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  • 1 LACOM, Departamento de Química, CCEN, Universidade Federal da Paraíba, Campus I, João Pessoa, PB, 58059-900, Brazil
  • 2 Universidade Federal do Rio Grande do Norte, Natal, RN, Brazil
  • 3 Divisão de Corrosão e Degradação, Instituto Nacional de Tecnologia, Rio de Janeiro, RJ, Brazil
  • 4 Universidade Federal do Maranhao, São Luiz, MA. ANP—Agência Nacional do Petróleo, Gás Natural e Biocombustíveis, Av. Rio Branco, 65/21° Andar, Rio de Janeiro, RJ, 20090-004, Brazil
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Abstract

Biodiesel is an increasingly attractive alternative to diesel fuel. The main component of Babassu biodiesel is lauric acid (C12:0), which is a saturated fatty acid with a high melting point. Controlling flow properties, such as viscosity and the cold filter plugging point, is critical because viscosity affects atomization, and crystal formation resulting from decreases in temperature can negatively affect engine starting and performance. To evaluate its flow characteristics more fully, the rheological properties of babassu biodiesel were analyzed, taking into account variations in temperature. The crystallization temperature was determined by modulated temperature differential scanning calorimetry (MT-DSC). The curve of biodiesel viscosity as a function of the biodiesel refrigeration temperature contained an inflection point (corresponding to a steep increase in viscosity) that was coincident with both the transition from a Newtonian-type flow to a pseudoplastic-type flow and the crystallization temperature obtained by MT-DSC, indicating that the appearance of crystals in the biodiesel increased its viscosity. The rheological properties of fatty acid methyl and ethyl mixtures (FAME and FAEE) with metropolitan diesel were also evaluated; a higher FAME percentage reduced viscosity in blends up to B100.

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