Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 105: Issue 2
Thermal behavior of oxidation of TiN and TiC nanoparticles
Authors:
J. SempereIQS Universitat Ramon Llull, Via Augusta, 390, 08017, Barcelona, Spain

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R. NomenIQS Universitat Ramon Llull, Via Augusta, 390, 08017, Barcelona, Spain

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E. SerraIQS Universitat Ramon Llull, Via Augusta, 390, 08017, Barcelona, Spain

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B. SempereIQS Universitat Ramon Llull, Via Augusta, 390, 08017, Barcelona, Spain

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D. GuglielmiIQS Universitat Ramon Llull, Via Augusta, 390, 08017, Barcelona, Spain

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Pages:
719–726
Online Publication Date:
24 Dec 2010
Publication Date:
01 Aug 2011
Article Category:
Research Article
DOI:
https://doi.org/10.1007/s10973-010-1214-x
Keywords:
Titanium nitride; Titanium carbide; Nanoparticles; Kinetic analysis; Oxidation; Thermal safety
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Abstract

Titanium nitride and carbide oxidation have been studied using TG and DSC. Titanium nitride shows a oxidation behavior were both techniques detect a unique phenomenon. Titanium carbide shows a variable behavior depending on the heating rate and sample size. Low masses and heating rates provide similar results to titanium nitride. However, using moderate sample sizes and scanning rates a two-stage oxidation is observed. The first step is extremely fast and exothermic, consuming the oxygen trapped inside the nanoparticle bed. The second is controlled by the diffusion of the oxygen and CO2 through the sample. Thermal safety conclusions are extracted from this observation. Energies of activation calculated using traditional kinetic models are lower than those found in the literature, being an indication of the influence of the specific surface of the material.

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Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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