Geopolymers
Inorganic polymeric new materials
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G. I. Zharkova
G. I. Zharkova
Nikolaev Institute of Inorganic Chemistry, SB RAS, Lavrentiev av., 3, Novosibirsk, Russia, 630090
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S. V. Sysoev
S. V. Sysoev
Nikolaev Institute of Inorganic Chemistry, SB RAS, Lavrentiev av., 3, Novosibirsk, Russia, 630090
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P. A. Stabnikov
P. A. Stabnikov
Nikolaev Institute of Inorganic Chemistry, SB RAS, Lavrentiev av., 3, Novosibirsk, Russia, 630090
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V. A. Logvinenko
V. A. Logvinenko
Nikolaev Institute of Inorganic Chemistry, SB RAS, Lavrentiev av., 3, Novosibirsk, Russia, 630090
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I. K. Igumenov
I. K. Igumenov
Nikolaev Institute of Inorganic Chemistry, SB RAS, Lavrentiev av., 3, Novosibirsk, Russia, 630090
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Abstract
Volatile palladium(II) β-iminoketonates of the general formula Pd(R–C(NH)–CH–CO–R1),where R and R1 are CH3, CF3, C(CH3)3 in various combinations, were synthesized and identified. Thermal properties of the resulting palladium(II) complexes in the solid phase were studied by thermogravimetric analysis under an argon atmosphere. The temperature dependence of the saturated vapor pressure was measured for the compounds by the flow method and thermodynamic characteristics of vaporization processes, enthalpy ΔHT and entropy ΔSTo, were determined. The atom-atomic potential calculation of the van der Waals energy (Ecryst) of the crystal lattice was performed and the results were compared to the experimental values of the sublimation enthalpy for the complexes under study.
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| Journal of Thermal Analysis and Calorimetry | |
|---|---|
| Language | English |
| Size | A4 |
| Year of Foundation |
1969 |
| Volumes per Year |
1 |
| Issues per Year |
24 |
| Founder | Akadémiai Kiadó |
| Founder's Address |
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. |
| Publisher | Akadémiai Kiadó Springer Nature Switzerland AG |
| Publisher's Address |
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. CH-6330 Cham, Switzerland Gewerbestrasse 11. |
| Responsible Publisher |
Chief Executive Officer, Akadémiai Kiadó |
| ISSN | 1388-6150 (Print) |
| ISSN | 1588-2926 (Online) |
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Temperature dependence of the rate of reaction in thermal analysis
The Arrhenius equation in condensed phase kinetics
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