Authors:
,
,
, and
G. Madhurambal
G. Madhurambal
Department of Chemistry, A D M College for Women, Nagapattinam, Tamil Nadu, India
Search for other papers by G. Madhurambal in
Current site
Google Scholar
PubMed
Search for other papers by G. Madhurambal in
Current site
Google Scholar
PubMed
M. Mariappan
M. Mariappan
Department of Chemistry, RVS College of Engineering and Technology, Karaikal, Pondicherry, India
Search for other papers by M. Mariappan in
Current site
Google Scholar
PubMed
Search for other papers by M. Mariappan in
Current site
Google Scholar
PubMed
B. Ravindran
B. Ravindran
Department of Physics, EGS Pillay Engineering College, Nagapattinam, India
Search for other papers by B. Ravindran in
Current site
Google Scholar
PubMed
Search for other papers by B. Ravindran in
Current site
Google Scholar
PubMed
S. C. Mojumdar
S. C. Mojumdar
Department of Chemical Technologies and Environment, Faculty of Industrial Technologies, Trencin University of A. Dubcek, Púchov, Slovakia
Department of Chemical and Biochemical Engineering, The University of Western Ontario, London, ON, N6A 5B9, Canada
Search for other papers by S. C. Mojumdar in
Current site
Google Scholar
PubMed
Department of Chemical and Biochemical Engineering, The University of Western Ontario, London, ON, N6A 5B9, Canada
Search for other papers by S. C. Mojumdar in
Current site
Google Scholar
PubMed
Abstract
Mixed crystals of various proportions of urea thiourea were grown by slow evaporation of aqueous solution at room temperature. The bright and transparent crystals obtained were characterized using thermogravimetry–differential thermal analysis (TG–DTA) and FTIR spectroscopic analyses. A fitting decomposition pattern for the title compound was formulated on the TG curve which shows a two-stage mass loss between 175 and 750 °C. In this temperature range, DTA curves show exothermic peaks supporting the formulated decomposition pattern. The FTIR spectra show the characteristic absorption, vibration frequencies due to urea thiourea. Detailed structural analysis of the compound is under progress.
ProCite
RefWorks
Reference Manager
BibTeX
Zotero
EndNote
-
1. Mojumdar, SC, Madhurambal, G, Saleh, MT. A study on synthesis and thermal, spectral and biological properties of carboxylato-Mg(II) and carboxylate-Cu(II) complexes with bioactive ligands. J Therm Anal Calorim. 2005;81:205–210. .
-
2. Mojumdar, SC, Melnik, M, Jona, E. Thermoanalytical investigation of magnesium(II) complexes with pyridine as bio-active ligand. J Therm Anal Calorim. 1999;56:541–546. .
-
3. Madhurambal, G, Ramasamy, P, Anbusrinivasan, P, Vasudevan, G, Kavitha, S, Mojumdar, SC. Growth and characterization studies of 2-bromo-4′-chloro-acetophenone (BCAP) crystals. J Therm Anal Calorim. 2008;94:59–62. .
-
4. Kubranova, M, Jona, E, Rudinska, E, Nemcekova, K, Ondrusova, D, Pajtasova, M. Thermal properties of Co-, Ni- and Cu-exchanged montmorillonite with 3-hydroxypyridine. J Therm Anal Calorim. 2003;74:251–257. .
-
5. Meenakshisundarm, SP, Parthiban, S, Madhurambal, G, Mojumdar, SC. Effect of chelating agent (1, 10-phenanthroline) on potassium hydrogen phthalate crystals. J Therm Anal Calorim. 2008;94:21–25. .
-
6. Boomadevi, S, Dhanasekaran, R, Ramasamy, P. Investigation on nucleation kinetics of urea crystals from methanol. Cryst Res Technol. 2002;37:159–168. .
-
7. Shannon, JJ, Haris, KDM. Phase transitions involving re-ordering of the guest molecules in solid organic compound: heptonic anhydride/urea. J Chem Soc. 1996;92:267–272.
-
8. Haris, KDM, Thomas, JM. Structural aspects of urea inclusion compounds and their investigation by X-ray diffraction study. J Chem Soc. 1990;86:2985–2996.
-
9. Madhurambal, G, Ramasamy, P, Anbusrinivasan, P, Suganthi, M, Vasudevan, G, Mojumdar, SC. The growth and characterization of 2, 4 dinitro phenyl hydrazone of benzophenone and mixed crystals. J Therm Anal Calorim. 2008;94:45–51. .
-
10. Rajasekaran, R, Rajendran, KV. Investigation on nucleation of cadmium thiourea chloride single crystals. Mater Chem Phys. 2003;82:273–280. .
-
11. Kumar, K, Ramamurthy, K. A novel growth method for zinc thiourea sulphate single crystals. Cryst Res Technol. 2006;41:217–220. .
-
12. Sangwal, K, Mielniczek-Brzoska, E. Effect of impurities on metastable zone width for the growth of ammonium oxalate monohydrate crystals from aqueous solutions. J Cryst Growth. 2004;267:662–675. .
-
13. George, AR, Harris, KDM. Computational investigation of surface structural relaxation in crystalline urea. J Mater Chem. 1995;5:133–140. .
