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  • 1 Nanoscience and Technology Division, Defence Materials and Stores Research and Development Establishment (DMSRDE), DMSRDE Post Office, G. T. Road, Kanpur 208013, India
  • | 2 University Department of Chemistry, Magadh University, Bodh-Gaya, India
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Abstract

The ligand [2-(1,2,3,4-thiatriazole-5-yliminomethyl)-phenol] (L) is a schiff base derived from condensation reaction of 1,2,3,4-thiatriazole-5-ylamine and Salicylaldehyde. Synthesis of the ligand (L) and the complex [Cu(II)(L)2]·2H2O have been studied in our previous work (Bharti et al., Asian J Chem 23(2):773–776, 2011). Thermal decomposition behavior of synthesized Cu(II) complex has been investigated by thermo gravimetric (TG) analysis at heating rate of 10 °C min−1 under nitrogen atmosphere. The mechanism of decomposition of Cu(II) complex has been established from TG data. Kinetic parameters such as order of reaction (n), activation energy (Ea), frequency factor (Z) and entropy of activation (ΔS) were calculated by using Freeman and Carroll (J Phys Chem 62:394–397, 1958) as well as Doyle’s methods as modified by Zsako (J Phys Chem 72(7):2406–2411, 1968).

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  • Impact Factor (2019): 2.731
  • Scimago Journal Rank (2019): 0.415
  • SJR Hirsch-Index (2019): 87
  • SJR Quartile Score (2019): Q3 Condensed Matter Physics
  • SJR Quartile Score (2019): Q3 Physical and Theoretical Chemistry
  • Impact Factor (2018): 2.471
  • Scimago Journal Rank (2018): 0.634
  • SJR Hirsch-Index (2018): 78
  • SJR Quartile Score (2018): Q2 Condensed Matter Physics
  • SJR Quartile Score (2018): Q2 Physical and Theoretical Chemistry

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
4
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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