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  • 1 Materials and Thermochemistry Laboratory, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian 116023, People's Republic of China
  • | 2 Graduate School of the Chinese Academy of Sciences, Beijing 100049, People's Republic of China
  • | 3 Faculty of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian 116029, People's Republic of China
  • | 4 Université de Haute Alsace, ENSCMu, Lab. LPI-GSEC, 3, Rue A. Werner, 68094, Mulhouse Cedex, France
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Abstract

Two metal-organic frameworks, Ca(2,6-NDC)(DMF) (1) and Mn3(2,6-NDC)3(DMF)4 (2) (where 2,6-NDC = 2,6-naphthalene dicarboxylate and DMF = N,N′-dimethylformamide) have been solvothermally synthesized under optimized conditions and characterized by X-ray powder diffraction, elemental analysis, FT-IR spectroscopy, and TG analysis. The thermal decomposition characteristics were investigated under air atmosphere from 300 to 1,170 K (for 1) and from 300 to 971 K (for 2). The molar heat capacities were measured from 198 to 548 K (for 1) and from 198 to 448 K (for 2) by temperature modulated differential scanning calorimetry (TMDSC) for the first time. The fundamental thermodynamic parameters such as entropy and enthalpy variations with temperature were calculated based on the experimentally determined molar heat capacities.

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  • Impact Factor (2019): 2.731
  • Scimago Journal Rank (2019): 0.415
  • SJR Hirsch-Index (2019): 87
  • SJR Quartile Score (2019): Q3 Condensed Matter Physics
  • SJR Quartile Score (2019): Q3 Physical and Theoretical Chemistry
  • Impact Factor (2018): 2.471
  • Scimago Journal Rank (2018): 0.634
  • SJR Hirsch-Index (2018): 78
  • SJR Quartile Score (2018): Q2 Condensed Matter Physics
  • SJR Quartile Score (2018): Q2 Physical and Theoretical Chemistry

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
4
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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