Authors:
S. Šnircová Department of Inorganic Materials and Environmental Engineering, Faculty of Industrial Technologies, University of Trenčín, SK-02032, Púchov, Slovakia

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E. Jóna Department of Inorganic Materials and Environmental Engineering, Faculty of Industrial Technologies, University of Trenčín, SK-02032, Púchov, Slovakia

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R. Janík Department of Inorganic Materials and Environmental Engineering, Faculty of Industrial Technologies, University of Trenčín, SK-02032, Púchov, Slovakia

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Ľ. Lajdová Department of Inorganic Materials and Environmental Engineering, Faculty of Industrial Technologies, University of Trenčín, SK-02032, Púchov, Slovakia

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S. Lendvayová Department of Inorganic Materials and Environmental Engineering, Faculty of Industrial Technologies, University of Trenčín, SK-02032, Púchov, Slovakia

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M. Loduhová Department of Inorganic Materials and Environmental Engineering, Faculty of Industrial Technologies, University of Trenčín, SK-02032, Púchov, Slovakia

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V. Šutinská Department of Inorganic Materials and Environmental Engineering, Faculty of Industrial Technologies, University of Trenčín, SK-02032, Púchov, Slovakia

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R. Durný Slovak Institute of Metrology, Karloveská 63, Bratislava, Slovakia

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P. Lizák Department of Industrial Design, Faculty of Industrial Technologies, Trencin University of A. Dubcek, Trencin, Slovakia

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S. C. Mojumdar Department of Inorganic Materials and Environmental Engineering, Faculty of Industrial Technologies, University of Trenčín, SK-02032, Púchov, Slovakia
University of New Brunswick, Fredericton, NB, E3B 5A3, Canada
Department of Chemical and Biochemical Engineering, The University of Western Ontario, London, ON, N6A 5B9, Canada

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Abstract

The influence of different steric properties of ethylenediamine (EDA), trimethylenediamine (TrMeEDA) and tetraethylenediamine (TeMeEDA) on the type of interactions with Co(II)-exchanged montmorillonite and thermal decomposition of these materials were studied. The results of X-ray diffraction (XRD), thermogravimetry (TG), derivative thermogravimetry (DTG) and spectral analysis shows that the studied ethylenediamines are intercalated into the interlayer space of montmorillonite. Thermal decomposition at 20–500 °C of studied samples with EDA proceeds in three steps (the release of chemosorbed amines, coordinated EDA and dehydroxylation) while the sample with TrMeEDA and TeMeEDA in five steps (also release the protonated forms). The effect of different steric properties of individual diamines is evident.

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  • 13. Sawant, SY, Verenkar, VMS, Mojumdar, SC. Preparation, thermal, XRD, chemical and FT-IR spectral analysis of NiMn2O4 nanoparticles and respective precursor. J Therm Anal Calorim. 2007;90:669672. .

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  • 14. Porob, RA, Khan, SZ, Mojumdar, SC, Verenkar, VMS. Synthesis, TG, SDC and infrared spectral study of NiMn2(C4H4O4)3·6N2H4—A precursor for NiMn2O4 nanoparticles. J Therm Anal Calorim. 2006;86:605608. .

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  • 15. Mojumdar, SC, Varshney, KG, Agrawal, A. Hybrid fibrous ion exchange materials: past, present and future. Res J Chem Environ. 2006;10:89103.

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  • 16. Doval, M, Palou, M, Mojumdar, SC. Hydration behaviour of C2S and C2AS nanomaterials, synthesized by sol-gel method. J Therm Anal Calorim. 2006;86:595599. .

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  • 17. Tiwari, NR, Rathore, A, Prabhune, A, Kulkarni, SK. Gold nanoparticles for colorimetric detection of hydrolysis of antibiotics by penicillin G acylase. Adv Biosci Biotechnol. 2010;1:322329. .

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  • 18. Varshney, G, Agrawal, A, Mojumdar, SC. Pyridine based cerium(IV) phosphate hybrid fibrous ion exchanger: synthesis, characterization and thermal behaviour. J Therm Anal Calorim. 2007;90:731734. .

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  • 19. Mojumdar, SC, Melnik, M, Jona, E. Thermal and spectral properties of Mg(II) and Cu(II) complexes with heterocyclic N-donor ligands. J Anal Appl Pyrol. 2000;53:149160. .

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  • 21. Mojumdar, SC, Sain, M, Prasad, RC, Sun, L, Venart, JES. Selected thermoanalytical methods and their applications from medicine to construction. J Therm Anal Calorim. 2007;60:653662. .

