Geopolymers
Inorganic polymeric new materials
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N. M. Rendtorff
N. M. Rendtorff
Centro de Tecnología de Recursos Minerales y Cerámica (CETMIC): (CIC-CONICET-CCT La Plata), Camino Centenario y 506, C.C.49, M. B. Gonnet, B1897ZCA, Buenos Aires, Argentina
Facultad de Ciencias Exactas, Universidad Nacional de La Plata, UNLP, Buenos Aires, Argentina
CIC-PBA, Buenos Aires, Argentina
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Facultad de Ciencias Exactas, Universidad Nacional de La Plata, UNLP, Buenos Aires, Argentina
CIC-PBA, Buenos Aires, Argentina
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L. B. Garrido
L. B. Garrido
Centro de Tecnología de Recursos Minerales y Cerámica (CETMIC): (CIC-CONICET-CCT La Plata), Camino Centenario y 506, C.C.49, M. B. Gonnet, B1897ZCA, Buenos Aires, Argentina
Facultad de Ciencias Exactas, Universidad Nacional de La Plata, UNLP, Buenos Aires, Argentina
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Facultad de Ciencias Exactas, Universidad Nacional de La Plata, UNLP, Buenos Aires, Argentina
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E. F. Aglietti
E. F. Aglietti
Centro de Tecnología de Recursos Minerales y Cerámica (CETMIC): (CIC-CONICET-CCT La Plata), Camino Centenario y 506, C.C.49, M. B. Gonnet, B1897ZCA, Buenos Aires, Argentina
Facultad de Ciencias Exactas, Universidad Nacional de La Plata, UNLP, Buenos Aires, Argentina
CONICET, Buenos Aires, Argentina
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Facultad de Ciencias Exactas, Universidad Nacional de La Plata, UNLP, Buenos Aires, Argentina
CONICET, Buenos Aires, Argentina
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Abstract
Mullite–Zirconia–Zircon composites have proved to be suitable for high-temperature structural applications, with good mechanical and fracture properties and good thermal shock resistance. In this paper, the special dilatometric behavior of a series of Mullite–Zirconia–Zircon (3–40 vol.% ZrO2) composites is evaluated and compared with that of a pure Zircon material and explained in terms of the high Zirconia linear thermal expansion coefficient (α) and Zirconia martensitic transformation. Linear thermal expansion (α) up to 1273 K is studied and correlated with the phase composition of the composites; a linear correlation was found with the m-ZrO2 content evaluated with the Rietveld method. Zirconia (m-ZrO2) dispersed grains containing ceramics material showed a hysteresis in a reversible dilatometric curve (DC). The martensitic transformation temperatures could be evaluated and then compared with the endothermic and exothermic peaks temperatures obtained from the differential thermal analysis (DTA). Furthermore, the hysteresis area was correlated with m-ZrO2 content, where composites with less than 10 vol.% ZrO2 did not show this behavior, and from this content up to 40 vol.% of ZrO2 a linear increase of the hysteresis area was found.
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| Journal of Thermal Analysis and Calorimetry | |
|---|---|
| Language | English |
| Size | A4 |
| Year of Foundation |
1969 |
| Volumes per Year |
1 |
| Issues per Year |
24 |
| Founder | Akadémiai Kiadó |
| Founder's Address |
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. |
| Publisher | Akadémiai Kiadó Springer Nature Switzerland AG |
| Publisher's Address |
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. CH-6330 Cham, Switzerland Gewerbestrasse 11. |
| Responsible Publisher |
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| ISSN | 1388-6150 (Print) |
| ISSN | 1588-2926 (Online) |
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Temperature dependence of the rate of reaction in thermal analysis
The Arrhenius equation in condensed phase kinetics
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