Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 103: Issue 1
Heat capacities and thermodynamic properties of MgNDC
Authors:
Li-Fang Song Materials and Thermochemistry Laboratory, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian 116023, People's Republic of China
Graduate School of the Chinese Academy of Sciences, Beijing 100049, People's Republic of China

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Cheng-Li Jiao Materials and Thermochemistry Laboratory, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian 116023, People's Republic of China
Graduate School of the Chinese Academy of Sciences, Beijing 100049, People's Republic of China

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Chun-Hong Jiang Materials and Thermochemistry Laboratory, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian 116023, People's Republic of China
Graduate School of the Chinese Academy of Sciences, Beijing 100049, People's Republic of China

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Jian Zhang Materials and Thermochemistry Laboratory, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian 116023, People's Republic of China

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Li-Xian Sun Materials and Thermochemistry Laboratory, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian 116023, People's Republic of China

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Fen Xu Faculty of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian 116029, People's Republic of China

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Qing-Zhu Jiao Faculty of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian 116029, People's Republic of China

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Yong-Heng Xing Faculty of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian 116029, People's Republic of China

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F. L. Huang State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing 100081, People's Republic of China

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Yong Du State Key Laboratory of Powder Metallurgy, Central South University, Changsha 410083, People's Republic of China

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Zhong Cao College of Chemistry and Biological Engineering, Changsha University of Science and Technology, Changsha 410076, People's Republic of China

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Fen Li Graduate School of the Chinese Academy of Sciences, Beijing 100049, People's Republic of China

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Jijun Zhao Laboratory of Materials Modification by Laser, Electron, and Ion Beams, Dalian University of Technology, Dalian 116024, China

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Pages:
365–372
Online Publication Date:
06 May 2010
Publication Date:
01 Jan 2011
Article Category:
Research Article
DOI:
https://doi.org/10.1007/s10973-010-0777-x
Keywords:
Magnesium; TMDSC; Metal-organic frameworks; Molar heat capacity; TG
Restricted access

Abstract

One-three-dimensional metal-organic frameworks Mg1.5(C12H6O4)1.5(C3H7NO)2 (MgNDC) has been synthesized solvothermally and characterized by single crystal XRD, powder XRD, FT-IR spectra. The low-temperature molar heat capacities of MgNDC were measured by temperature modulated differential scanning calorimetry (TMDSC) over the temperature range from 205 to 470 K for the first time. No phase transition or thermal anomaly was observed in the experimental temperature range. The thermodynamic parameters of MgNDC such as entropy and enthalpy relative to reference temperature of 298.15 K were derived based on the above molar heat capacities data. Moreover, the thermal stability and decomposition of MgNDC was further investigated through thermogravimetry (TG)–mass spectrometer (MS). Three stages of mass loss were observed in the TG curve. TG–MS curve indicated that the oxidative degradation products of MgNDC are mainly H2O, CO2, NO, and NO2.

  • 1. Murray, LJ, Dinca, M, Long, JR 2009 Hydrogen storage in metal-organic frameworks. Chem Soc Rev 38:1294–1314 .

  • 2. Lee, J, Farha, OK, Roberts, J, Scheidt, KA, Nguyen, ST, Hupp, JT 2009 Metal-organic framework materials as catalysts. Chem Soc Rev 38:1450–1459 .

  • 3. Liu, YY, Zhang, J, Xu, F, Sun, LX, Zhang, T, You, WS et al. 2008 Lithium-based 3D coordination polymer with hydrophilic structure for sensing of solvent molecules. Cryst Growth Des 8:3127–3129 .

    • Crossref
    • Search Google Scholar
    • Export Citation

  • 4. Bae, YS, Mulfort, KL, Frost, H, Ryan, P, Punnathanam, S, Broadbelt, LJ et al. 2008 Separation of CO2 from CH4 using mixed-ligand metal-organic frameworks. Langmuir 24:8592–8598 .

    • Crossref
    • Search Google Scholar
    • Export Citation

  • 5. Rieter, WJ, Taylor, KML, An, HY, Lin, WL, Lin, WB 2006 Nanoscale metal-organic frameworks as potential multimodal contrast enhancing agents. J Am Chem Soc 128:9024–9025 .

