View More View Less
  • 1 Institute for Sorption and Problems of Endoecology NAS of Ukraine, 13 Naumov Str., 03164, Kyiv, Ukraine
  • | 2 Institute of Chemistry and Chemical Technologies, L'viv National Polytechnic University, 12 Stepan Bandera Str., 79013, L'viv, Ukraine
  • | 3 Faculty of Chemistry, Maria Curie-Sklodowska University, Maria Curie-Sklodowska Sq. 3, 20–031, Lublin, Poland
Restricted access

Abstract

The deposition of molybdenum and vanadium oxides onto fumed silica, titania, and alumina as supports through dry milling has been carried out. The structure of prepared compositions has been investigated by means of XRD, DTA–TG, FTIR, and UV–Vis spectroscopy, nitrogen adsorption. The deposited crystal phases are sufficiently uniformly distributed on support surface. The supported oxides are subjected to dispersion in process of milling to the state of oligomeric or isolated species. Milled bulk and deposited MoO3 (first of all, on alumina) possesses improved catalytic performance in process of epoxidation of 1-octene. Vanadium pentoxide also has higher activity in this process.

  • 1. Ted Oyama S , editor. Mechanism in homogeneous and heterogeneous epoxidation catalysis. Amsterdam, Elsevier; 2008.

  • 2. da Palma Carreiro, E, Burke, AJ 2006 Catalytic epoxidation of olefins using MoO3 and TBHP: Mechanistic considerations and the effect of amine additives on the reaction. J Mol Catal A 249:123128 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 3. Moussa, N, Ghorbel, A, Grange, P 2005 Vanadia-silica catalysts prepared by sol–gel method: application for epoxidation reaction. J Sol-Gel Sci Technol 33:127132 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 4. Centi, G, Cavani, F, Trifiro, F 2001 Selective oxidation by heterogeneous catalysis Kluwer/Plenum New York.

  • 5. Oyama, ST 1988 Crystal face anisotropy of propilene oxidation on molybdenum trioxide. Bull Chem Soc Jpn 61:25852594 .

  • 6. Bielanski, A, Najbar, M 1997 V2O5–MoO3 catalysts for benzene oxidation. Appl Catal A 157:223261 .

  • 7. Dai, H, Bell, AT, Iglesia, E 2004 Effects of molybdena on the catalytic properties of vanadia domains supported on alumina for oxidative dehydrogenation of propane. J Catal 221:491499 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 8. Zazhigalov, VA, Haber, J, Stoch, J, Kharlamov, AI, Bogutskaya, LV, Bacherikova, IV, Kowal, A 1997 Influence of the mechanochemical treatment on the reactivity of V-containing oxide systems. Solid State Ionics 101–103:12571262 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 9. Zazhigalov, VA, Khalameida, SV, Litvin, NS, Bacherikova, IV, Stoch, J, Depero, L 2008 Effect of the mechanochemical treatment of a V2O5/MoO3 oxide mixture on its properties. Kinet Catal 49:692701 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 10. Bogutskaya, LV, Khalameida, SV, Zazhigalov, VA, Kharlamov, AI, Lyashenko, LV, Byl’, OG 1999 Effect of mechanochemical treatment on the structure and physicochemical properties of MoO3. Theor Exp Chem 35:242246 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 11. Skwarek E , Khalameida S, Janusz W, Sydorchuk V, Konovalova N, Zazhigalov V, Skubiszewska-Zięba J, Leboda R. Influence of mechanochemical activation on structure and some properties of mixed vanadium-molybdenum oxides. J Therm Anal Calorim. 2011. doi: .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 12. Milas, NA, Surgenor, DM 1946 Studies in organic peroxides. VIII. t-butyl hydroperoxide and di-t-butyl peroxide. J Am Chem Soc 68:205208 .

