Geopolymers
Inorganic polymeric new materials
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I. Blanco
I. Blanco
Department of Industrial and Mechanical Engineering, University of Catania, V.le A. Doria, 6, 95125, Catania, Italy
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L. Abate
L. Abate
Department of Physical and Chemical Methodologies for Engineering, University of Catania, V.le A. Doria, 6, 95125, Catania, Italy
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F. A. Bottino
F. A. Bottino
Department of Industrial and Mechanical Engineering, University of Catania, V.le A. Doria, 6, 95125, Catania, Italy
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P. Bottino
P. Bottino
Department of Pharmaceutical Sciences, University of Catania, V.le A. Doria 6, 95125, Catania, Italy
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M. A. Chiacchio
M. A. Chiacchio
Department of Chemical Sciences, University of Catania, V.le A. Doria, 6, 95125, Catania, Italy
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Abstract
Seven variously substituted derivatives of polyhedral oligomeric silsesquioxanes (POSSs) with general formula R7R′1 (SiO1.5)8, where R- and R′- were a cyclopentyl and a substituted phenyl group, respectively, were prepared in this study, and their compositions were checked by elemental analysis, 1H NMR and 13C NMR spectroscopy. The compounds obtained were studied by TG and DTA techniques, in both flowing nitrogen and static air atmospheres, to draw useful information about their resistance to thermal degradation. Experiments, performed in the 35–700 °C temperature range, showed different behaviours between the two used atmospheres. The formation of volatile compounds only, with a near-complete mass loss, was observed under nitrogen; by contrast, in oxidative environment, a solid residue (≈50% in every case) was obtained because of the formation of SiO2 as indicated by the FTIR spectra performed. The results obtained for the various compounds investigated were discussed and compared with each other, and heat resistance classifications in the studied environments were made.
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| Journal of Thermal Analysis and Calorimetry | |
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Temperature dependence of the rate of reaction in thermal analysis
The Arrhenius equation in condensed phase kinetics
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