Geopolymers
Inorganic polymeric new materials
Author:
Authors:
,
,
, and
Ian Harvey J. Arellano
Ian Harvey J. Arellano
STMicroelectronics, 9 Mountain Drive, Light Industry and Science Park II, Calamba City 4027, Laguna, Philippines
Search for other papers by Ian Harvey J. Arellano in
Current site
Google Scholar
PubMed
Search for other papers by Ian Harvey J. Arellano in
Current site
Google Scholar
PubMed
Jeiel G. Guarino
Jeiel G. Guarino
Synthetic Organic Research Laboratory, Institute of Chemistry, University of the Philippines, Diliman, Quezon City 1101, Philippines
Search for other papers by Jeiel G. Guarino in
Current site
Google Scholar
PubMed
Search for other papers by Jeiel G. Guarino in
Current site
Google Scholar
PubMed
Fiona U. Paredes
Fiona U. Paredes
Synthetic Organic Research Laboratory, Institute of Chemistry, University of the Philippines, Diliman, Quezon City 1101, Philippines
Search for other papers by Fiona U. Paredes in
Current site
Google Scholar
PubMed
Search for other papers by Fiona U. Paredes in
Current site
Google Scholar
PubMed
Susan D. Arco
Susan D. Arco
Synthetic Organic Research Laboratory, Institute of Chemistry, University of the Philippines, Diliman, Quezon City 1101, Philippines
Search for other papers by Susan D. Arco in
Current site
Google Scholar
PubMed
Search for other papers by Susan D. Arco in
Current site
Google Scholar
PubMed
Abstract
The thermal stability of the ionic liquids (ILs) 1-n-butyl-3-methylimidazolium bromide, [BMIM]Br, and 1-n-octyl-3-methylimidazolium bromide, [OMIM]Br, was evaluated through thermogravimetry (TG). Long-term isothermal TG studies revealed that both of these ILs exhibit appreciable decomposition even at temperatures significantly lower than the onset decomposition temperature, previously determined from fast scan TG experiments. The long-term TG studies of both the ILs showed linear mass loss as a function of time at each temperature of 10 °C interval in the range 533–573 K over a period of 10 h. The kinetics of isothermal decomposition of ILs was analyzed using pseudo-zero-order rate expression. The activation energies for the isothermal decomposition of [BMIM]Br and [OMIM]Br under nitrogen atmosphere are 219.86 and 212.50 kJ mol−1, respectively. The moisture absorption kinetics of these ILs at 25 °C and 30% relative humidity (RH) and at 85 °C and 85% RH were also studied. Water uptake of ILs exposed at 25 °C/30%RH follows a simple saturation behavior in agreement with Weibull model while that at 85 °C/85%RH fortuitously fit into the Henderson–Pabis model.
ProCite
RefWorks
Reference Manager
BibTeX
Zotero
EndNote
-
1. Holbrey, JD, Seddon, KR 1999 Ionic liquids. Clean Prod Processes 1:223–226.
-
2. Seddon, KR Ionic liquids for clean technologies. J Chem Technol Biotech 1997 68:351–356 .
-
3. Welton, T Room-temperature ionic liquids: solvents for synthesis and catalysis. Chem Rev 1999 99:2071–2073 .
-
4. Wilkes, JS, Levisky, JA, Wilson, RA, Charles, LH 1982 Dialkylimidazolium chloroaluminate melts: a new class of room-temperature ionic liquids for electrochemistry, spectroscopy, and synthesis. Inorg Chem 21:1263–1264 .
-
5. Quinn, BM, Ding, Z, Moulton, R, Bard, AJ 2002 Novel electrochemical studies of ionic liquids. Langmuir 18:1734–1742 .
-
6. Olivier-Bourbigou, H, Magna, L, Morvan, D 2010 Ionic liquids and catalysis: recent progress from knowledge to applications. Appl Catal A Gen 373:1–56 .
-
7. Hapiot, P, Lagrost, C 2008 Electrochemical reactivity in room-temperature ionic liquids. Chem Rev 108:2238–2264 .
-
8. Wang, X, Ohlin, CA, Lu, Q, Fei, ZF, Hu, J, Dyson, PJ 2007 Cytotoxicity of ionic liquids and precursor compounds towards human cell line HeLa. Green Chem 9:1191–1197 .
-
9. Schneider, S, Hawkins, T, Rosander, M, Vaghjiani, G, Chambreau, S, Drake, G 2008 Ionic liquids as hypergolic fuels. Energy Fuels 22:2871–2872 .
-
10. Reichardt, C 2005 Polarity of ionic liquids determined empirically by means of solvatochromic pyridinium N-phenolate betaine dyes. Green Chem 7:339–351.
