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  • 1 Department of Chemistry and Forensic Sciences, University of Technology, Sydney, PO Box 123, Broadway, NSW, 2007, Australia
  • | 2 Faculty of Science, University of Technology, Sydney, PO Box 123, Broadway, NSW, 2007, Australia
  • | 3 Australian Museum, 6 College Street, Sydney, NSW, 2010, Australia
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Abstract

The potential of thermogravimetric analysis (TG) as a tool for the characterisation of ochre paint used in indigenous Australian bark paintings has been investigated. TG has been combined with differential scanning calorimetry (DSC) and mass spectrometry (MS) to identify and quantify the main inorganic and organic components present in the paints. The results obtained were supported by comparison with infrared spectra and XRD data obtained for the same specimens. The potential of thermal methods for the characterisation ochres has been demonstrated, with subtle differences between small samples being able to be identified.

  • 1. Perkins, H, West, M, eds. One sun one moon: aboriginal art in Australia. Sydney: Art Gallery of New South Wales; 2007.

  • 2. Creagh, DC, Kubik, ME, Sterns, M. One the feasibility of establishing the provenance of Australian Aboriginal artefacts using synchrotron radiation X-ray diffraction and proton induced X-ray emission. Nucl Instrum Methods Phys Res A. 2007;580:721724. .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 3. O’Neill, PM, Creagh, DC, Sterns, M. Studies of the composition of pigments used traditionally in Australian Aboriginal bark paintings. Radiat Phys Chem. 2004;71:841842. .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 4. Creagh, DC. The characterisation of artefacts of cultural heritage significance using physical techniques. Radiat Phys Chem. 2005;74:426442. .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 5. Creagh, D, Lee, A, Otieno-Alego, V, Kubik, M. Recent and future developments in the use of radiation for the study of objects of cultural heritage significance. Radiat Phys Chem. 2009;78:367374. .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 6. Creagh, DC, Otieno-Alego, V. The use of radiation for the study of material of cultural heritage significance. Nucl Instrum Methods Phys Res B. 2004;213:670676. .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 7. Madejova, J. FTIR techniques in clay mineral studies. Vib Spectrosc. 2003;31:110. .

  • 8. Genestar, C, Pons, C. Earth pigments in painting: characterisation and differentiation by means of FTIR spectroscopy and SEM-EDS microanalysis. Anal Bioanal Chem. 2005;382:269274. .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 9. Ip, KH, Stuart, BH, Ray, AS, Thomas, PS. A spectroscopic investigation of the weathering of a heritage Sydney sandstone. Spectrochim Acta A. 2008;71:10321035. .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 10. Cornell, RM, Schwertmann, U. The iron oxides: structures, properties, reactions, occurrences and uses. Weinheim: Wiley-VCH; 2003.

  • 11. Bertraux, J, Frohlich, F, Ildefonse, P. Multicomponent analysis of FTIR spectra: quantification of amorphous and crystallized mineral phases in synthetic and natural sediments. J Sediment Res. 1998;68:440447.

    • Search Google Scholar
    • Export Citation
  • 12. Guo, Y, Bustin, RM. FTIR spectroscopy and reflectance of modern charcoals and fungal decayed woods: implications for studies of inertinite in coals. Int J Coal Geol. 1998;37:2953. .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 13. Genestar Julia, C, Pons Bonafe, C. The use of natural earths in picture: study and differentiation by thermal analysis. Thermochim Acta. 2004;413:185192. .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 14. Frost, RL, Ding, Z, Ruan, HD. Thermal analysis of goethite: relevance to Australian indigenous art. J Therm Anal Calorim. 2003;71:783797. .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 15. Dweck, J. Qualitative and quantitative characterization of Brazilian natural and organophilic clays by thermal analysis. J Therm Anal Calorim. 2008;92:129135. .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 16. Onishi, A, Thomas, PS, Stuart, BH, Guerbois, JP, Forbes, S. TG-MS characterisation of pig bone in an inert atmosphere. J Therm Anal Calorim. 2007;88:405409. .

    • Crossref
    • Search Google Scholar
    • Export Citation

Manuscript Submission: HERE

  • Impact Factor (2019): 2.731
  • Scimago Journal Rank (2019): 0.415
  • SJR Hirsch-Index (2019): 87
  • SJR Quartile Score (2019): Q3 Condensed Matter Physics
  • SJR Quartile Score (2019): Q3 Physical and Theoretical Chemistry
  • Impact Factor (2018): 2.471
  • Scimago Journal Rank (2018): 0.634
  • SJR Hirsch-Index (2018): 78
  • SJR Quartile Score (2018): Q2 Condensed Matter Physics
  • SJR Quartile Score (2018): Q2 Physical and Theoretical Chemistry

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
4
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)