Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 106: Issue 3
Use of different techniques in the evaluation of the oxidative stability of poultry fat biodiesel
Authors:
E. F. S. M. Ramalho Departamento de Química, CCEN, LACOM—Laboratório de Combustíveis e Materiais, Universidade Federal da Paraíba, João Pessoa, PB, CEP 58059-900, Brazil

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A. R. Albuquerque Departamento de Química, CCEN, LACOM—Laboratório de Combustíveis e Materiais, Universidade Federal da Paraíba, João Pessoa, PB, CEP 58059-900, Brazil

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A. L. Souza Departamento de Química, CCEN, LACOM—Laboratório de Combustíveis e Materiais, Universidade Federal da Paraíba, João Pessoa, PB, CEP 58059-900, Brazil

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A. K. Barro Universidade Federal do Maranhao, São Luiz, MA, Brazil
ANP—Agência Nacional do Petróleo, Gás Natural e Biocombustíveis. Av. Rio Branco, 65/21° Andar, 20090-004, Rio de Janeiro, RJ, Brazil

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A. S. Maia Departamento de Química, CCEN, LACOM—Laboratório de Combustíveis e Materiais, Universidade Federal da Paraíba, João Pessoa, PB, CEP 58059-900, Brazil

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I. M. G. Santos Departamento de Química, CCEN, LACOM—Laboratório de Combustíveis e Materiais, Universidade Federal da Paraíba, João Pessoa, PB, CEP 58059-900, Brazil

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A. G. Souza Departamento de Química, CCEN, LACOM—Laboratório de Combustíveis e Materiais, Universidade Federal da Paraíba, João Pessoa, PB, CEP 58059-900, Brazil

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Pages:
787–791
Online Publication Date:
16 Apr 2011
Publication Date:
01 Dec 2011
Article Category:
Research Article
DOI:
https://doi.org/10.1007/s10973-011-1545-2
Keywords:
Oxidative stability; Biodiesel; Poultry fat; PDSC; Rancimat; PetroOxy
Restricted access

Abstract

The poultry fat methylic (BMF) and ethylic (BEF) biodiesels were synthesized through transesterification by homogeneous basic catalysis. The chromatographic analyses showed the palmitic, stearic, oleic, and linoleic esters as majority components. Owing to its considerable amount of polyunsaturated fat acids, poultry fat usually leads to a biodiesel with low oxidative stability. In this study, the oxidation of their ethylic and methylic biodiesels was evaluated by Rancimat, PDSC, and PetroOxy. The OSI (Rancimat) was of 0.47 and 0.40 h for the ethylic and methylic biodiesel, respectively. In PDSC, both fuels presented an OT of about 120–123 °C. PetroOxy analysis indicated an OxyStab of 11 min for BEF and higher than 11 min for BMF. There was no correspondence among the oxidative stabilities of the employed techniques [OT(BEF) ≈ OT(BMF), OSI(BEF) > OSI(BMF), and OxyStab(BEF) < OxyStab(BMF)]. The discussion of these results was based on the indicator measured by each technique: enthalpic events are observed by PDSC; conductivity of volatile secondary oxidation products is measured by Rancimat; reduction of the oxygen pressure is determined by PetroOxy. This discussion showed that these different indicators do not reflect the same stage of the oxidative process as energy is release at the beginning of the propagation step, oxygen pressure decreases during the propagation step, and oxidation products are formed during the termination step.

  • 1. Tang, HY, Wang, AF, Salley, SO, Ng, KYS. The effect of natural and synthetic antioxidants on the oxidative stability of biodiesel. J Am Oil Chem Soc. 2008;85: 4 373–382. .

    • Crossref
    • Search Google Scholar
    • Export Citation

  • 2. Bouaid, A, Martinez, M, Aracil, J. Long storage stability of biodiesel from vegetable and used frying oils. Fuel. 2007;86:2596–2602. .

  • 3. Frankel EN . Lipid oxidation. 2nd ed. Bridgwater: The Oily Press, PJ Barnes & Associates; 2005.

  • 4. Asghar, A, Lin, CF, Gray, JI, Buckley, DJ, Booren, AM, Crackel, RL, Flegal, CJ. Influence of oxidized dietary oil and antioxidant supplementation on membrane-bound lipid stability in broiler meat. Brit Poultry Sci. 1989;30:815–819. .

    • Crossref
    • Search Google Scholar
    • Export Citation

  • 5. Guzman, RDE, Tang, HY, Salley, S, Ng, KYS. Synergistic effects of antioxidants on the oxidative stability of soybean oil-and poultry fat-based biodiesel. J Am Oil Chem Soc. 2009;86:459–467. .

