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S. Ľalíková
S. Ľalíková
Department of Inorganic Materials and Environmental Engineering, Faculty of Industrial Technologies, University of Trenčín, 02001, Púchov, Slovak Republic
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M. Pajtášová
M. Pajtášová
Department of Inorganic Materials and Environmental Engineering, Faculty of Industrial Technologies, University of Trenčín, 02001, Púchov, Slovak Republic
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M. Chromčíková
M. Chromčíková
Vitrum Laugaricio—Joint Glass Center of IIC SAS, TnU AD, FChPT STU and RONA, j.s.c., Študentská 2, SK-911 50, Trenčín, Slovak Republic
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M. Liška
M. Liška
Vitrum Laugaricio—Joint Glass Center of IIC SAS, TnU AD, FChPT STU and RONA, j.s.c., Študentská 2, SK-911 50, Trenčín, Slovak Republic
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V. Šutinská
V. Šutinská
Department of Inorganic Materials and Environmental Engineering, Faculty of Industrial Technologies, University of Trenčín, 02001, Púchov, Slovak Republic
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M. Olšovský
M. Olšovský
Department of Inorganic Materials and Environmental Engineering, Faculty of Industrial Technologies, University of Trenčín, 02001, Púchov, Slovak Republic
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D. Ondrušová
D. Ondrušová
Department of Inorganic Materials and Environmental Engineering, Faculty of Industrial Technologies, University of Trenčín, 02001, Púchov, Slovak Republic
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S. C. Mojumdar
S. C. Mojumdar
University of New Brunswick, Fredericton, NB, E3B 5A3, Canada
Department of Chemical and Biochemical Engineering, The University of Western Ontario, London, ON, N6A 5B9, Canada
Department of Chemical Technologies and Environment, Faculty of Industrial Technologies, Trenčín University, 020 32, Púchov, Slovakia
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Department of Chemical and Biochemical Engineering, The University of Western Ontario, London, ON, N6A 5B9, Canada
Department of Chemical Technologies and Environment, Faculty of Industrial Technologies, Trenčín University, 020 32, Púchov, Slovakia
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Abstract
This paper is devoted to the investigation of the properties of the natural rubber composites prepared using the cation exchanged-montmorillonite fillers. The characteristics of the montmorillonite fillers were studied by Fourier transform infrared spectroscopy (FTIR) and thermogravimetry (TG). These characterized fillers were used to preparation of the natural rubber composites, which were submitted to measurements of dynamic-mechanical thermal analysis (DMTA) and vulcanizing characteristics (MH, ML, ts, tc(90), Rv) as well as physico-mechanical properties (tensile strength, modulus at 300 elongation—M300, tensibility).
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1. Sarkar, M, Dana, K, Ghatak, S, Banerjee, A. Polypropylene–clay composite prepared from Indian bentonite. Bull Mater Sci. 2008;31: 1 23–28. .
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2. Teh, PL, Ishak, MZA, Ishiaku, US, Karger-Kocsis, J. Cure characteristics and mechanical properties of natural rubber/organoclay nanocomposites. Jurnal Teknologi. 2003;39:1–10.
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3. Bhattacharyya, S, Sinturel, C, Bahloul, O, Saboungi, ML, Thomas, S, Salvetat, JP. Improving reinforcement of natural rubber by networking of activated carbon nanotubes. Carbon. 2008;46:1037–1045. .
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4. Park, CI, Park, OO, Lim, GJ, Kim, HJ. The fabrication of syndiotactic polystyrene/organophilic clay nanocomposites and their properties. Polymer. 2001;42:7465–7475. .
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5. Paul, M, Alexandre, M, Degee, P, Henrist, C, Rulmont, A, Dubois, P. New nanocomposite materials based on plasticized poly(L-lactide) and organo-modified montmorillonites: thermal and morphological study. Polymer. 2003;44:443–450. .
