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  • 1 Department of Inorganic Chemistry, Faculty of Chemistry, University of Bucharest, 90-92 Panduri St., 050663 Sector 5, Bucharest, Romania
  • | 2 Department of Inorganic Chemistry, Carol Davila University of Medicine and Pharmacy, 6 Traian Vuia St., Bucharest, Romania
  • | 3 Department of Organic Chemistry, Carol Davila University of Medicine and Pharmacy, 6 Traian Vuia St., Bucharest, Romania
  • | 4 Department of Pharmaceutical Chemistry, Carol Davila University of Medicine and Pharmacy, 6 Traian Vuia St., Bucharest, Romania
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Abstract

Two new complexes having general formula VOL2·nH2O [(1) L: 5-hydroxyflavone, n = 1; (2) L: chrysin, n = 4] were synthesized and characterized. Based on IR and electronic data we concluded that studied flavones act as bidentate ligands in complexes with metallic ion coordinated in a square-pyramidal stereochemistry. The thermal analysis (TG, DTA) elucidated the composition and also the number and nature of the water molecules. The thermal behavior also indicated strong interactions between oxovanadium (IV) and these oxygen donor ligands.

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
4
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)