Authors:
E. A. Ukraintseva A. V. Nikolaev Institute of Inorganic Chemistry SB RAS, Acad. Lavrentyev ave. 3, 630090, Novosibirsk, Russia

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G. N. Chekhova A. V. Nikolaev Institute of Inorganic Chemistry SB RAS, Acad. Lavrentyev ave. 3, 630090, Novosibirsk, Russia

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D. V. Pinakov A. V. Nikolaev Institute of Inorganic Chemistry SB RAS, Acad. Lavrentyev ave. 3, 630090, Novosibirsk, Russia

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Abstract

Thermal dissociation processes for acetonitrile inclusion compounds based on the polymer fluorographite host matrix C2FxBr0.01·yCH3CN, where x = 0.49–0.92, y = 0.174–0.285, are investigated. Thermodynamic parameters (ΔH°av, ΔS°av, ΔG°298) for deintercalation of the compounds of the first filling step into the compounds of the second step and gaseous guest within temperature range 294–352 K were determined. The effect of the host matrix fluorination degree on the thermodynamic characteristics of the studied processes is demonstrated.

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
1
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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