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  • 1 Department of Chemistry, Laboratory of Catalysis and Petrochemistry, Federal University of Rio Grande do Norte, Natal, RN, 59078-970, Brazil
  • 2 Department of Materials Science and Engineering, Laboratory of Catalysis and Petrochemistry, Federal University of Rio Grande do Norte, Natal, RN, 59078-970, Brazil
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Abstract

Biodiesel is defined as a mixture of mono- or di-alquil esters of vegetable oil or animal fats. During long-term storage, oxidation caused by contact with air (autoxidation) presents a legitimate concern in relation to monitoring and maintaining fuel quality. Extensive oxidative degradation may compromise the quality by adversely affecting kinematic viscosity, acid value, or peroxide value. The oxidation susceptibility of biodiesel, due to the presence of triacilglycerides of poly-unsaturated fatty acids, was evaluated in this study. Samples of sunflower, castor, and soybean biodiesels were obtained through the transesterification reaction, with the intention of achieving the thermal stability study through thermogravimetrical analyses and differential scanning calorimetry high pressure. It was furthermore observed through thermogravimetry and pressure differential scanning calorimetry curves that castor biodiesel exhibited the highest thermal and oxidative stability.

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