Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 106: Issue 2
Thermal decomposition study of bismuth (III) trichloride complex with 1,10-phenanthroline as the ligand
Authors:
José Geraldo de P. Espínola Departamento de Química, Centro de Ciências Exatas e da Natureza, Universidade Federal da Paraíba, João Pessoa, PB, Brazil

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Evandro P. S. Martins Departamento de Química, Centro de Ciências Exatas e da Natureza, Universidade Federal da Paraíba, João Pessoa, PB, Brazil

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Franklin P. Aguiar Departamento de Química, Centro de Ciências Exatas e da Natureza, Universidade Federal da Paraíba, João Pessoa, PB, Brazil

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Haryane R. M. Silva Departamento de Química, Centro de Ciências Exatas e da Natureza, Universidade Federal da Paraíba, João Pessoa, PB, Brazil

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M. G. Fonseca Departamento de Química, Centro de Ciências Exatas e da Natureza, Universidade Federal da Paraíba, João Pessoa, PB, Brazil

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L. N. H. Arakaki Departamento de Química, Centro de Ciências Exatas e da Natureza, Universidade Federal da Paraíba, João Pessoa, PB, Brazil

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Ercules E. S. Teotônio Departamento de Química, Centro de Ciências Exatas e da Natureza, Universidade Federal da Paraíba, João Pessoa, PB, Brazil

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Pages:
601–606
Online Publication Date:
17 Feb 2011
Publication Date:
01 Nov 2011
Article Category:
Research Article
DOI:
https://doi.org/10.1007/s10973-011-1341-z
Keywords:
Bismuth complex; Decomposition kinetic; Phenanthroline
Restricted access

Abstract

The complex BiCl3·L (L = 1,10-phenanthroline) was synthesized and characterized by elemental analysis and infrared spectroscopy (IR). Infrared spectroscopy data suggested that the nitrogen atom of the aromatic ring is bonded to the bismuth atom. The kinetic study of thermal degradation was determined by non-isothermal thermogravimetry. Two methods based on integral equation of Coats-Redfern, were necessary for determining the kinetic trip: the fitting method, known as the checking model and an iso-conversional method. The latter gives the activation energy for each degree of conversion and the first, the kinetic model gives activation energy and the pre-exponential factor for thermal decomposition processes that occur through a single simple mechanism. The kinetic parameters, Ea and log A for the heating rates of 5, 10, and 15 min K−1, were determined considering the decomposition model denoted by F0/R1 in the range of degree of conversion between 0.065 and 0.71.

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Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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