abstract
The enthalpies of solution of tetraethyl- and tetra-n-hexylammonium bromides have been measured in mixtures of formamide with ethylene glycol at 298.15 and 313.15 K in the whole mole fraction range by the calorimetric method. The standard enthalpies of solution in binary mixtures have been calculated with Redlich–Rosenfeld–Meyer type equation. The enthalpy and heat capacity parameters of pair interaction of organic electrolytes with EG in FA and with FA in EG have been computed and discussed. The enthalpy interaction parameters of single ions with EG in FA medium have been evaluated and compared with those for ion–water and ion–MeOH interaction in FA. The standard heat capacities of solution have been evaluated. The excess enthalpies of solution, ΔsolHE, of Et4NBr, Bu4NBr, and Hex4NBr have been determined. The ΔsolHE values are positive for Et4NBr and negative for Bu4NBr and Hex4NBr and become more negative from Bu4NBr to Hex4NBr.
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2. Kustov, AV, Smirnova, NL, Antonova, OA, Korolev, VP. Thermodynamic characteristics of solution and interparticle interactions in water–formamide–Et4NBr and methanol–formamide–Et4NBr systems. Russ J Phys Chem 2008 82:1549–1554 .
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3. Korolev, VP, Smirnova, NL, Antonova, OA, Kustov, AV. Heat properties of Bu4NBr solutions in binary mixtures based on formamide. Russ J Gen Chem 2008 78:2013–2018 .
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| Journal of Thermal Analysis and Calorimetry | |
|---|---|
| Language | English |
| Size | A4 |
| Year of Foundation |
1969 |
| Volumes per Year |
1 |
| Issues per Year |
24 |
| Founder | Akadémiai Kiadó |
| Founder's Address |
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. |
| Publisher | Akadémiai Kiadó Springer Nature Switzerland AG |
| Publisher's Address |
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. CH-6330 Cham, Switzerland Gewerbestrasse 11. |
| Responsible Publisher |
Chief Executive Officer, Akadémiai Kiadó |
| ISSN | 1388-6150 (Print) |
| ISSN | 1588-2926 (Online) |
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Temperature dependence of the rate of reaction in thermal analysis
The Arrhenius equation in condensed phase kinetics
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