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  • 22. Meenakshisundarm, SP, Parthiban, S, Madhurambal, G, Mojumdar, SC. Effect of chelating agent (1, 10-phenanthroline) on potassium hydrogen phthalate crystals. J Therm Anal Calorim. 2008;94:2125. .

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  • 23. Rejitha, KS, Mathew, S. Investigations on the thermal behavior of hexaamminenickel(II) sulphate using TG-MS and TR-XRD. Glob J Anal Chem. 2010;1: 1 100108.

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  • 24. Ondrusova, D, Jona, E, Simon, P. Thermal properties of N-ethyl-N-phenyldithiocarbamates and their influence on the kinetics of cure. J Therm Anal Calorim. 2002;67:147152. .

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  • 25. Madhurambal, G, Ramasamy, P, Anbusrinivasan, P, Vasudevan, G, Kavitha, S, Mojumdar, SC. Growth and characterization studies of 2-bromo-4′-chloro-acetophenone (BCAP) crystals. J Therm Anal Calorim. 2008;94:5962. .

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  • 26. Ukraintseva, EA, Logvinenko, VA, Soldatov, DV, Chingina, TA. Thermal dissociation processes for clathrates [CuPy4(NO3)2]·2G (G=tetrahydrofurane, chloroform). J Therm Anal Calorim. 2004;75:337345. .

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  • 27. Raileanu, M, Todan, L, Crisan, M, Braileanu, A, Rusu, A, Bradu, C, Carpov, A, Zaharescu, M. Sol-gel materials with pesticide deliveryproperties. J Environ Prot. 2010;1:302313. .

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  • 28. Varshney, KG, Agrawal, A, Mojumdar, SC. Pectin based cerium(IV) and thorium(IV) phosphates as novel hybrid fibrous ion exchangers synthesis, characterization and thermal behaviour. J Therm Anal Calorim. 2005;81:183189. .

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  • 29. Mojumdar, SC, Šimon, P, Krutošíková, A. [1]Benzofuro[3, 2-c]pyridine: synthesis and coordination reactions. J Therm Anal Calorim. 2009;96:103109. .

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  • 30. Jona, E, Rudinska, E, Sapietova, M, Pajtasova, M, Ondrusova, D, Jorik, V, Mojumdar, SC. Interaction of pyridine derivatives into the interlayer spaces of Cu(II)-montmorillonites. Res J Chem Environ. 2005;9:4143.

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  • 31. Mojumdar, SC, Miklovic, J, Krutosikova, A, Valigura, D, Stewart, JM. Furopyridines and furopyridine-Ni(II) complexes—Synthesis, thermal and spectral characterization. J Therm Anal Calorim. 2005;81:211215. .

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  • 32. Vasudevan, G, AnbuSrinivasan, P, Madhurambal, G, Mojumdar, SC. Thermal analysis, effect of dopants, spectral characterisation and growth aspects of KAP crystals. J Therm Anal Calorim. 2009;96:99102. .

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  • 33. Jóna, E, Kubranová, M, Mojumdar, SC, Kopcová, M. Interactions of Co(II)-exchanged montmorillonite with pyridine, 4-methyl- and ethylpyridine. Chem Pap. 2002;56:295298.

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  • 34. Jóna, E, Rudinská, G, Sapietová, M, Pavlík, V, Drábik, M, Mojumdar, SC. Interactions of different heterocyclic compounds with monionic forms of montmorillonite: thermal, IR- spectral and X-ray studies of Ni(II)-montmorillonite with 3-R-and 2-R-pyridines (R=CH3, Cl, NH2). J Therm Anal Calorim. 2007;90:687691. .

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  • 35. Jóna, E, Rudinská, E, Kubranová, M, Pajtašová, M, Jorík, V. Intercalation of pyridine derivatives and complex formation in the interlayer space of Cu(II)-montmorillonite. Chem Pap. 2005;59:248250.

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  • 36. Khaorapapong, N, Kuroda, K, Hashizumi, H, Ogawa, M. Solid state intercalation of 4, 4′-bipyridine and 1,2-di(4-pyridine) ethylene into the interlayer spaces of Co(II) Ni (II)-, and Cu(II)-montmorillonites. Appl Clay Sci. 2001;19:6976. .

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  • 37. Breen, C. Thermogravimetric study of the desorption of cyclohexylamine and pyridine from an acid-treated Wyoming bentonite. Clay Miner. 1991;26:473486. .

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
1
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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