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Yu. Trach Institute of Chemistry and Chemical Technologies, L’viv National Polytechnic University, 12 Stepan Bandera Str., Lviv 79013, Ukraine

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V. Sydorchuk Institute of Sorption and Endoecology, National Academy of Sciences of Ukraine, 13 General Naumov Str., Kyiv 03164, Ukraine

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O. Makota Institute of Chemistry and Chemical Technologies, L’viv National Polytechnic University, 12 Stepan Bandera Str., Lviv 79013, Ukraine

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S. Khalameida Institute of Sorption and Endoecology, National Academy of Sciences of Ukraine, 13 General Naumov Str., Kyiv 03164, Ukraine

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R. Leboda Faculty of Chemistry, Maria Curie-Sklodowska University, Maria Curie-Sklodowska Sq. 3, 20-031, Lublin, Poland

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J. Skubiszewska-Zięba Faculty of Chemistry, Maria Curie-Sklodowska University, Maria Curie-Sklodowska Sq. 3, 20-031, Lublin, Poland

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V. Zazhigalov Institute of Sorption and Endoecology, National Academy of Sciences of Ukraine, 13 General Naumov Str., Kyiv 03164, Ukraine

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Abstract

Deposited catalysts composition H3PMo12O40/SiO2 and Ag/H3PMo12O40/SiO2 have been synthesized on the basis of fumed silica, including milling technique. Physical–chemical characteristics of prepared catalysts have been studied by means of XRD, DTA-TG, FTIR, UV–Vis spectroscopy, and adsorption of nitrogen. Catalysts possess meso- or meso-macroporous structure and contain deposited Keggin heteropolycompounds. Deposition of heteropolycompounds on support with high specific surface area results in increase of selectivity to epoxide in epoxidation reactions. The use of milling during catalyst synthesis leads to further growth of selectivity of epoxides formation.

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
1
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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