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6. Mojumdar, SC, Raki, L. Preparation, thermal, spectral and microscopic studies of calcium silicate hydrate-poly(acrylic acid) nanocomposite materials. J Therm Anal Calorim. 2006;85:99–105. .
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7. Sawant, SY, Verenkar, VMS, Mojumdar, SC. Preparation, thermal, XRD, chemical and FT-IR spectral analysis of NiMn2O4 nanoparticles and respective precursor. J Therm Anal Calorim. 2007;90:669–672. .
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8. Porob, RA, Khan, SZ, Mojumdar, SC, Verenkar, VMS. Synthesis, TG, SDC and infrared spectral study of NiMn2(C4H4O4)3·6N2H4—a precursor for NiMn2O4 nanoparticles. J Therm Anal Calorim. 2006;86:605–608. .
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9. Mojumdar, SC, Varshney, KG, Agrawal, A. Hybrid fibrous ion exchange materials: past, present and future. Res J Chem Environ. 2006;10:89–103.
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10. Doval, M, Palou, M, Mojumdar, SC. Hydration behaviour of C2S and C2AS nanomaterials, synthesized by sol–gel method. J Therm Anal Calorim. 2006;86:595–599. .
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11. Tiwari, NR, Rathore, A, Prabhune, A, Kulkarni, SK. Gold nanoparticles for colorimetric detection of hydrolysis of antibiotics by penicillin G acylase. Adv Biosci Biotechnol. 2010;1:322–329. .
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12. Varshney, G, Agrawal, A, Mojumdar, SC. Pyridine based cerium(IV) phosphate hybrid fibrous ion exchanger: synthesis, characterization and thermal behaviour. J Therm Anal Calorim. 2007;90:731–734. .
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13. Mojumdar, SC, Melnik, M, Jona, E. Thermal and spectral properties of Mg(II) and Cu(II) complexes with heterocyclic N-donor ligands. J Anal Appl Pyrolysis. 2000;53:149–160. .
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14. Borah, B, Wood, JL. Complex hydrogen bonded cations. The benzimidazole benzimidazolium cation. Can J Chem. 1976;50:2470–2481. .
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15. Mojumdar, SC, Sain, M, Prasad, RC, Sun, L, Venart, JES. Selected thermoanalytical methods and their applications from medicine to construction. J Therm Anal Calorim. 2007;60:653–662. .
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16. Meenakshisundarm, SP, Parthiban, S, Madhurambal, G, Mojumdar, SC. Effect of chelating agent (1,10-phenanthroline) on potassium hydrogen phthalate crystals. J Therm Anal Calorim. 2008;94:21–25. .
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17. Skorsepa, JS, Gyoryova, K, Melnik, M. Preparation, identification and thermal properties of (CH3CH2COO)2Zn·2L·H2O (L=thiourea, nicotinamide, caffeine or theorbromine). J Therm Anal Calorim. 1995;44:169–177. .
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18. Ondrusova, D, Jona, E, Simon, P. Thermal properties of N-ethyl-N-phenyldithiocarbamates and their influence on the kinetics of cure. J Therm Anal Calorim. 2002;67:147–152. .
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19. Madhurambal, G, Ramasamy, P, Anbusrinivasan, P, Vasudevan, G, Kavitha, S, Mojumdar, SC. Growth and characterization studies of 2-bromo-4′-chloro-acetophenone (BCAP) crystals. J Therm Anal Calorim. 2008;94:59–62. .
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20. Ukraintseva, EA, Logvinenko, VA, Soldatov, DV, Chingina, TA. Thermal dissociation processes for clathrates [CuPy4(NO3)2]·2G (G=tetrahydrofurane, chloroform). J Therm Anal Calorim. 2004;75:337–345. .
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21. Raileanu, M, Todan, L, Crisan, M, Braileanu, A, Rusu, A, Bradu, C, Carpov, A, Zaharescu, M. Sol–gel materials with pesticide deliveryproperties. J Environ Prot. 2010;1:302–313. .
