Authors:
Edson C. da Silva Filho LIMAV, Chemistry, Federal University of Piauí, Teresina, PI, 64049-550, Brazil

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Pedro D. R. Monteiro LIMAV, Chemistry, Federal University of Piauí, Teresina, PI, 64049-550, Brazil

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Kaline S. Sousa Institute of Chemistry, University of Campinas, P.O. Box 6154, Campinas, SP, 13084-971, Brazil

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Claudio Airoldi Institute of Chemistry, University of Campinas, P.O. Box 6154, Campinas, SP, 13084-971, Brazil

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Abstract

In this work Chitosan (Ch) was chemically modified with ethylenesulfide (Es) under solvent-free conditions to give (ChEs), displaying a high content of thiol groups due to opening of the three member cyclic reagent. ChEs was used in studies of lead and cadmium adsorption from aqueous solution, using the batchwise method and calorimetric studies were accomplished to those interactions, through the calorimetric titration technique. The obtained results show that the modified Ch, ChEs is a material, that besides presenting the advantages of being a biopolymer, it showed a good adsorption capacity of the lead and cadmium cation metallic, that are extremely poisonous and harmful to the environment. The results of the calorimetric titration showed that the related thermodynamic parameters to those adsorptions shown favorable thermodynamic data.

  • 1. Sorlier, P, Denuzière, A, Viton, C, Domard, A 2001 Relation between the degree of acetylation and the electrostatic properties of chitin and chitosan. Biomacromolecules 170:765772 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 2. Methacanon, P, Prasitsilp, M, Pothsreea, T, Pattaraarchachai, J 2003 Heterogeneous N-deacetylation of squid chitin in alkaline solution. Carbohydr Polym 52:119123 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 3. Cestari, AR, Vieira, EFS, Oliveira, IA, Bruns, RE 2007 The removal of Cu(II) and Co(II) from aqueous solutions using cross-linked chitosan-Evaluation by the factorial design methodology. J Hazard Mater 143:816 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 4. Tolaimate, A, Desbrières, J, Rhazi, M, Alagui, A, Vincendon, M 2000 On the influence of deacetylation process on the physicochemical characteristics of chitosan from squid chitin. Polymer 41:24632469 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 5. Klemm, D, Heublein, B, Fink, HP, Bohn, A 2005 Cellulose: fascinating biopolymer and sustainable raw material. Angew Chem Int Ed 44:33583393 .

  • 6. Kumar, MNVR 2000 A review of chitin and chitosan applications. React Funct Polym 46:127 .

  • 7. Ye, X, Yang, Q, Wang, Y, Li, N 1998 Electrochemical behaviour of gold, silver, platinum and palladium on the glassy carbon electrode modified by chitosan and its application. Talanta 47:10991106 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 8. Sousa, KS, Silva Filho, EC, Airoldi, C 2009 Ethylenesulfide as a useful agent for incorporation into the biopolymer chitosan in a solvent-free reaction for use in cation removal. Carbohydr Res 344:17161723 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 9. OAC Monteiro Jr Airoldi, C 1999 Some thermodynamic data on copper–chitin and copper–chitosan biopolymer interactions. J Colloid Interface Sci 212:212219 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 10. Machado, MO, Lopes, ECN KS de Sousa Airoldi, C 2009 The effectiveness of the protected amino group on crosslinked chitosans for copper removal and the thermodynamics of interaction at the solid/liquid interface. Carbohydr Polym 77:760766 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 11. Da Fonseca, MG, Da Silva Filho, EC RSDA Machado Jr Arakaki, LNH, Espínola, JGP, Oliveira, SF, Airoldi, C 2004 Anchored fibrous chrysotile sílica and its ability in using nitrogen basic centers on cátion complexing from aqueous solution. Colloids Surf A 227:8591 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 12. Arakaki, LNH, Alves, APM, SilvaFilho, ECd, Fonseca, MG, Oliveira, SF, Espínola, JGP, Airoldi, C 2007 Sequestration of Cu(II), Ni(II), and Co(II) by ethyleneimine immobilized on sílica. Thermochim Acta 453:7274 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 13. JCP de Melo da Silva Filho, EC, Santana, SAA, Airoldi, C 2009 Maleic anhydride incorporated onto cellulose and thermodynamics of cátion-exchange process at the solid/liquid interface. Colloids Surf A 346:138145 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 14. Oliveira, FJVE, da Silva Filho, EC MA Melo Jr Airoldi, C 2009 Modified coupling agents base don thiourea, immobilized onto sílica. Thermodynamics of copper adsorption. Surf Sci 603:22002206 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 15. da Silva Filho, EC JCP de Melo da Fonseca, MG, Airoldi, C 2009 Cation removal using cellulose chemically modified by a Schiff base procedure applying green principles. J Colloid Interface Sci 340:815 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 16. Arakaki, LNH, da Fonseca, MG, da Silva Filho, EC, Alves, APM KS de Sousa Silva, ALP 2006 Extraction of Pb(II), Cd(II), and Hg(II) from aqueous solution by nitrogen and thiol functionality grafted to silica gel measured by calorimetry. Thermochim Acta 450:1215 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 17. Lima, IS, Airoldi, C 2004 A thermodynamic investigation on chitosan–divalent cation interactions. Thermochim Acta 421:133139 .

  • 18. da Silva Filho, EC JCP de Melo Airoldi, C 2006 Preparation of ethylenediamine-anchored cellulose and determination of thermochemical data for the interaction between cations and basic centers at the solid/liquid interface. Carbohydr Res 341:28422850 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 19. Santana, SAA, Vieira, AP, da Silva Filho, EC, Melo, JCP, Airoldi, C 2010 Immobilization of ethylenesulfide on babassu coconut epicarp and mesocarp for divalent cation sorption. J Hazard Mater 147:714719 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 20. Lima, IS, Lazarin, AM, Airoldi, C 2006 Cyclic voltammetric investigations on copper α-N, O-succinated chitosan interactions. Carbohydr Polym 64:385390 .

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
1
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)