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V. Meenatchi Department of Chemistry, Annamalai University, Annamalainagar 608 002, Tamilnadu, India

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K. Muthu Department of Chemistry, Annamalai University, Annamalainagar 608 002, Tamilnadu, India

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M. Rajasekar Department of Chemistry, Annamalai University, Annamalainagar 608 002, Tamilnadu, India

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S. P. Meenakshisundaram Department of Chemistry, Annamalai University, Annamalainagar 608 002, Tamilnadu, India

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S. C. Mojumdar Department of Chemistry, University of Guelph, Guelph, ON, Canada
Department of Chemical Technologies and Environment, Faculty of Industrial Technologies, Trenčín University of A. Dubček, 020 32, Púchov, Slovakia

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Abstract

Single crystals of o-hydroxybenzoic acid (o-HBA, salicylic acid) have been grown by slow evaporation solution growth technique. It crystallizes in monoclinic system with two molecular units in the cell (centrosymmetric space group P21/c). The lattice parameters are a = 4.8967(6) Å, b = 11.2204(14) Å, c = 11.3027(15) Å and β = 92.096(12)°. The modes of vibrations of different functional groups present were identified by FT-IR studies. Differential scanning calorimetry (DSC) study reveals the purity of the sample and no decomposition is observed up to the melting point. The crystals are further characterized using UV–Vis and powder XRD. Effect of solvents on the growth and morphology has been investigated. The crystalline cohesion is achieved by intra and intermolecular hydrogen bonds.

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  • 16. Sawant, SY, Verenkar, VMS, Mojumdar, SC 2007 Preparation, thermal, XRD, chemical and FT-IR spectral analysis of NiMn2O4 nanoparticles and respective precursor. J Therm Anal Calorim 90:669672 .

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  • 17. Porob, RA, Khan, SZ, Mojumdar, SC, Verenkar, VMS 2006 Synthesis, TG, SDC and infrared spectral study of NiMn2(C4H4O4)3·6N2H4—a precursor for NiMn2O4 nanoparticles. J Therm Anal Calorim 86:605608 .

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  • 18. Mojumdar, SC, Varshney, KG, Agrawal, A 2006 Hybrid fibrous ion exchange materials: past, present and future. Res J Chem Environ 10:89103.

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  • 19. Doval, M, Palou, M, Mojumdar, SC 2006 Hydration behaviour of C2S and C2AS nanomaterials, synthesized by sol–gel method. J Therm Anal Calorim 86:595599 .

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  • 20. Mojumdar, SC, Moresoli, C, Simon, LC, Legge, RL 2011 Edible wheat gluten (WG) protein films: preparation, thermal, mechanical and spectral properties. J Therm Anal Calorim 104:929936 .

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  • 21. Varshney, G, Agrawal, A, Mojumdar, SC 2007 Pyridine based cerium(IV) phosphate hybrid fibrous ion exchanger: synthesis, characterization and thermal behaviour. J Therm Anal Calorim 90:731734 .

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  • 22. Mojumdar, SC, Melnik, M, Jona, E 2000 Thermal and spectral properties of Mg(II) and Cu(II) complexes with heterocyclic N-donor ligands. J Anal Appl Pyrolysis 53:149160 .

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  • 24. Mojumdar, SC, Sain, M, Prasad, RC, Sun, L, Venart, JES 2007 Selected thermoanalytical methods and their applications from medicine to construction. J Therm Anal Calorim 60:653662 .

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  • 25. Meenakshisundarm, SP, Parthiban, S, Madhurambal, G, Mojumdar, SC 2008 Effect of chelating agent (1,10-phenanthroline) on potassium hydrogen phthalate crystals. J Therm Anal Calorim 94:2125 .

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  • 26. Rejitha, KS, Mathew, S 2010 Investigations on the thermal behavior of hexaamminenickel(II) sulphate using TG-MS and TR-XRD. Glob J Anal Chem 1 1 100108.

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  • 27. Pajtášová, M, Ondrušová, D, Jóna, E, Mojumdar, SC, Ľalíková, S, Bazyláková, T, Gregor, M 2010 Spectral and thermal characteristics of copper(II) carboxylates with fatty acid chains and their benzothiazole adducts. J Therm Anal Calorim 100:769777 .

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  • 28. Madhurambal, G, Ramasamy, P, Anbusrinivasan, P, Vasudevan, G, Kavitha, S, Mojumdar, SC 2008 Growth and characterization studies of 2-bromo-4′-chloro-acetophenone (BCAP) crystals. J Therm Anal Calorim 94:5962 .

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  • 29. Gonsalves, LR, Mojumdar, SC, Verenkar, VMS 2011 Synthesis and characterisation of Co0.8Zn0.2Fe2O4 nanoparticles. J Therm Anal Calorim 104:869873 .

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  • 30. Raileanu, M, Todan, L, Crisan, M, Braileanu, A, Rusu, A, Bradu, C, Carpov, A, Zaharescu, M 2010 Sol–gel materials with pesticide delivery properties. J Environ Prot 1:302313 .

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  • 31. Varshney, KG, Agrawal, A, Mojumdar, SC 2005 Pectin based cerium(IV) and thorium(IV) phosphates as novel hybrid fibrous ion exchangers synthesis, characterization and thermal behaviour. J Therm Anal Calorim 81:183189 .

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  • 32. Mojumdar, SC, Šimon, P, Krutošíková, A 2009 [1]Benzofuro[3, 2-c]pyridine: synthesis and coordination reactions. J Therm Anal Calorim 96:103109 .

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  • 33. Moricová, K, Jóna, E, Plško, A, Mojumdar, SC 2010 Thermal stability of Li2O–SiO2–TiO2 gels evaluated by the induction period of crystallization. J Therm Anal Calorim 100:817820 .

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  • 34. Mojumdar, SC, Miklovic, J, Krutosikova, A, Valigura, D, Stewart, JM 2005 Furopyridines and furopyridine-Ni(II) complexes—Synthesis, thermal and spectral characterization. J Therm Anal Calorim 81:211215 .

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  • 35. Vasudevan, G, AnbuSrinivasan, P, Madhurambal, G, Mojumdar, SC 2009 Thermal analysis, effect of dopants, spectral characterisation and growth aspects of KAP crystals. J Therm Anal Calorim 96:99102 .

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  • 36. El Nasr, E, Fujii, A, Yahagi, T, Ebata, T, Mikami, N 2005 Laser spectroscopic investigation of salicylic acids hydrogen bonded with water in supersonic jets: microsolvation effects for excited state proton dislocation. J Phys Chem A 109:24982504 .

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  • 37. Smith, G, Wermuth, UD, White, JM 2002 Acta Crystallogr E 58:o1315o1317 .

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
1
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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