Geopolymers
Inorganic polymeric new materials
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Susan Moreno-Molek
Susan Moreno-Molek
Department of Biological, Geological, and Environmental Sciences, Cleveland State University, Cleveland, OH, 44115, USA
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Salaam Saleh
Salaam Saleh
Department of Biological, Geological, and Environmental Sciences, Cleveland State University, Cleveland, OH, 44115, USA
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Druthiman Reddy Mantheni
Druthiman Reddy Mantheni
Department of Chemistry, Cleveland State University, Cleveland, OH, 44115, USA
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Manik Pavan Kumar Maheswaram
Manik Pavan Kumar Maheswaram
Department of Chemistry, Cleveland State University, Cleveland, OH, 44115, USA
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Tobili Sam-Yellowe
Tobili Sam-Yellowe
Department of Biological, Geological, and Environmental Sciences, Cleveland State University, Cleveland, OH, 44115, USA
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Alan T. Riga
Alan T. Riga
Department of Chemistry, Cleveland State University, Cleveland, OH, 44115, USA
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Abstract
Cytokines and soluble cytokine receptors serve as important protein biomarkers for chronic and infectious disease diagnosis. The development of biosensors capable of detecting cytokines or their soluble receptors in patient bodily fluids is a growing area of research. In an ongoing series of studies to understand the thermal analytical behavior of cytokines and their soluble receptors, dielectric thermal analysis (DETA) and thermogravimetry (TG) were used in investigations to determine if differentiations based on dielectric properties (e.g., conductivity) of the proteins could be identified. Permittivity (∊′) and dielectric loss factor (∊″) measurements were performed over a frequency range of 0.1–300,000 Hz. Up to 20 min, water associated with the samples was conductive, interacting with the proteins and affecting the temperature-dependent relaxation spectra of proteins. A trend analysis revealed differences between surface charge at 0.1 Hz and bulk charge at 300,000 Hz. In addition, the greatest change detected among proteins was due to the conductivity (dielectric loss factor). Beyond a 20 min drying time, the observed conductivity was due to intrinsic properties of the proteins with limited dependence on frequency. A 100% water loss was obtained for samples within 20–30 min by TG. Sample drying by TG could serve as a preparatory step in drying protein samples for further DETA and DSC analysis.
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1. Clark, IA, Budd, AC, Alleva, LM, Cowden, WB. Human malaria disease: a consequence of inflammatory cytokine release. Malaria J. 2006;5:85 .
-
2. Prakash, D, Fesel, C, Jain, R, Cazanave, P, Mishra, GC, Pied, S. Clusters of cytokines determine malaria severity in Plasmodium falciparum-infected patients from endemic areas of Central India. J Infect Dis. 2006;194:198–207. .
-
3. Armah, HB, Wilson, NO, Sarfo, BY, Powell, MD, Bond, VC, Anderson, W, Adjei, AA, Gyasi, RK, Tettey, Y, Wiredu, EK, Tongren, JE, Udhayakumar, V, Stiles, JK. Cerebrospinal fluid and serum biomarkers of cerebral malaria mortality in Ghanaian children. Malaria J. 2007;6:147 .
-
4. Akanmori, BD, Kurtzhalas, JAL, Goka, BQ, Adabayeri, V, Ofori, MF, Nkrumah, FK, Behr, C, Hviid, L. Distinct patterns of cytokine regulation in discrete clinical forms of Plasmodium falciparum malaria. Eur Cytokine Netw. 2000;11:113–118.
-
5. Kindt, TJ, Goldsby, RA, Osborne, BA. Kuby immunology. 6 New York: W.H. Freeman and Company; 2007.
-
6. Baker, J, Ho, M, Pelecanos, A, et al. Global sequence variation in the histidine-rich proteins 2 and 3 of Plasmodium falciparum: implications for the performance of malaria rapid diagnostic tests. Malaria J. 2010;9:129 .
-
7. Gamboa, D, Ho, MF, Bendeezu, J, Torres, K, Chiodini, PL, Barnwell, JW, Incardonas, S, Perkins, M, Bell, D, McCarthy, J, Cheng, Q. A large proportion of P. falciparum isolates in the Amazon region of Peru lack pfhrp2 and pfhrp3: implications for malaria diagnostic tests. PLoS One. 2010;5:e8091 .
-
8. Matthews, ME, Atkinson, I, Presswala, L, Najjar, O, Gerhardstein, N, Wei, R, Rye, E, Riga, AT. Dielectric classification of D- and L-amino acids by thermal and analytical methods. J Therm Anal Calorim. 2008;93:281–287. .
-
9. Marzec, E, Warchol, W. Dielectric properties of a protein–water system in selected animal tissues. Bioelectrochemistry. 2005;65:89–94. .
-
10. Presswala, L, Matthews, ME, Atkinson, I, Najjar, O, Gerhardstein, N, Moran, J, Wei, R, Riga, AT. Discovery of bound and unbound waters in crystalline amino acids revealed by thermal analysis. J Therm Anal Calorim. 2008;93:295–300. .
-
11. Suherman, PM, Taylor, P, Smith, G. Low frequency dielectric study on hydrated ovalbumin. J Non Cryst Solids. 2002;305:317–321. .
-
12. Oliverberg, M, Tan, Y, Fershi, AR. Negative activation enthalpies in the kinetics of protein folding. Proc Natl Acad Sci USA. 1995;92:8926–8929. .
-
13. Saleh S , Moreno-Molek S, Manthen DR, Maheswaram MPK, Sam-Yellowe T, Riga AT. Thermal behavior and signature patterns of human cytokine and soluble cytokine receptors investigated using dielectric thermal analysis and thermogravimetry. J Therm Anal Calorim. .
-
14. Michnik, A, Michalik, K, Kluczewska, A, Drazga, Z. Comparativr DSC study of human and bovine serum albumin. J Therm Anal Calorim. 2006;84:113–117. .
-
15. Michnik, A, Drazga, Z. Thermal denaturation of mixture of human serum proteins DSC study. J Therm Anal Calorim. 2010;101:513–518. .
-
16. Mantheni DR , Maheswaram MPK, Sobhi HF, Riga A, Matthews ME, Alexander KS. Solid state studies of drugs and chemicals by dielectric and calorimetric analysis. J Therm Anal Calorim. .
-
17. Ruderman, G, De Xammar Oro, JR. On the dielectric spectra of proteins in conducting media. J Biol Phys. 1992;18:167–174. .
-
18. Cinelli, A, Onori, S, Stravato, A. Dielectric behavior of lysozyme and ferricytochrome-c in water/ethylene-glycol solution. Biophys J. 2004;86:1118–1123. .
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| Journal of Thermal Analysis and Calorimetry | |
|---|---|
| Language | English |
| Size | A4 |
| Year of Foundation |
1969 |
| Volumes per Year |
1 |
| Issues per Year |
24 |
| Founder | Akadémiai Kiadó |
| Founder's Address |
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. |
| Publisher | Akadémiai Kiadó Springer Nature Switzerland AG |
| Publisher's Address |
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. CH-6330 Cham, Switzerland Gewerbestrasse 11. |
| Responsible Publisher |
Chief Executive Officer, Akadémiai Kiadó |
| ISSN | 1388-6150 (Print) |
| ISSN | 1588-2926 (Online) |
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Temperature dependence of the rate of reaction in thermal analysis
The Arrhenius equation in condensed phase kinetics
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