  • 13. Khalameida, S, Skubiszewska-Zięba, J, Zazhigalov, V, Leboda, R, Wieczorek-Cuirowa, K 2010 Chemical and phase transformation in the V2O5-(NH4)2Mo2O7 system during the mechanochemical treatment in various media. J Therm Anal Calorim 101:823832 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 14. Heinike, G 1980 Tribochemistry Academie Verlag Berlin.

  • 15. Repelin, Y, Husson, E, Abello, L, Lucazeau, G 1985 Structural study of gels of V2O5: normal coordinate analysis. Spectrochim Acta 41A:9931003.

    • Search Google Scholar
    • Export Citation
  • 16. Eda, K 1991 Longitudinal-transverse splitting effects in IR absorption spectra of MoO3. J Solid State Chem 95:6473 .

  • 17. Davydov, AA 2003 Molecular spectroscopy of oxide catalyst surfaces Wiley and Sons Chichester .

  • 18. Khaleel, AA, Klaubunde, KJ 2002 Characterization of aerogel prepared high-surface-area alumina: in situ FTIR study of dehydroxilation and pyridine adsorption. Chem Eur J 8:39913998 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 19. Herrera, JE, Kwak, JH, Hu, JZ, Wang, Y, Peden, CHF 2006 Synthes of nanodispersed oxides of vanadium, titanium, molybdenum and tunsten on mesoporous silica using atomic layer deposition. Top Catal 39:245255 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 20. Khodakov, A, Yang, J, Su, S, Iglesia, E, Bell, AT 1998 Structure and properties of vanadium oxide–zirconia catalysts for propane oxidative dehydrogenetion. J Catal 177:343351 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 21. Thielemann, JP, Ressler, T, Walter, A, Tzolova-Muller, G, Hess, C 2011 Structure of molybdenum oxide supported on silica studied by Raman, UV-Vis and X-ray absorption spectroscopy. Appl Catal A 399:2834 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 22. Hess, C 2007 Direct correlation of the dispersion and structure in vanadium oxide supported on silica SBA-15. J Catal 248:120123 .

  • 23. Bulanek, R, Capek, L, Setnička, M, Cičmanec, P 2011 DR UV-Vis study of the supported vanadium oxide catalysts. J Phys Chem C 115:1243012438 .

  • 24. Weber, RS 1995 Effect of local structure on the UV-visible absorption edges of molybdenum oxide clusters and supported molybdenum oxides. J Catal 151:470474 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 25. Mestl, G, Srinivasan, TKK, Knozinger, H 1995 Mechanically activated MoO3. 3. Characterization by vibration spectroscopy. Langmuir 11:37953804 .

  • 26. Rana, RK, Visvanathan, B 1999 Mo incorporation in MCM-41 type zeolite. Catal Lett 52:2529 .

  • 27. Lytvyn, NS, Khalameida, SV, Zazhigalov, VO 2010 Effect of the mechanochemical treatment on properties of MoO3. Rep Natl Acad Sci Ukraine 9:108113 (in Russian).

    • Search Google Scholar
    • Export Citation

Manuscript Submission: HERE

  • Impact Factor (2019): 2.731
  • Scimago Journal Rank (2019): 0.415
  • SJR Hirsch-Index (2019): 87
  • SJR Quartile Score (2019): Q3 Condensed Matter Physics
  • SJR Quartile Score (2019): Q3 Physical and Theoretical Chemistry
  • Impact Factor (2018): 2.471
  • Scimago Journal Rank (2018): 0.634
  • SJR Hirsch-Index (2018): 78
  • SJR Quartile Score (2018): Q2 Condensed Matter Physics
  • SJR Quartile Score (2018): Q2 Physical and Theoretical Chemistry

For subscription options, please visit the website of Springer.

Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
4
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

Monthly Content Usage

Abstract Views Full Text Views PDF Downloads
May 2021 1 0 0
Jun 2021 2 0 0
Jul 2021 1 0 0
Aug 2021 7 0 0
Sep 2021 0 0 0
Oct 2021 0 0 0
Nov 2021 0 0 0