View More View Less
  • 1 Department of Inorganic Materials and Environmental Engineering, Faculty of Industrial Technologies, University of Trenčín, 02001, Púchov, Slovak Republic
  • | 2 Vitrum Laugaricio—Joint Glass Center of IIC SAS, TnU AD, FChPT STU and RONA, j.s.c., Študentská 2, SK-911 50, Trenčín, Slovak Republic
  • | 3 University of New Brunswick, Fredericton, NB, E3B 5A3, Canada
  • | 4 Department of Chemical and Biochemical Engineering, The University of Western Ontario, London, ON, N6A 5B9, Canada
  • | 5 Department of Chemical Technologies and Environment, Faculty of Industrial Technologies, Trenčín University, 020 32, Púchov, Slovakia
Restricted access

Abstract

This paper is devoted to the investigation of the properties of the natural rubber composites prepared using the cation exchanged-montmorillonite fillers. The characteristics of the montmorillonite fillers were studied by Fourier transform infrared spectroscopy (FTIR) and thermogravimetry (TG). These characterized fillers were used to preparation of the natural rubber composites, which were submitted to measurements of dynamic-mechanical thermal analysis (DMTA) and vulcanizing characteristics (MH, ML, ts, tc(90), Rv) as well as physico-mechanical properties (tensile strength, modulus at 300 elongation—M300, tensibility).

  • 1. Sarkar, M, Dana, K, Ghatak, S, Banerjee, A. Polypropylene–clay composite prepared from Indian bentonite. Bull Mater Sci. 2008;31: 1 2328. .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 2. Teh, PL, Ishak, MZA, Ishiaku, US, Karger-Kocsis, J. Cure characteristics and mechanical properties of natural rubber/organoclay nanocomposites. Jurnal Teknologi. 2003;39:110.

    • Search Google Scholar
    • Export Citation
  • 3. Bhattacharyya, S, Sinturel, C, Bahloul, O, Saboungi, ML, Thomas, S, Salvetat, JP. Improving reinforcement of natural rubber by networking of activated carbon nanotubes. Carbon. 2008;46:10371045. .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 4. Park, CI, Park, OO, Lim, GJ, Kim, HJ. The fabrication of syndiotactic polystyrene/organophilic clay nanocomposites and their properties. Polymer. 2001;42:74657475. .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 5. Paul, M, Alexandre, M, Degee, P, Henrist, C, Rulmont, A, Dubois, P. New nanocomposite materials based on plasticized poly(L-lactide) and organo-modified montmorillonites: thermal and morphological study. Polymer. 2003;44:443450. .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 6. Mojumdar, SC, Raki, L. Preparation, thermal, spectral and microscopic studies of calcium silicate hydrate-poly(acrylic acid) nanocomposite materials. J Therm Anal Calorim. 2006;85:99105. .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 7. Sawant, SY, Verenkar, VMS, Mojumdar, SC. Preparation, thermal, XRD, chemical and FT-IR spectral analysis of NiMn2O4 nanoparticles and respective precursor. J Therm Anal Calorim. 2007;90:669672. .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 8. Porob, RA, Khan, SZ, Mojumdar, SC, Verenkar, VMS. Synthesis, TG, SDC and infrared spectral study of NiMn2(C4H4O4)3·6N2H4—a precursor for NiMn2O4 nanoparticles. J Therm Anal Calorim. 2006;86:605608. .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 9. Mojumdar, SC, Varshney, KG, Agrawal, A. Hybrid fibrous ion exchange materials: past, present and future. Res J Chem Environ. 2006;10:89103.

    • Search Google Scholar
    • Export Citation
  • 10. Doval, M, Palou, M, Mojumdar, SC. Hydration behaviour of C2S and C2AS nanomaterials, synthesized by sol–gel method. J Therm Anal Calorim. 2006;86:595599. .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 11. Tiwari, NR, Rathore, A, Prabhune, A, Kulkarni, SK. Gold nanoparticles for colorimetric detection of hydrolysis of antibiotics by penicillin G acylase. Adv Biosci Biotechnol. 2010;1:322329. .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 12. Varshney, G, Agrawal, A, Mojumdar, SC. Pyridine based cerium(IV) phosphate hybrid fibrous ion exchanger: synthesis, characterization and thermal behaviour. J Therm Anal Calorim. 2007;90:731734. .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 13. Mojumdar, SC, Melnik, M, Jona, E. Thermal and spectral properties of Mg(II) and Cu(II) complexes with heterocyclic N-donor ligands. J Anal Appl Pyrolysis. 2000;53:149160. .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 14. Borah, B, Wood, JL. Complex hydrogen bonded cations. The benzimidazole benzimidazolium cation. Can J Chem. 1976;50:24702481. .

