Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 107: Issue 1
Preparation, X-ray crystallography and thermolysis of transition metal nitrates of 2,2′-bipyridine (Part 63)
Authors:
Dinesh Kumar Department of Chemistry, DDU Gorakhpur University, Gorakhpur 273009, India

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Inder Pal Singh Kapoor Department of Chemistry, DDU Gorakhpur University, Gorakhpur 273009, India

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Gurdip Singh Department of Chemistry, DDU Gorakhpur University, Gorakhpur 273009, India

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Nidhi Goel Department of Chemistry, IIT, Roorkee 247667, India

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Udai Pratap Singh Department of Chemistry, IIT, Roorkee 247667, India

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Pages:
325–334
Online Publication Date:
11 Aug 2011
Publication Date:
01 Jan 2012
Article Category:
Research Article
DOI:
https://doi.org/10.1007/s10973-011-1781-5
Keywords:
2,2′-bipyridine; Isoconversional; Ignition delay; Isothermal TG; Thermolysis; Iron and cobalt complexes
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Abstract

Recent work has described the preparation and characterization of the two complexes [Fe2(C10H8N2)4O(OH2)2](NO3)4 and [Co(C10H8N2)3]2[Co(OH2)6]·7(OH2) (NO3)8 in which both the nitrogen atoms of 2,2′-bipyridine are directly bonded with the metals. Their structures were determined by single-crystal X-ray diffraction at 296 K. Thermolysis of these complexes has been detailed by the use of TG–DTA and ignition delay measurements. Kinetics of thermal decomposition has also been established. Model free isoconversional and model fitting kinetic approaches have been applied to isothermal TG data for the decomposition of these complexes.

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Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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