Geopolymers
Inorganic polymeric new materials
Author:
Authors:
,
,
, and
Shashi B. Kalia
Shashi B. Kalia
Department of Chemistry, Himachal Pradesh University, Shimla, Himachal Pradesh, 171005, India
Search for other papers by Shashi B. Kalia in
Current site
Google Scholar
PubMed
Search for other papers by Shashi B. Kalia in
Current site
Google Scholar
PubMed
Priyanka Sankhyan
Priyanka Sankhyan
Department of Chemistry, Himachal Pradesh University, Shimla, Himachal Pradesh, 171005, India
Search for other papers by Priyanka Sankhyan in
Current site
Google Scholar
PubMed
Search for other papers by Priyanka Sankhyan in
Current site
Google Scholar
PubMed
R. Puri
R. Puri
Department of Chemistry, Himachal Pradesh University, Shimla, Himachal Pradesh, 171005, India
Search for other papers by R. Puri in
Current site
Google Scholar
PubMed
Search for other papers by R. Puri in
Current site
Google Scholar
PubMed
J. Christopher
J. Christopher
R&D, Indian Oil Corporation, Faridabad, Haryana, India
Search for other papers by J. Christopher in
Current site
Google Scholar
PubMed
Search for other papers by J. Christopher in
Current site
Google Scholar
PubMed
Abstract
Non-isothermal techniques, i.e. thermogravimetry (TG) and differential scanning calorimetry (DSC), have been applied to investigate the thermal behaviour of carbaryl (1-naphthyl-N-methylcarbamate = 1-Naph-N-Mecbm) and its complexes, M(1-Naph-N-Mecbm)4X2, where M = Cu, X = Cl, NO3 and CH3COO and M = Zn, X = Cl. Carbaryl and Zn(1-Naph-N-Mecbm)4Cl2 complex exhibit two-stage thermal decomposition while the copper(II) complexes exhibit three and four-stage decomposition in their TG curves. The nature of the metal ion has been found to play highly influential role on the nature of thermal decomposition products as well as energy of activation ‘E∗’. The presence of different anions does not seem to alter the thermal decomposition patterns. The complexes display weak to medium intensity exothermic and endothermic DSC curves, while the free ligand exhibits two endothermic peaks. The kinetic and thermodynamic parameters namely, the energy of activation ‘E∗’, the frequency factor ‘A’ and the entropy of activation ‘S∗’ etc. have been rationalized in relation to the bonding aspect of the carbaryl ligand. The nature and chemical composition of the residues of the decomposition steps have been studied by elemental analysis and FTIR data.
ProCite
RefWorks
Reference Manager
BibTeX
Zotero
EndNote
-
1. Ali, RM-A, Mohsen, R, Parisa, N. Solvent-free preparation of primary carbamates. Turk J Chem. 2006;30:269–276.
-
2. Dibenedetto, A, Aresta, M, Fragale, C, Narracci, M. Reaction of silylalkylmono- and silylalkyldi-amines with carbon dioxide: evidence of formation of inter- and intra-molecular ammonium carbamates and their conversion into organic carbamates of industrial interest under carbon dioxide catalysis. Green Chem. 2006;4:439–443. .
-
3. Gupte, SP, Shivarkar, AB, Chaudhari, RV. Carbamate synthesis by solid-base catalyzed reaction of disubstituted ureas and carbonates. J Chem Soc Chem Commun. 2001;24:2620–2621.
-
4. Motolcsy G , Nadasy M, Andriska V, editors. Pesticide chemistry. Budapest: Academiai Kiado; 1988. p. 90.
-
5. Thompson, A. Pest control on field vegetables threatened by the loss of organophosphorus (OP) and carbamate insecticides. Pestic Outlook. 2002;13:84–86. .
-
6. Martin, LL, Davis, L, Klein, JT, Nemoto, P, Olsen, GE, Bores, GM, Camacho, F, Petko, WW, Rush, DK, Selk, D, Smith, CP, Vargas, HM, Wilson, JT, Effland, RC, Fink, DM. Synthesis and preliminary structure-activity relationships of 1-[(3-fluoro-4-pyridinyl)amino]-3-methyl-1H-indol-5-yl methyl carbamate (P10358), a novel acetylcholinesterase inhibitor. Bioorg Med Chem Lett. 1997;7:157–162. .
-
7. Feldmen, D, Barbalata, A. Synthetic polymers, technology, properties, applications. London: Chapman and Hall; 1996 273.
