Geopolymers
Inorganic polymeric new materials
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Kseniya V. Zherikova
Kseniya V. Zherikova
Nikolaev Institute of Inorganic Chemistry SB RAS, Lavrentiev av., 3, 630090, Novosibirsk, Russia
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Ludmila N. Zelenina
Ludmila N. Zelenina
Nikolaev Institute of Inorganic Chemistry SB RAS, Lavrentiev av., 3, 630090, Novosibirsk, Russia
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Natalia B. Morozova
Natalia B. Morozova
Nikolaev Institute of Inorganic Chemistry SB RAS, Lavrentiev av., 3, 630090, Novosibirsk, Russia
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Tamara P. Chusova
Tamara P. Chusova
Nikolaev Institute of Inorganic Chemistry SB RAS, Lavrentiev av., 3, 630090, Novosibirsk, Russia
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Abstract
Complexes of ruthenium(III) with the following beta-diketone derivatives: 2,4-pentanedione (Ru(acac)3), 1,1,1,6,6,6-hexafluoro-2,4-pentanedione (Ru(hfac)3), and 2-methoxy-2,6-dimethyl-3,5-heptanedione (Ru(mdhd)3) were synthesized, purified, and identified by chemical analysis and melting points. By difference-scanning calorimetry (DSC) in vacuum the thermodynamic characteristics of melting processes were defined. Using the static method with quartz membrane zero-manometer, the temperature dependencies of saturated and unsaturated vapor pressure were obtained for Ru(hfac)3. The standard thermodynamic characteristics of vaporization processes enthalpy ΔHT* and entropy ΔS°T* were determined.
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| Journal of Thermal Analysis and Calorimetry | |
|---|---|
| Language | English |
| Size | A4 |
| Year of Foundation |
1969 |
| Volumes per Year |
1 |
| Issues per Year |
24 |
| Founder | Akadémiai Kiadó |
| Founder's Address |
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. |
| Publisher | Akadémiai Kiadó Springer Nature Switzerland AG |
| Publisher's Address |
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. CH-6330 Cham, Switzerland Gewerbestrasse 11. |
| Responsible Publisher |
Chief Executive Officer, Akadémiai Kiadó |
| ISSN | 1388-6150 (Print) |
| ISSN | 1588-2926 (Online) |
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Temperature dependence of the rate of reaction in thermal analysis
The Arrhenius equation in condensed phase kinetics
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