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  • 1 Physical Chemistry and Polymer Science (FYSC), Vrije Universiteit Brussel, Pleinlaan 2, B-1050, Brussels, Belgium
  • | 2 Electrochemical and Surface Engineering (SURF), Vrije Universiteit Brussel, Pleinlaan 2, B-1050, Brussels, Belgium
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Abstract

A self-healing material for coating applications was synthesized using the Diels–Alder (DA) reaction as cross-linking reaction. The built-in reversibility allows local mobility and rearrangements in the polymeric network, which is composed of a furan functionalized epoxy-amine and a bismaleimide. The self-healing material was characterized by physical–chemical means using Fourier Transform Infrared spectroscopy, thermogravimetric analysis (TG) and rapid heat-cool differential scanning calorimetry. It has been shown that the reversibility, as a result of a change in DA/retro-DA equilibrium, occurs in a temperature window ranging from ca. 80 to 150 °C. The repeatability of the non-autonomous healing was checked by TG, showing no evaporation or degradation of the components involved in the temperature window of interest.

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Manuscript Submission: HERE

  • Impact Factor (2019): 2.731
  • Scimago Journal Rank (2019): 0.415
  • SJR Hirsch-Index (2019): 87
  • SJR Quartile Score (2019): Q3 Condensed Matter Physics
  • SJR Quartile Score (2019): Q3 Physical and Theoretical Chemistry
  • Impact Factor (2018): 2.471
  • Scimago Journal Rank (2018): 0.634
  • SJR Hirsch-Index (2018): 78
  • SJR Quartile Score (2018): Q2 Condensed Matter Physics
  • SJR Quartile Score (2018): Q2 Physical and Theoretical Chemistry

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
4
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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