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Shmuel Yariv Institute of Chemistry, The Hebrew University of Jerusalem, Campus Edmund Y. Safra, 91904, Jerusalem, Israel

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Mikhail Borisover Institute of Soil, Water and Environmental Sciences, The Volcani Center, Agricultural Research Organization, POB 6, 50250, Bet Dagan, Israel

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Isaak Lapides Institute of Chemistry, The Hebrew University of Jerusalem, Campus Edmund Y. Safra, 91904, Jerusalem, Israel

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Abstract

Organoclays are the adsorption products of organic matter by clay minerals. In modern technology, organoclay-based nanocomposites obtained by modifying Na-clay by primary adsorption of organic ammonium cations or long-chain cationic surfactants are widely used in different industries. They are potential candidates for serving as sorbents of different organic compounds by secondary adsorption. Organoclays are widely spread in the environment and are responsible for the colloid behavior of different environmental elements such as soils. This manuscript summarizes some of the basic knowledge on thermal analysis of organoclays and reviews some of the recent studies carried out in our laboratory on organoclays which occur in the environment, those applied in industry and of those obtained by secondary adsorption processes. Complexes in the environment or those used in industry are mainly of the smectite clay mineral montmorillonite and their thermal analysis in air is treated here.

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  • 43. Yermiyahu, Z, Landau, A, Zaban, A, Lapides, I, Yariv, S 2003 Monoionic montmorillonites treated with Congo-red Differential thermal analysis study. J Therm Anal Calorim. 72:431441 .

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  • 47. Borisover, M, Bukhanovsky, N, Lapides, S, Yariv, S 2010 Thermal treatment of organoclays: effect on the aqueous sorption of nitrobenzene on n-hexadecyltrimethyl ammonium montmorillonite. Appl Surf Sci. 256:55395544 .

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  • 48. Burstein, F, Borisover, M, Lapides, S, Yariv, S 2008 Secondary adsorption on nitrobenzene and m-nitrophenol by hexadecyltrimethylammonium-montmorillonite: thermo-XRD-analysis. J Therm Anal Calorim. 92:3542 .

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  • 49. Abramova, E, Lapides, I, Yariv, S 2007 Thermo-XRD investigation of monoionic montmorillonites mechanochemically treated with urea. J Therm Anal Calorim. 90:97106 .

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  • 50. Yermiyahu, Z, Lapides, I, Yariv, S 2008 Thermo-infrared-spectroscopy analysis of the interaction of naphthylammonium-montmorillonite with sodium nitrite. Colloid Polym Sci. 286:12331242 .

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  • 51. Yermiyahu, Z, Lapides, I, Yariv, S 2007 Synthesis and thermo-XRD-analysis of the organo-clay color pigment Naphthylazonaphthylammonium-montmorillonite. J Therm Anal Calorim. 88:795800 .

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  • 52. Yermiyahu, Z, Kogan, A, Lapides, I, Pelly, I, Yariv, S 2008 Thermal study of naphthylammonium- and naphthylazonaphthylammonium montmorillonite, XRD and DTA. J Therm Anal Calorim. 91:125135 .

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  • 53. Siebner-Freibach, H, Hadar, Y, Yariv, S, Lapides, I, Chen, Y 2006 Thermospectroscopic study of the adsorption mechanism of the hydroxamic siderophore ferrioxamine B by calcium montmorillonite. J Agric Food Chem. 54:13991408 .

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  • 54. Cohen, E, Joseph, T, Lapides, I, Yariv, S 2005 The adsorption of berberine by montmorillonite and thermo-XRD analysis of the organo-clay complex. Clay Miner 40:223232 .

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  • 55. Yermiyahu, Z, Lapides, I, Yariv, S 2005 Thermo-XRD-analysis of montmorillonite treated with protonated Congo-red. Curve fitting. Appl Clay Sci. 30:3341 .

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  • 56. Yermiyahu, Z, Lapides, I, Yariv, S 2007 Thermo-visible-absorption-spectroscopy study of the protonated Congo-red montmorillonite complex. Appl Clay Sci. 37:111 .

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  • 57. Ni, R, Huang, Y, Yao, C 2009 Thermogravimetric analysis of organoclays intercalated with the Gemini surfactants. J Therm Anal Calorim. 96:943947 .

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  • 58. Lu, L, Cai, J, Frost, RL 2010 Desorption of stearic acid upon surfactant adsorbed montmorillonite. J Therm Anal Calorim. 100:141144 .

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
1
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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