-
8. Jensen AT . Process for the preparation of organic isocyanates. US Patent No. 5,449,817; 1995.
-
9. Daly, NJ, Ziolkowski, F. The thermal decompositions of carbamates. IV. The ethylN-methyl-carbamate system. Int J Chem Kinet. 1980;12:241–252. .
-
10. Kim, CK, Kim, DJ, Zhang, H, Hsieh, Y-H, Lee, B-S, Lee, HW, Kim, CK. Substituent effects on the gas-phase pyrolyses of 2-substituted ethyl N,N-dialkylcarbamates: a theoretical study. Bull Korean Chem Soc. 2007;28:1031–1034. .
-
11. Kalia SB , Priyanka S. Transition element complexes of carbaryl and their synthesis. Indian Patent, Application Number 2194/DEL02009.
-
12. Mohan J . Organic spectroscopy, principles and applications. 2nd ed. 2009.
-
13. Coats, AW, Redfern, JP. Kinetic parameters from thermogravimetric data. Nature. 1964;201:68–69. .
-
14. Katib, SMA. Thermal decomposition of nickel(II), palladium(II), and platinum(II) complexes of N-allyl-N′-pyrimidin-2ylthiourea. J Therm Anal Calorim. 2011;103:647–652. .
-
15. Avsar, G, Altinel, H, Yilmaz, MK, Guzel, B. Synthesis, characterization, and thermal decomposition of fluorinated salicylaldehyde Schiff base derivatives (Salen) and their complexes with copper(II). J Therm Anal Calorim. 2010;101:199–203. .
-
16. Zsakó, J, Várhelyi, C, Kékedy, E. Kinetics and mechanism of substitution reactions of complexes—III: thermal decomposition of complexes of the type [Co(DH)2Am2]X. J Inorg Nucl Chem. 1966;28:2637–2646. .
-
17. Khadikar, PV, Ali, V, Heda, B. Kinetics of thermal dehydration of some bis-(4-aminosalicylato)-diaquo complexes of transition metal ions. Thermochim Acta. 1984;82:253–361. .
-
18. Prabhumirashi, LS, Khoje, JK. Thermogravimetric and differential thermal analysis of bipyridyl,ortho-phenylenediamine and 1,10 phenanthroline complexes of some Cu(II) salts. Indian J Chem. 2004;43A:299–302.
-
19. Sawney, SS, Bansal, AK. Kinetics of the non-isothermal decomposition of some metal derivatives of 8-quinolinol and its dihalo derivatives from DTG/DTA curves. Thermochim Acta. 1983;66:347–350. .
-
20. Chourasia, P, Suryesh, KK, Mishra, AP. Synthesis and structural investigation of some mixed-ligand selenito complexes of cobalt(II). Proc Indian Acad Sci (Chem Sci). 1993;105:173–181.
-
21. Aslanidis, P, Gaki, V, Chrissafis, K, Lalia-Kantouri, M. Luminescence and thermal behavior by simultaneous TG/DTG–DTA coupled with MS of neutral copper(I) complexes with heterocyclic thiones. J Therm Anal Calorim. 2011;103:525–531. .
To see the editorial board, please visit the website of Springer Nature.
Manuscript Submission: HERE
For subscription options, please visit the website of Springer Nature.
| Journal of Thermal Analysis and Calorimetry | |
|---|---|
| Language | English |
| Size | A4 |
| Year of Foundation |
1969 |
| Volumes per Year |
1 |
| Issues per Year |
24 |
| Founder | Akadémiai Kiadó |
| Founder's Address |
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. |
| Publisher | Akadémiai Kiadó Springer Nature Switzerland AG |
| Publisher's Address |
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. CH-6330 Cham, Switzerland Gewerbestrasse 11. |
| Responsible Publisher |
Chief Executive Officer, Akadémiai Kiadó |
| ISSN | 1388-6150 (Print) |
| ISSN | 1588-2926 (Online) |
Monthly Content Usage
| Abstract Views | Full Text Views | PDF Downloads | |
|---|---|---|---|
| Apr 2024 | 3 | 0 | 0 |
| May 2024 | 12 | 0 | 0 |
| Jun 2024 | 23 | 0 | 0 |
| Jul 2024 | 30 | 0 | 0 |
| Aug 2024 | 39 | 0 | 0 |
| Sep 2024 | 10 | 0 | 0 |
| Oct 2024 | 0 | 0 | 0 |
Temperature dependence of the rate of reaction in thermal analysis
The Arrhenius equation in condensed phase kinetics
Author:
Copyright Akadémiai Kiadó AKJournals is the trademark of Akadémiai Kiadó's journal publishing business branch.
Powered by PubFactory