  • 15. Mojumdar, SC, Sain, M, Prasad, RC, Sun, L, Venart, JES. Selected thermoanalytical methods and their applications from medicine to construction. J Therm Anal Calorim. 2007;60:653662. .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 16. Meenakshisundarm, SP, Parthiban, S, Madhurambal, G, Mojumdar, SC. Effect of chelating agent (1,10-phenanthroline) on potassium hydrogen phthalate crystals. J Therm Anal Calorim. 2008;94:2125. .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 17. Skorsepa, JS, Gyoryova, K, Melnik, M. Preparation, identification and thermal properties of (CH3CH2COO)2Zn·2L·H2O (L=thiourea, nicotinamide, caffeine or theorbromine). J Therm Anal Calorim. 1995;44:169177. .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 18. Ondrusova, D, Jona, E, Simon, P. Thermal properties of N-ethyl-N-phenyldithiocarbamates and their influence on the kinetics of cure. J Therm Anal Calorim. 2002;67:147152. .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 19. Madhurambal, G, Ramasamy, P, Anbusrinivasan, P, Vasudevan, G, Kavitha, S, Mojumdar, SC. Growth and characterization studies of 2-bromo-4′-chloro-acetophenone (BCAP) crystals. J Therm Anal Calorim. 2008;94:5962. .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 20. Ukraintseva, EA, Logvinenko, VA, Soldatov, DV, Chingina, TA. Thermal dissociation processes for clathrates [CuPy4(NO3)2]·2G (G=tetrahydrofurane, chloroform). J Therm Anal Calorim. 2004;75:337345. .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 21. Raileanu, M, Todan, L, Crisan, M, Braileanu, A, Rusu, A, Bradu, C, Carpov, A, Zaharescu, M. Sol–gel materials with pesticide deliveryproperties. J Environ Prot. 2010;1:302313. .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 22. Varshney, KG, Agrawal, A, Mojumdar, SC. Pectin based cerium(IV) and thorium(IV) phosphates as novel hybrid fibrous ion exchangers synthesis, characterization and thermal behaviour. J Therm Anal Calorim. 2005;81:183189. .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 23. Mojumdar, SC, Šimon, P, Krutošíková, A. [1]Benzofuro[3,2-c]pyridine: synthesis and coordination reactions. J Therm Anal Calorim. 2009;96:103109. .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 24. Jona, E, Rudinska, E, Sapietova, M, Pajtasova, M, Ondrusova, D, Jorik, V, Mojumdar, SC. Interaction of pyridine derivatives into the interlayer spaces of Cu(II)-montmorillonites. Res J Chem Environ. 2005;9:4143.

    • Search Google Scholar
    • Export Citation
  • 25. Mojumdar, SC, Miklovic, J, Krutosikova, A, Valigura, D, Stewart, JM. Furopyridines and furopyridine–Ni(II) complexes—synthesis, thermal and spectral characterization. J Therm Anal Calorim. 2005;81:211215. .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 26. Geethamma, VG, Kalaprasad, G, Groeninckx, G, Thomas, S. Dynamic mechanical behavior of short coir fiber reinforced natural rubber composites. Compos A. 2005;36:14991506. .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 27. Leszczynska, A, Pielichowski, K. Application of thermal analysis methods for characterization of polymer/montmorillonite nanocomposites. J Therm Anal Calorim. 2008;93: 3 677687. .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 28. Jóna, E, Rudinská, E, Sapietová, M, Pajtášová, M, Ondrušová, D, Jorík, V, Mojumdar, SC. Intercalation of pyridine derivatesinto the interlayer spaces of Cu(II)-montmorillonites. Res J Chem Environ. 2005;9: 2 4143.

    • Search Google Scholar
    • Export Citation
  • 29. Kubranová, M, Jóna, E, Rudinská, E, Nemčeková, K, Ondrušová, D, Pajtášová, M. Thermal properties of Co-, Ni- and Cu-exchanged montmorillonite with 3 hydroxypyridine. J Therm Anal Calorim. 2003;74:251257. .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 30. Jóna, E, Sapietová, M, Šnircová, S, Pajtášová, M, Ondrušová, D, Pavlík, V, Lajdová, Ľ, Mojumdar, SC. Characterization and thermal properties of Ni-exchanged montmorillonite with benzimidazole. J Therm Anal Calorim. 2008;94: 1 6973. .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 31. STN 62 1425. A preparation of rubber compounds.

  • 32. STN 62 1416. A determination of vulcanization characteristics.

  • 33. STN 62 1436 (ISO 37). A determination of tensile properties.

  • 34. STN 62 1431. A determination of hardness by pressig of point of hardness tester Shore A.

  • 35. Jia, QX, Wu, YP, Wang, YQ, Lu, M, Zhang, LQ. Enhanced interfacial interaction of rubber/clay nanocomposites by a novel two-step method. Compos Sci Technol. 2008;68:10501056. .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 36. Siengchin, S, Karger-Kocsis, J. Structure and creep response of toughened and nanoreinforced polyamides produced via the latex route: effect of nanofiller type. Compos Sci Technol. 2009;69:677683. .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 37. Ľalíková, S, Pajtášová, M, Ondrušová, D, Bazyláková, T, Olšovský, M, Jóna, E, Mojumdar, SC. Thermal and spectral properties of natural bentonites and their application as reinforced nanofillers in polymeric materials. J Therm Anal Calorim. 2010;100:745749. .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 38. Olšovský, M, Gášek, P, Ľalíková, S, Bazyláková, T, Macho, V. Kopolymérna síra ako vulkanizačné činidlo pre nenasýtené kaučuky. Chem Listy. 2009;103:924930.

    • Search Google Scholar
    • Export Citation

Manuscript Submission: HERE

  • Impact Factor (2019): 2.731
  • Scimago Journal Rank (2019): 0.415
  • SJR Hirsch-Index (2019): 87
  • SJR Quartile Score (2019): Q3 Condensed Matter Physics
  • SJR Quartile Score (2019): Q3 Physical and Theoretical Chemistry
  • Impact Factor (2018): 2.471
  • Scimago Journal Rank (2018): 0.634
  • SJR Hirsch-Index (2018): 78
  • SJR Quartile Score (2018): Q2 Condensed Matter Physics
  • SJR Quartile Score (2018): Q2 Physical and Theoretical Chemistry

For subscription options, please visit the website of Springer.

Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
4
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

Monthly Content Usage

Abstract Views Full Text Views PDF Downloads
Apr 2021 0 0 0
May 2021 0 0 0
Jun 2021 0 0 0
Jul 2021 2 0 0
Aug 2021 0 0 0
Sep 2021 0 0 0
Oct 2021 0 0 0