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22. Varshney, KG, Agrawal, A, Mojumdar, SC. Pectin based cerium(IV) and thorium(IV) phosphates as novel hybrid fibrous ion exchangers synthesis, characterization and thermal behaviour. J Therm Anal Calorim. 2005;81:183–189. .
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23. Mojumdar, SC, Šimon, P, Krutošíková, A. [1]Benzofuro[3,2-c]pyridine: synthesis and coordination reactions. J Therm Anal Calorim. 2009;96:103–109. .
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24. Jona, E, Rudinska, E, Sapietova, M, Pajtasova, M, Ondrusova, D, Jorik, V, Mojumdar, SC. Interaction of pyridine derivatives into the interlayer spaces of Cu(II)-montmorillonites. Res J Chem Environ. 2005;9:41–43.
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25. Mojumdar, SC, Miklovic, J, Krutosikova, A, Valigura, D, Stewart, JM. Furopyridines and furopyridine–Ni(II) complexes—synthesis, thermal and spectral characterization. J Therm Anal Calorim. 2005;81:211–215. .
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26. Geethamma, VG, Kalaprasad, G, Groeninckx, G, Thomas, S. Dynamic mechanical behavior of short coir fiber reinforced natural rubber composites. Compos A. 2005;36:1499–1506. .
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27. Leszczynska, A, Pielichowski, K. Application of thermal analysis methods for characterization of polymer/montmorillonite nanocomposites. J Therm Anal Calorim. 2008;93: 3 677–687. .
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28. Jóna, E, Rudinská, E, Sapietová, M, Pajtášová, M, Ondrušová, D, Jorík, V, Mojumdar, SC. Intercalation of pyridine derivatesinto the interlayer spaces of Cu(II)-montmorillonites. Res J Chem Environ. 2005;9: 2 41–43.
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29. Kubranová, M, Jóna, E, Rudinská, E, Nemčeková, K, Ondrušová, D, Pajtášová, M. Thermal properties of Co-, Ni- and Cu-exchanged montmorillonite with 3 hydroxypyridine. J Therm Anal Calorim. 2003;74:251–257. .
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30. Jóna, E, Sapietová, M, Šnircová, S, Pajtášová, M, Ondrušová, D, Pavlík, V, Lajdová, Ľ, Mojumdar, SC. Characterization and thermal properties of Ni-exchanged montmorillonite with benzimidazole. J Therm Anal Calorim. 2008;94: 1 69–73. .
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31. STN 62 1425. A preparation of rubber compounds.
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32. STN 62 1416. A determination of vulcanization characteristics.
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33. STN 62 1436 (ISO 37). A determination of tensile properties.
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34. STN 62 1431. A determination of hardness by pressig of point of hardness tester Shore A.
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35. Jia, QX, Wu, YP, Wang, YQ, Lu, M, Zhang, LQ. Enhanced interfacial interaction of rubber/clay nanocomposites by a novel two-step method. Compos Sci Technol. 2008;68:1050–1056. .
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36. Siengchin, S, Karger-Kocsis, J. Structure and creep response of toughened and nanoreinforced polyamides produced via the latex route: effect of nanofiller type. Compos Sci Technol. 2009;69:677–683. .
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37. Ľalíková, S, Pajtášová, M, Ondrušová, D, Bazyláková, T, Olšovský, M, Jóna, E, Mojumdar, SC. Thermal and spectral properties of natural bentonites and their application as reinforced nanofillers in polymeric materials. J Therm Anal Calorim. 2010;100:745–749. .
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38. Olšovský, M, Gášek, P, Ľalíková, S, Bazyláková, T, Macho, V. Kopolymérna síra ako vulkanizačné činidlo pre nenasýtené kaučuky. Chem Listy. 2009;103:924–930.
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| Journal of Thermal Analysis and Calorimetry | |
|---|---|
| Language | English |
| Size | A4 |
| Year of Foundation |
1969 |
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