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S. Parthiban Department of Chemistry, Faculty of Engineering and Technology, Annamalai University, Annamalainagar 608 002, India

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H. Anandalakshmi Department of Chemistry, Faculty of Engineering and Technology, Annamalai University, Annamalainagar 608 002, India

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S. Senthilkumar Chemistry Wing, DDE, Annamalai University, Annamalainagar 608 002, India

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V. Karthikeyan Chemistry Wing, DDE, Annamalai University, Annamalainagar 608 002, India

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S. C. Mojumdar Department of Chemistry, University of Guelph, Guelph, ON, Canada
Department of Chemical Technologies and Environment, Faculty of Industrial Technologies, Trenčín University of A. Dubček, 020 32, Púchov, Slovakia

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Abstract

We have prepared pure and divalent vanadyl ion-doped magnesium rubidium sulfate hexahydrate crystals by using slow evaporation solution growth technique. It is interesting to observe that Vo(II) doping influences the physical properties of MRSH. Presence of Vo(II) ions in the doped specimen was confirmed by energy dispersive spectroscopy and electron paramagnetic resonance spectroscopy. FTIR studies reveal that the doping of vanadium ion has not altered the basic structure of MRSH. Scanning electron microscope studies of doped sample reveals that structure defect centers are formed in the crystals. Gradual decomposition patterns were observed for pure and doped specimens in thermogravimetry and differential thermogravimetry. The grown crystals were also characterized by powder X-ray diffraction. The second harmonic generation efficiency tested using Kurtz powder technique is not influenced by the added dopant.

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
1
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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