Geopolymers
Inorganic polymeric new materials
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Kang-Zhen Xu
Kang-Zhen Xu
Department of Chemical Engineering/Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Northwest University, Xi’an 710069, People’s Republic of China
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Yong-Shun Chen
Yong-Shun Chen
Department of Chemical Engineering/Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Northwest University, Xi’an 710069, People’s Republic of China
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Min Wang
Min Wang
Department of Chemical Engineering/Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Northwest University, Xi’an 710069, People’s Republic of China
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Jin-An Luo
Jin-An Luo
Department of Chemical Engineering/Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Northwest University, Xi’an 710069, People’s Republic of China
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Ji-Rong Song
Ji-Rong Song
Department of Chemical Engineering/Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Northwest University, Xi’an 710069, People’s Republic of China
Conservation Technology Department, The Palace Museum, Beijing 100009, People’s Republic of China
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Conservation Technology Department, The Palace Museum, Beijing 100009, People’s Republic of China
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Feng-Qi Zhao
Feng-Qi Zhao
Xi’an Modern Chemistry Research Institute, Xi’an 710065, People’s Republic of China
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Rong-Zu Hu
Rong-Zu Hu
Xi’an Modern Chemistry Research Institute, Xi’an 710065, People’s Republic of China
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Abstract
A novel energetic material, 4,5-dihydroxyl-2-(dinitromethylene)-imidazolidine (DDNI), was synthesized by the reaction of FOX-7 and glyoxal in water at 70 °C. Thermal behavior of DDNI was studied with DSC and TG-DTG methods, and presents only an intense exothermic decomposition process. The apparent activation energy and pre-exponential factor of the decomposition reaction were 286.0 kJ mol−1 and 1031.16 s−1, respectively. The critical temperature of thermal explosion of DDNI is 183.78 °C. Specific heat capacity of DDNI was studied with micro-DSC method and theoretical calculation method, and the molar heat capacity is 217.76 J mol−1 K−1 at 298.15 K. The adiabatic time-to-explosion was also calculated to be a certain value between 14.54 and 16.34 s. DDNI presents lower thermal stability, for its two ortho-hydroxyl groups, and its thermal decomposition process becomes quite intense.
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| Journal of Thermal Analysis and Calorimetry | |
|---|---|
| Language | English |
| Size | A4 |
| Year of Foundation |
1969 |
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| Founder | Akadémiai Kiadó |
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| Publisher | Akadémiai Kiadó Springer Nature Switzerland AG |
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Temperature dependence of the rate of reaction in thermal analysis
The Arrhenius equation in condensed phase kinetics
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