-
14. Boomadevi, S, Dhanasekaran, R, Ramasamy, P. Investigation on nucleation kinetics of urea crystals from methanol. Cryst Res Technol. 2002;37:159–168. .
-
15. Verma, S, Singh, MK, Wadhavan, VK, Suresh, CH. Growth morphology of zinctris(thiourea)sulphate crystals. J Phys. 2000;54:879–884.
-
16. Gupte, SS, Desai, CF. Vickers hardness anisotropy and slip system in zinc(tris)thioureasulphate crystals. Cryst Res Technol. 1999;34:1329–1332. .
-
17. Krishnan, H, Justin, C, Jerome, S. Growth and characterization of novel ferroelectric urea-succinic acid single crystals. J Cryst Growth. 2008;310:3313–3317. .
-
18. Varshney, KG, Agrawal, A, Mojumdar, SC. Pectin based cerium(IV) and thorium(IV) phosphates as novel hybrid fibrous ion exchangers synthesis, characterization and thermal behaviour. J Therm Anal Calorim. 2005;81:183–189. .
-
19. Zaitseva, NP, Rashkovich, LN, Bogatyreva, SV. 1995 Stability of KH2PO4 and K(H, D)2PO4solutions at fast crystal growth rates. J Cryst Growth. 148:276–282. .
-
20. Udayalakshmi, K, Ramamurthi, K. 2006 Optical, mechanical and thermal properties of p-bromoacetanilide. Cryst Res Technol. 41:795–799. .
-
21. Hall, SR, Kolinsky, PV, Jones, R, Allen, S, Gordon, P, Bothwell, B, Bloor, D, Norman, PA, Hursthouse, M, Karaulov, A, Baldwin, J, Goodyear, M, Bishop, D. Polymorphism and nonlinear optical activity in organic crystals. J Cryst Growth. 1986;79:745–751. .
-
22. Nyvlt, J, Rychly, R, Gottfried, J, Wurzelova, J. Metastable zone-width of some aqueous solutions. J Cryst Growth. 1970;6:151–162. .
-
23. Kurtz, SK, Perry, TT. A powder technique for the evaluation of nonlinear optical materials. J Appl Phys. 1968;39:3798–3813. .
-
24. Madhurambal, G, Mojumdar, SC, Hariharan, S, Ramasamy, P. TG, DTC, FT-IR and Raman spectral analysis of Zna/Mgb ammonium sulfate mixed crystals. J Therm Anal Calorim. 2004;78:125–133. .
-
25. Ushasree, PM, Jayavel, R, Ramasamy, P. Growth and characterization of phosphate mixed ZTS single crystals. Mater Sci Eng B. 1999;65:153–158. .
-
26. Bhagavannarayana, G, Choubey, A, Shubin, YV, Lal, K. Study of point defects in as-grown and annealed bismuth germanate single crystals. J Appl Cryst. 2005;38:448–454. .
-
27. Jayalakshmi, D, Kumar, J. Growth and characterization of bis thiourea zinc acetate. Cryst Res Technol. 2006;41:37–40. .
-
28. Anie S , Cyriac M, Ittyachen MA. Growth and characterization of a new metal organic crystal: Potassium thiourea bromide. Mater Lett. 2001;49:299–302.
-
29. Shahil, S, Stella, S, P, Mythili. Growth and characterization of pure and doped cadmium thiourea acetate single crystals. J Cryst Growth. 2008;310:2555–2562. .
-
30. Bhagavannarayana, G, Kushwaha, SK, Parthiban, S. Influence of inorganic and organic additives on the crystal growth, properties and crystalline perfection of tris (thiourea) copper (I) chloride crystals. J Cryst Growth. 2008;310:2575–2583. .
To see the editorial board, please visit the website of Springer Nature.
Manuscript Submission: HERE
For subscription options, please visit the website of Springer Nature.
| Journal of Thermal Analysis and Calorimetry | |
|---|---|
| Language | English |
| Size | A4 |
| Year of Foundation |
1969 |
| Volumes per Year |
1 |
| Issues per Year |
24 |
| Founder | Akadémiai Kiadó |
| Founder's Address |
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. |
| Publisher | Akadémiai Kiadó Springer Nature Switzerland AG |
| Publisher's Address |
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. CH-6330 Cham, Switzerland Gewerbestrasse 11. |
| Responsible Publisher |
Chief Executive Officer, Akadémiai Kiadó |
| ISSN | 1388-6150 (Print) |
| ISSN | 1588-2926 (Online) |
Monthly Content Usage
| Abstract Views | Full Text Views | PDF Downloads | |
|---|---|---|---|
| Oct 2024 | 135 | 0 | 0 |
| Nov 2024 | 39 | 0 | 0 |
| Dec 2024 | 46 | 0 | 0 |
| Jan 2025 | 78 | 1 | 1 |
| Feb 2025 | 51 | 0 | 0 |
| Mar 2025 | 32 | 0 | 0 |
| Apr 2025 | 0 | 0 | 0 |
Author:
Copyright Akadémiai Kiadó AKJournals is the trademark of Akadémiai Kiadó's journal publishing business branch.
Powered by PubFactory