Geopolymers
Inorganic polymeric new materials
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Jintao Wan
Jintao Wan
State Key Laboratory of Chemical Engineering, Department of Chemical and Biochemical Engineering, Zhejiang University, Hangzhou 310027, China
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Hong Fan
Hong Fan
State Key Laboratory of Chemical Engineering, Department of Chemical and Biochemical Engineering, Zhejiang University, Hangzhou 310027, China
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Bo-Geng Li
Bo-Geng Li
State Key Laboratory of Chemical Engineering, Department of Chemical and Biochemical Engineering, Zhejiang University, Hangzhou 310027, China
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Cun-Jin Xu
Cun-Jin Xu
State Key Laboratory of Chemical Engineering, Department of Chemical and Biochemical Engineering, Zhejiang University, Hangzhou 310027, China
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Zhi-Yang Bu
Zhi-Yang Bu
State Key Laboratory of Chemical Engineering, Department of Chemical and Biochemical Engineering, Zhejiang University, Hangzhou 310027, China
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Abstract
A novel acrylonitrile-capped poly(propylene imine) dendrimer (PAN4) was synthesized and characterized with FTIR and 1H-NMR. PAN4 and its precursor (poly(propylene imine) dendrimer (1.0GPPI) were employed to cure bisphenol A epoxy resin (DGEBA), and the nonisothermal reaction kinetics of DGEBA/PAN4 and DGEBA/1.0GPPI was systematically investigated using a differential scanning calorimeter (DSC) in a comparative way. The apparent activation energies determined with the Kissinger method were 59.7 kJ/mol for DGEBA/1.0GPPI and 53.9 kJ/mol for DGEBA/PAN4. Applied the Málek method, it was found that a two-parameter autocatalytic model (SB(m, n)) could well simulate the reaction rates, and further analysis of the reaction rate constants showed PAN4 could cure DGEBA at a greatly decreased rate by a factor a more than ten compared with 1.0GPPI control.
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| Journal of Thermal Analysis and Calorimetry | |
|---|---|
| Language | English |
| Size | A4 |
| Year of Foundation |
1969 |
| Volumes per Year |
1 |
| Issues per Year |
24 |
| Founder | Akadémiai Kiadó |
| Founder's Address |
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. |
| Publisher | Akadémiai Kiadó Springer Nature Switzerland AG |
| Publisher's Address |
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. CH-6330 Cham, Switzerland Gewerbestrasse 11. |
| Responsible Publisher |
Chief Executive Officer, Akadémiai Kiadó |
| ISSN | 1388-6150 (Print) |
| ISSN | 1588-2926 (Online) |
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Temperature dependence of the rate of reaction in thermal analysis
The Arrhenius equation in condensed phase kinetics
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