    • Crossref
    • Search Google Scholar
    • Export Citation

  • 6. Park, JY, Kim, DK, Lee, JP, Park, SC, Kim, YJ, Lee, JS. Blending effects of biodiesels on oxidation stability and low temperature flow properties. Bioresource Technol. 2008;99:1196–1203. .

    • Crossref
    • Search Google Scholar
    • Export Citation

  • 7. Vasconcelos, AFF, Dantas, MB, Filho, MGR, Rosenhaim, R, Cavalcanti, EHS, Antoniosi Filho, NR, Sinfrônio, FSM, Santos, IMG, Souza, AG. Influence of drying processes on oxidative stability of ethyl corn biodiesel by differential scanning calorimetry. J Therm Anal Calorim. 2009;97: 2 657–660. .

    • Crossref
    • Search Google Scholar
    • Export Citation

  • 8. Castelló, ML, Dweck, J, Aranda, DAG. Thermal stability and water content determination of glycerol by thermogravimetry. J Therm Anal Calorim. 2009;97: 2 627–630. .

    • Crossref
    • Search Google Scholar
    • Export Citation

  • 9. Knothe, G, Dunn, RO. Dependence of oil stability index of fatty compounds on their structure and concentration in the presence of metals. J Am Oil Chem Soc. 2003;80:1021–1025. .

    • Crossref
    • Search Google Scholar
    • Export Citation

  • 10. Method EN 14112. European Committee for Standardization (2003) Fat and oil derivatives-fatty acid methyl esters (FAME)-determination of oxidation stability (accelerated oxidation test), Brussels: European Committee for Standardization Press;2003.

    • Search Google Scholar
    • Export Citation

  • 11. Kowalski, B, Ratusz, K, Kowalska, D, Bekas, W. Determination of the oxidative stability of vegetable oils by differential scanning calorimetry and Rancimat measurements. Eur J Lipid Sci Tech. 2004;106: 3 165–169. .

    • Crossref
    • Search Google Scholar
    • Export Citation

  • 12. Moser, BR. Comparative oxidative stability of fatty acid alkyl esters by accelerated methods. J Am Oil Chem Soc. 2009;86: 7 699–706. .

  • 13. Candeia, RA, Freitas, JCO, Souza, MAF, Conceição, MM, Santos, IMG, Soledade, LEB, et al. Thermal and rheological behavior of diesel and methanol biodiesel blends. J Therm Anal Calorim. 2007;87:653–656. .

    • Crossref
    • Search Google Scholar
    • Export Citation

  • 14. Dantas, MB, Conceição, MM, VJ Fernandes Jr, Santos, NA, Rosenhaim, R, Marques, ALB, et al. Thermal and kinetic study of corn biodiesel obtained by the methanol and ethanol routes. J Therm Anal Calorim. 2007;87:835–839. .

    • Crossref
    • Search Google Scholar
    • Export Citation

  • 15. Conceição, MM, VJ Fernandes Jr, Bezerra, AF, Silva, MCD, Santos, IMG, Silva, FC, et al. Dynamic kinetic calculation of castor oil biodiesel. J Therm Anal Calorim. 2007;87:865–869. .

    • Crossref
    • Search Google Scholar
    • Export Citation

  • 16. Candeia, RA, Silva, MCD, Carvalho Filho, JR, Brasilino, MGA, Bicudo, TC, Santos, IMG, Souza, AG. 2009 Influence of soybean biodiesel content on basic properties of biodiesel–diesel blends. Fuel. 88:738–743. .

    • Crossref
    • Search Google Scholar
    • Export Citation

  • 17. Kodali, DR. 2005 Oxidative stability measurement of high-stability oils by pressure differential scanning calorimeter (PDSC). J Agr Food Chem. 53:7649–7653. .

    • Crossref
    • Search Google Scholar
    • Export Citation

  • 18. A.O.C.S., American Oil Chemistry Society. Official and tentative method, vol 1. 3rd edn. Chicago; 1985.

  • 19. Demirbas, A. Progress and recent trends in biodiesel fuels. Energ Convers Manage. 2009;50:14–34. .

  • 20. Litwinienko, G. Autoxidation of unsaturated fatty acids and their esters. J Therm Anal Calorim. 2001;65:639–646. .

  • 21. Litwinienko, G, Daniluk, A, Kasprzycka-Guttman, T. Study on autoxidation kinetics of fats by differential scanning calorimetry 1. Saturated C12–C18 fatty acids and their esters. Ind Eng Chem Res. 2000;39:7–12. .

    • Crossref
    • Search Google Scholar
    • Export Citation

  • 22. Gardner, HW. Reactions of hydroperoxides-products of high molecular weight Chan, HSW, eds. Autoxidation of unsaturated lipids. London: Academic Press; 1987 51–93.

    • Search Google Scholar
    • Export Citation
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Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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