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  • 1 Department of Physical Chemistry, Faculty of Chemical Technology, University of Pardubice, Studentská 573, CZ-53210, Pardubice, Czech Republic
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Abstract

Adsorption of CO2 as probe molecule on alkali-metal zeolites of MFI structure was investigated by joint volumetry–calorimetry. Consideration was given to the interpretation of the heat evolved when a probe molecule is adsorbed on the surface. In particular, the number and the strength of adsorption sites are discussed as functions of zeolite structure, concentration, and nature of extra-framework cation. The adsorption heats (qiso) of CO2 interaction with alkali-metal cations decrease for MFI zeolite with high Si/Al in the sequence Li+ > Na+ > K+ from 54 kJ/mol to 49 and 43 kJ/mol, respectively. In addition, the adsorption heats are influenced by concentration of Al in the framework. This phenomenon is attributed to formation of bridged CO2 adsorption complexes formed between two cations. On the base of quantitative analysis of adsorption processes, presence of geminal adsorption complexes was suggested for adsorption at higher equilibrium pressures.

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  • Impact Factor (2019): 2.731
  • Scimago Journal Rank (2019): 0.415
  • SJR Hirsch-Index (2019): 87
  • SJR Quartile Score (2019): Q3 Condensed Matter Physics
  • SJR Quartile Score (2019): Q3 Physical and Theoretical Chemistry
  • Impact Factor (2018): 2.471
  • Scimago Journal Rank (2018): 0.634
  • SJR Hirsch-Index (2018): 78
  • SJR Quartile Score (2018): Q2 Condensed Matter Physics
  • SJR Quartile Score (2018): Q2 Physical and Theoretical Chemistry

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
4
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)