    • Crossref
    • Search Google Scholar
    • Export Citation

  • 6. Contreras, R, Flores-Parra, A, Mijangos, E, Tellez, F, Lopez-Sandoval, H, Barba-Behrens, N 2009 From mono to polydentate azole and benzazole derivatives, versatile ligands for main group and transition metal atoms. Coord Chem Rev 253:1979–1999 .

    • Crossref
    • Search Google Scholar
    • Export Citation

  • 7. Banerjee, D, Kim, SJ, Parise, JB 2009 Lithium based metal-organic framework with exceptional stability. Cryst Growth Des 9:2500–2503 .

  • 8. Liu, YY, Zhang, H, Sun, LX, Xu, F, You, WS, Zhao, Y 2008 Solvothermal synthesis and characterization of a lithium coordination polymer possessing a highly stable 3D network structure. Inorg Chem Commun 11:396–399 .

    • Crossref
    • Search Google Scholar
    • Export Citation

  • 9. Chen, SP, Yang, Q, Gao, S 2009 Syntheses, characterization and thermal properties of lanthanide complexes with 2-mercaptonicotinic acid. J Therm Anal Calorim 95:685–689 .

    • Crossref
    • Search Google Scholar
    • Export Citation

  • 10. Leitner, J, Ruzicka, K, Sedmidubsky, D, Svoboda, P 2009 Heat capacity, enthalpy and entropy of calcium niobates. J Therm Anal Calorim 95:397–402 .

    • Crossref
    • Search Google Scholar
    • Export Citation

  • 11. Markin, AV, Ruchenin, VA, Smirnova, NN, Gorina, EA, Titova, SN, Domrachev, GA 2010 Heat capacity and standard thermodynamic functions of a fullerene complex, ((CH3)(3)Si)(12)C-60, over the range from T → 0 K to T = 350 K. J Chem Eng Data 55:871–875 .

    • Crossref
    • Search Google Scholar
    • Export Citation

  • 12. Dinca, M, Long, JR 2005 Strong H-2 binding and selective gas adsorption within the microporous coordination solid Mg-3(O2C–C10H6–CO2)(3). J Am Chem Soc 127:9376–9377 .

    • Crossref
    • Search Google Scholar
    • Export Citation

  • 13. Wunderlich, B, Jin, YM, Boller, A 1994 Mathematical-description of differential scanning calorimetry based on periodic temperature modulation. Thermochim Acta 238:277–293 .

    • Crossref
    • Search Google Scholar
    • Export Citation

  • 14. Wunderlich, B 2006 The contributions of MDSC to the understanding of the thermodynamics of polymers. J Therm Anal Calorim 85:179–187 .

  • 15. Danley, RL New modulated DSC measurement technique. Thermochim Acta 2003 402:91–98.

  • 16. Chau, J, Garlicka, I, Wolf, C, Teh, J 2007 Modulated DSC as a tool for polyethylene structure characterization. J Therm Anal Calorim 90:713–719 .

    • Crossref
    • Search Google Scholar
    • Export Citation

  • 17. Qiu, SJ, Chu, HL, Zhang, J, Qi, YN, Sun, LX, Xu, F 2008 Heat capacities and thermodynamic properties of CoPc and CoTMPP. J Therm Anal Calorim 91:841–848 .

    • Crossref
    • Search Google Scholar
    • Export Citation

  • 18. Archer, DG Thermodynamic properties of synthetic sapphire (Alpha-Al2O3), standard reference material 720 and the effect of temperature-scale differences on thermodynamic properties. J Phys Chem Ref Data 1993 22:1441–1453 .

    • Crossref
    • Search Google Scholar
    • Export Citation

  • 19. Ginnings, DC, Furukawa, GT 1953 Heat capacity standards for the range 14-degrees-K to 1200-degrees-K. J Am Chem Soc 75:522–527 .

  • 20. Sheldrick, GM 1997 SHELX97, Program for crystal structure refinement Göttingen University Germany.

  • Collapse
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Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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