Authors:
Marcela Stoia Faculty of Chemistry and Chemical Engineering, University “Politehnica” Timisoara, P. Victoriei No. 2, 300006, Timisoara, Romania

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Paul Barvinschi Faculty of Physics, West University of Timisoara, Bv. V. Parvan No. 4, 300223, Timisoara, Romania

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Lucian Barbu Tudoran Electron Microscopy Center, Faculty of Biology & Geology, Babes-Bolyai University, 5–7 Clinicilor Street, 400006, Cluj-Napoca, Romania

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Mirela Barbu Faculty of Chemistry and Chemical Engineering, University “Politehnica” Timisoara, P. Victoriei No. 2, 300006, Timisoara, Romania

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Mircea Stefanescu Faculty of Chemistry and Chemical Engineering, University “Politehnica” Timisoara, P. Victoriei No. 2, 300006, Timisoara, Romania

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Abstract

Nickel ferrite powders were synthesized by thermal decomposition of the precursors obtained in the redox reaction between the mixture of Ni(NO3)2·6H2O and Fe(NO3)3·9H2O with polyalcohol: 1,4-butanediol, polyvinyl alcohol and also with their mixture. During this reaction the primary C–OH groups were oxidized at –COOH, while secondary C–OH groups at C=O groups. The carboxylic groups formed coordinate to the present Ni(II) and Fe(III) cations leading to carboxylate type compounds, further used as precursors for NiFe2O4. These precursors were characterized by thermal analysis and FT-IR spectrometry. All precursors thermally decomposed up to 350 °C leading to nickel ferrite weakly crystallized. By annealing at higher temperatures, nanocrystalline nickel ferrite powders were obtained, as resulted from XRD. SEM images have evidenced the formation of nanoparticulate powders; these powders present magnetic properties characteristic to the oxidic system formed by magnetic nanoparticles.

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
1
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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