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S. Lendvayová Department of Chemical Technologies and Environment, Faculty of Industrial Technologies, Trenčín University of A. Dubček, SK-020 32, Púchov, Slovakia

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K. Moricová Department of Chemical Technologies and Environment, Faculty of Industrial Technologies, Trenčín University of A. Dubček, SK-020 32, Púchov, Slovakia

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E. Jóna Department of Chemical Technologies and Environment, Faculty of Industrial Technologies, Trenčín University of A. Dubček, SK-020 32, Púchov, Slovakia

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J. Kraxner Vitrum Laugaricio – Joint Glass Center of Institute of Inorganic Chemistry SAS, Alexander Dubcek University of Trencin and RONA Lednicke Rovne, Studentska 2, SK-911 50, Trencin, Slovak Republic

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M. