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  • 1 Bio-Coordination Laboratory, Department of Chemistry, Dr H. S. Gour University, Sagar 470003, MP, India
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Abstract

The coordination complex of Cu (II) with the Schiff base derived from 4-chloroaniline with salicylaldehyde have been synthesized and characterized by micro analytical data; FT–IR, UV–Vis, FAB-mass and thermal analysis studies. Thermal data show degradation of complexes. We carried out thermal analysis at three different heating rates viz. 5, 10 and 20 °C per min. The activation thermodynamic parameters, such as activation energy (E∗), entropy of activation (ΔS∗), enthalpy of activation (ΔH∗) and Gibbs free energy (ΔG∗) have been calculated with the help of TG, DTA and DTG curves using Coats–Redfern method. The stoichiometry of the complexes are in 1:2 (M:L) molar ratio. Synthesized complex has been tested for their reactivity and substitution behaviour.

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  • Impact Factor (2019): 2.731
  • Scimago Journal Rank (2019): 0.415
  • SJR Hirsch-Index (2019): 87
  • SJR Quartile Score (2019): Q3 Condensed Matter Physics
  • SJR Quartile Score (2019): Q3 Physical and Theoretical Chemistry
  • Impact Factor (2018): 2.471
  • Scimago Journal Rank (2018): 0.634
  • SJR Hirsch-Index (2018): 78
  • SJR Quartile Score (2018): Q2 Condensed Matter Physics
  • SJR Quartile Score (2018): Q2 Physical and Theoretical Chemistry

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
4
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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