-
11. Noda, A, Hayamizu, K, Watanabe, M 2001 Pulsed-gradient spin-echo 1H and 19F NMR ionic diffusion coefficient, viscosity, and ionic conductivity of non-chloroaluminate room-temperature ionic liquids. J Phys Chem B 105:4603–4610 .
-
12. Martino, W JF de la Mora Yoshida, Y, Saito, G, Wilkes, J 2006 Surface tension measurements of highly conducting ionic liquids. Green Chem 8:390–397 .
-
13. Earle, MJ, Esperanca, JMSS, Gilea, MA, Lopes, JNC, Rebelo, LPN, Magee, JW, Seddon, KR, Widegren, JA 2006 The distillation and volatility of ionic liquids. Nature 439:831–834 .
-
14. Kamavaram, V, Reddy, RG 2008 Thermal stabilities of di-alkylimidazolium chloride ionic liquids. Int J Therm Sci 47:773–777 .
-
15. Kosmulski, M, Gustafsson, J, Rosenholm, JB 2004 Thermal stability of low temperature ionic liquids revisited. Thermochim Acta 412:47–53 .
-
16. Baranyai, KJ, Deacon, GB, MacFarlane, DR, Pringle, JM, Scott, JL 2004 Thermal degradation of ionic liquids at elevated temperatures. Aust J Chem 57:145–147 .
-
17. Huddleston, JG, Visser, AE, Reichert, WM, Willauer, HD, Broker, GA, Rogers, RD 2001 Characterization and comparison of hydrophilic and hydrophobic room temperature ionic liquids incorporating the imidazolium cation. Green Chem 3:156–164 .
-
18. Seddon, KR, Stark, A, Torrés, MJ 2000 Influence of chloride, water, and organic solvents on the physical properties of ionic liquids. Pure Appl Chem 72:2275–2287 .
-
19. Hanioka, S, Maruyama, T, Sotani, T, Teramoto, M, Matsuyama, H, Nakashima, K, Hanaki, M, Kubota, F, Goto, M 2008 CO2 separation facilitated by task-specific ionic liquids using a supported liquid membrane. J Membr Sci 314:1–4 .
-
20. Zhao, W, He, G, Zhang, L, Ju, J, Dou, H, Nie, F, Li, C, Liu, H 2010 Effect of water in ionic liquid on the separation performance of supported ionic liquid membrane for CO2/N2. J Membr Sci 350:279–285 .
-
21. Ramenskaya, LM, Grishina, EP, Pimenova, AM, Gruzdev, MS 2008 The influence of water on the physicochemical characteristics of 1-butyl-3-methylimidazolium bromide ionic liquid. Russ J Phys Chem A 82:1098–1103 .
-
22. Fox, DM, Gilman, JW HC De Long Trulove, PC TG decomposition kinetics of 1-butyl-2, 3-dimethylimidazolium tetrafluoroborate and the thermal effects of contaminants. J Chem Thermodyn 2005 37:900–905 .
-
23. Obliosca, JM, Arco, SD, Huang, MH 2007 Synthesis and optical properties of 1-Alkyl-3-methylimidazolium lauryl sulfate ionic liquids. J Fluoresc 17:613–618 .
To see the editorial board, please visit the website of Springer Nature.
Manuscript Submission: HERE
For subscription options, please visit the website of Springer Nature.
| Journal of Thermal Analysis and Calorimetry | |
|---|---|
| Language | English |
| Size | A4 |
| Year of Foundation |
1969 |
| Volumes per Year |
1 |
| Issues per Year |
24 |
| Founder | Akadémiai Kiadó |
| Founder's Address |
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. |
| Publisher | Akadémiai Kiadó Springer Nature Switzerland AG |
| Publisher's Address |
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. CH-6330 Cham, Switzerland Gewerbestrasse 11. |
| Responsible Publisher |
Chief Executive Officer, Akadémiai Kiadó |
| ISSN | 1388-6150 (Print) |
| ISSN | 1588-2926 (Online) |
Monthly Content Usage
| Abstract Views | Full Text Views | PDF Downloads | |
|---|---|---|---|
| Apr 2024 | 54 | 0 | 0 |
| May 2024 | 24 | 0 | 0 |
| Jun 2024 | 23 | 0 | 0 |
| Jul 2024 | 53 | 0 | 0 |
| Aug 2024 | 48 | 0 | 0 |
| Sep 2024 | 60 | 0 | 0 |
| Oct 2024 | 13 | 0 | 0 |
Temperature dependence of the rate of reaction in thermal analysis
The Arrhenius equation in condensed phase kinetics
Author:
Copyright Akadémiai Kiadó AKJournals is the trademark of Akadémiai Kiadó's journal publishing business branch.
Powered by PubFactory