Authors:
Chun-Hong Jiang Materials and Thermochemistry Laboratory, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian 116023, People's Republic of China
Graduate School of the Chinese Academy of Sciences, Beijing 100049, People's Republic of China

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Li-Fang Song Materials and Thermochemistry Laboratory, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian 116023, People's Republic of China
Graduate School of the Chinese Academy of Sciences, Beijing 100049, People's Republic of China

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Cheng-Li Jiao Materials and Thermochemistry Laboratory, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian 116023, People's Republic of China
Graduate School of the Chinese Academy of Sciences, Beijing 100049, People's Republic of China

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Jian Zhang Materials and Thermochemistry Laboratory, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian 116023, People's Republic of China

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Li-Xian Sun Materials and Thermochemistry Laboratory, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian 116023, People's Republic of China

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Fen Xu Faculty of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian 116029, People's Republic of China

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Yong Du State Key Laboratory of Powder Metallurgy, Central South University, Changsha 410083, People's Republic of China

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Zhong Cao School of Chemistry and Environmental Engineering, Changsha University of Science and Technology, Changsha 410076, People's Republic of China

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Abstract

A three-dimensional lithium-based metal–organic framework Li2(2,6-NDC) (2,6-NDC = 2,6-naphthalene dicarboxylate) has been synthesized solvothermally and characterized by X-ray powder diffraction, elemental analysis, FT-IR spectroscopy, thermogravimetry and mass spectrometer analysis (TG–MS). The framework has exceptional stability and is stable to 863 K. The thermal decomposition characteristic of this compound was investigated through the TG–MS from 293 to 1250 K. The molar heat capacity of the compound was measured by temperature modulated differential scanning calorimetry (TMDSC) over the temperature range from 195 to 670 K for the first time. The thermodynamic parameters such as entropy and enthalpy versus 298.15 K based on the above molar heat capacity were calculated.

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
1
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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