Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 106: Issue 2
Crystallization study of SrSnO3:Fe
Authors:
F. T. G. Vieira Laboratório de Combustíveis e Materiais/INCTMN, Departamento de Química, Universidade Federal da Paraíba, Campus I, João Pessoa, PB, Brazil

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A. L. M. Oliveira Laboratório de Combustíveis e Materiais/INCTMN, Departamento de Química, Universidade Federal da Paraíba, Campus I, João Pessoa, PB, Brazil

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D. S. Melo Laboratório de Combustíveis e Materiais/INCTMN, Departamento de Química, Universidade Federal da Paraíba, Campus I, João Pessoa, PB, Brazil

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S. J. G. Lima LSR, Departamento de Engenharia Mecânica/CT, Universidade Federal da Paraíba, Campus I, João Pessoa, PB, Brazil

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E. Longo LIEC/INCTMN, Instituto de Química, UNESP, Araraquara, SP, Brazil

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A. S. Maia Laboratório de Combustíveis e Materiais/INCTMN, Departamento de Química, Universidade Federal da Paraíba, Campus I, João Pessoa, PB, Brazil

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A. G. Souza Laboratório de Combustíveis e Materiais/INCTMN, Departamento de Química, Universidade Federal da Paraíba, Campus I, João Pessoa, PB, Brazil

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I. M. G. Santos Laboratório de Combustíveis e Materiais/INCTMN, Departamento de Química, Universidade Federal da Paraíba, Campus I, João Pessoa, PB, Brazil

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Pages:
507–512
Online Publication Date:
05 Apr 2011
Publication Date:
01 Nov 2011
Article Category:
Research Article
DOI:
https://doi.org/10.1007/s10973-011-1509-6
Keywords:
TG/DTA; Fe3+; Crystallization
Restricted access

Abstract

Alkaline earth stannates have recently become important materials in ceramic technology due to its application as humidity sensor. In this work, alkaline earth stannates doped with Fe3+ were synthesized by the polymeric precursor method, with calcination at 300 °C/7 h and between 400 and 1100 °C/4 h. The powder precursors were characterized by TG/DTA after partial elimination of carbon. Characterization after the second calcination step was done by X-ray diffraction, infrared spectroscopy, and UV–vis spectroscopy. Results confirmed the formation of the SrSnO3:Fe with orthorhombic perovskite structure, besides SrCO3 as secondary phase. Crystallization occurred at 600 °C, being much lower than the crystallization temperature of perovskites synthesized by solid state reaction. The analysis of TG curves indicated that the phase crystallization was preceded by two thermal decomposition steps. Carbonate elimination occurred at two different temperatures, around 800 °C and above 1000 °C.

  • 1. Souza, SC, Alves, MCF, Oliveira, ALM, Longo, E, Vieira, FTG, Gomes, RM, Soledade, LEB, Souza, AG, Santos, IMG. SrSnO3:Nd obtained by the polymeric precursor method. J Therm Anal Calorim. 2009;97:85–190. .

    • Crossref
    • Search Google Scholar
    • Export Citation

  • 2. Tejuca, LG, Fierro, LG. Properties and applications of perovskite-type oxides. New York: Marcel Pekker INC; 1993.

  • 3. Alves, MCF, Souza, SC, Silva, MRS, Paris, EC, Lima, SJG, Gomes, RM, Longo, E, Souza, AG, Santos, IMG. Thermal analysis applied in the crystallization study of SrSnO3. J Therm Anal Calorim. 2009;97:179–183. .

    • Crossref
    • Search Google Scholar
    • Export Citation

  • 4. Kim, MG, Cho, HS, Yo, CH. Fe K-edg X-ray absorption (XANES/EXAFS) spectroscopic study of the nonstoichiometric SrFe1-xSnxO3-x system. J Phys Chem Solids. 1998;59:1369–1381. .

    • Crossref
    • Search Google Scholar
    • Export Citation

  • 5. Roh, KS, Ryu, KH, Yo, CH. Nonstoichiometric and physical properties of the SrSn1-xFexO3-x system. J Solid State Chem. 1999;142:288–293. .

  • 6. Beurmann, PS, Thangadurai, V, Weppner, W. Phase transitions in the SrSnO3–SrSnO3 solid solutions: X-ray diffraction and Mössbauer studies. J Solid State Chem. 2003;174:392–402. .

    • Crossref
    • Search Google Scholar
    • Export Citation

  • 7. Alves, MCF, Souza, SC, Lima, SJG, Longo, E, Souza, AG, Santos, IMG. Influence of the precursor salts in the synthesis of CaSnO3 by the polymeric precursor method. J Therm Anal Calorim. 2007;87:763–766. .

    • Crossref
    • Search Google Scholar
    • Export Citation

  • 8. Dondi, M, Cruciani, G, Guarini, G, Matteuci, F, Raimondo, M. The role of counterions (Mo, Nb, Sb, W) in Cr, Mn, Ni and V doped rutile ceramic pigments Part 2. Colour and technological properties. Ceram Int. 2006;32:393–405. .

    • Crossref
    • Search Google Scholar
    • Export Citation

  • 9. Dondi, M, Matteucci, F, Cruciani, G. Zirconium titanate ceramic pigments: crystal structure, optical spectroscopy and technological properties. J Solid State Chem. 2006;179:233–246. .

    • Crossref
    • Search Google Scholar
    • Export Citation

  • 10. Rao, JL, Murali, A, Rao, ED. Electron paramagnetic resonance and optical spectra of Fe(III) ions in alkali zinc borosulphate glasses. J Non Cryst Solids. 1996;202:215–221. .

    • Crossref
    • Search Google Scholar
    • Export Citation

  • 11. Reddy, KN, Reddy, GS, Reddy, SL, Roo, PS. Optical absorption and EPR spectral studies of vauquelinite. Cryst Res Technnol. 2006;41:818–821. .

    • Crossref
    • Search Google Scholar
    • Export Citation

  • 12. Taran, NM, Langer, K. Electronic absorption spectra of Fe3+ in andradite and epidote at different temperatures and pressures. Eur J Mineral. 2000;12:7–15.

    • Search Google Scholar
    • Export Citation

  • 13. Nyquist, R, Kagel, R. Infrared spectra of inorganic compounds. London: Academic Press; 1971.

  • 14. Perry, CH, Mccarthy, DJ, Rupprecht, G. Dieletric dispersion of some perovskite zirconates. Phys Rev. 1965;138:1537–1538. .

  • 15. Karlsson, M, Matic, A, Knee, CS, Ahmed, I, Eriksson, SG, Borjesson, L. Short-Range structure of proton-conducting perovskite BaInxZr1-xO3-x/2 (x = 0–0.75). Chem Mater. 2008;20:3480–3486. .

    • Crossref
    • Search Google Scholar
    • Export Citation
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Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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