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  • 1 Department of Chemistry, Faculty of Science, Golestan University, Gorgan, Iran
  • | 2 UMR CNRS 6521, Université de Bretagne Occidentale, BP 809, 29285, Brest Cedex, France
  • | 3 Department of Chemistry, The University of Burdwan, Burdwan, West Bengal, India
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Abstract

New 1D-chain copper(I) complex [Cu2(μ-(3,4,5-MeO-ba)2bn)(μ-I)2]n (1), where (3,4,5-MeO-ba)2bn = N,N′-bis(3,4-dimethoxybenzylidene)-butane-1,4-diamine, involving a new bidentate Schiff-base containing a flexible spacer (=N–C–C–C–C–N=) has been synthesized and characterized by elemental analyses (CHN) and FT-IR spectroscopy. The crystal structure of 1 was determined from single-crystal X-ray diffraction analyses and shows the (3,4,5-MeO-ba)2en acts as a bridging ligand with the nitrogen atoms of the two imine functions and leading to the dinuclear [Cu2((μ-(3,4,5-MeO-ba)2en)] groups. Such dinuclear [Cu2((μ-(3,4,5-MeO-ba)2en)] groups are bridged by two iodine anions [(μ-I)2] to form a neutral 1D-chain copper(I) iodide coordination polymer. The coordination polyhedron about the copper(I) center in 1 is best described as a distorted trigonal planar. Thermogravimetric analyses reveal the thermal stability and decomposition pattern of 1.

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  • SJR Quartile Score (2018): Q2 Condensed Matter Physics
  • SJR Quartile Score (2018): Q2 Physical and Theoretical Chemistry

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
4
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)