Abstract
A complex of Erbium perchloric acid coordinated with l-aspartic acid and imidazole, Er2(Asp)2(Im)8(ClO4)6·10H2O was synthesized for the first time. It was characterized by IR and elements analysis. The heat capacity and thermodynamic properties of the complex were studied with an adiabatic calorimeter (AC) from 80 to 390 K and differential scanning calorimetry (DSC) from 100 to 300 K. Glass transition and phase transition were discovered at 220.45 and 246.15 K, respectively. The glass transition was interpreted as a freezing-in phenomenon of the reorientational motion of ClO4− ions and the phase transition was attributed to the orientational order/disorder process of ClO4− ions. The thermodynamic functions [HT − H298.15] and [ST − S298.15] were derived in the temperature range from 80 to 390 K with temperature interval of 5 K. Thermal decomposition behavior of the complex in nitrogen atmosphere was studied by thermogravimetric (TG) analysis and differential scanning calorimetry (DSC).
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1. Anghileri, LJ 1975 On the antitumor activity of gallium and lanthanides. Arzneim Forsch 25:793–795.
-
2. McCarthy GJ . Rare earths in modern science and technology, vol 2. New York: Plenum press; 1980; p. 25–105.
-
3. Sudhindra, NM, Joshi, GK, Bhutra, MP 1982 Syntheses and absorption spectral studies of Praseodymium (II) and Neodymium (II) complexes with amino acids. Indian J Chem 21A:275–278.
-
4. Xu, H, Chen, L 2003 Study on the complex site of l-tyrosine with rare-earth element Eu3+. Spectrochim Acta A 59:657–662 .
-
5. Zhang, H, Feng, J, Zhu, W-f 2000 Rare-earth element distribution characteristics of biological chains in rare-earth element-high background regions and their implications. Biol Trace Elem Res 73:19–27 .
-
6. Glowiak, T, Legendziewicz, J, Huskowska, E, Gawryszewska, P 1996 Ligand chirality effect on the structure and its spectroscopic consequences in [Ln2(Ala)4(H2O)8](ClO4)6. Polyhedron 15:2939–2947 .
-
7. Liu, B-P, Lv, X-C, Tan, Z-C, Zhang, Z-H, Shi, Q, Yang, L-N, Xing, J, Sun, L-X, Zhang, T 2007 Molar heat capacity and thermodynamic properties of crystalline Ho(Asp)Cl2·6H2O. J Therm Anal Calorim 89:283–287 .
-
8. Liu, B-P, Tan, Z-C, Lu, J-l, Lan, X-Z, Sun, L-X, Xu, F, Yu, P, Xing, J 2003 Low-temperature heat capacity and thermodynamic properties of crystalline [RE (Gly)3(H2O)2]Cl3·2H2O (RE = Pr, Nd, Gly = Glycine). Thermochim Acta 397:67–73 .
-
9. Qi, Y-n, Zhang, J, Qiu, S-j, Sun, L-x, Xu, F, Zhu, M et al. 2009 Thermal stability, decomposition and glass transition behavior of PANI/NiO composites. J Therm Anal Calorim 98:533–537 .
-
10. Song, L-F, Jiang, C-H, Zhang, J, Sun, L-X, Xu, F et al. 2010 Heat capacities and thermodynamic properties of a novel mixed-ligands MOFs. J Therm Anal Calorim 100:679–684 .
-
11. Song, L-F, Jiang, C-H, Zhang, J, Sun, L-X, Xu, F et al. 2010 Heat capacities and thermodynamic properties of MgBTC. J Therm Anal Calorim 101:365–370 .
-
12. Nakamoto, K 1986 Infrared spectra of inorganic and coordination compounds 4 Wiley New York 258.
-
13. Wayda, AL, Kaplan, ML 1990 Mixed ligand imidazole complexes of organolanthanides. Polyhedron 9:751–756 .
-
14. Tan, Z-C, Liu, B-P, Yan, J-B, Sun, L-X 2003 A fully automated adiabatic calorimeter workable between 80 and 400 K. Comput Appl Chem 20:264–268 (in Chinese).
-
15. Nan, Z-D, Tan, Z-C 2004 Low-temperature heat capacities and derived thermodynamic functions of cyclohexane. J Therm Anal Calorim 76:955–963 .
-
16. Tong, B, Tan, Z-C, Lv, X-C, Sun, L-X, Xu, F, Shi, Q, Li, Y-S 2007 Low-temperature heat capacities and thermodynamic properties of 2,2-dimethyl-1,3-propanediol. J Therm Anal Calorim 901:217–221 .
-
17. Lv, X-C, Gao, X-H, Tan, Z-C 2008 Molar heat capacity and thermodynamic properties of 1,2-cyclohexane dicarboxylic anhydride [C8H10O3]. J Therm Anal Calorim 92:523–527 .
-
18. Tan, Z-C, Sun, G-Y, Yin, A-X, Wang, W-B, Ye, J-C, Zhou, L-X 1995 An adiabatic low-temperature calorimeter for heat capacity measurement of small samples. J Therm Anal 45:59–67 .
-
19. Donald, GA 1993 Thermodynamic properties of synthetic sapphire standard reference material 720 and the effect of temperature-scale difference on thermodynamic properties. J Phys Chem Ref Data 22:1441–1452 .
-
20. Anna, MM, Edward, M, Hetmańczyk, L, Natkaniec, I, Ściesińska, E, Ściesiński, J, Wróbel, S 2005 Phase transition, molecular motions, structural changes and low-frequency vibrations in [Cu(NH3)5](ClO4)2. Chem Phys 317:188–197 .
-
21. Hangam, SS, Westrumj, ER 1960 Heat capacities and thermodynamic properties of globular molecules. I. Adamantane and hexamethylenetetramine. Thermodyn Prop Globul Mol 64:1547–1551.
-
22. Yukawa, Y, Igarashi, S, Masuda, Y, Oguni, M 2002 Phase transition and glass transition concerning configurational order/disorder of ions in crystalline (TMA)2[Sr{Ni(pro)2}6](ClO4)4 and (TMA)[Sm{Ni(pro)2}6](ClO4)4. J Mol Struct 605:277–290 .
-
23. Udowenko, AA, Laptash, NM, Maslennikova, IG 2003 Orientation disorder in ammonium elpasolites: crystal structures of (NH4)3AlF6,(NH4)3TiOF5 and (NH4)3FeF6. J Fluor Chem 124:5–15 .
-
24. Meng, J-X, Li, J-H, Xie, G-W, Huang, W-G, Liang, H-Z 2002 Lanthanide ion luminescence probe: low temperature phase transition of EuS4N complex. Spectrosc Spectr Anal 22:562–565 (in Chinese).
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| Journal of Thermal Analysis and Calorimetry | |
|---|---|
| Language | English |
| Size | A4 |
| Year of Foundation |
1969 |
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| Founder | Akadémiai Kiadó |
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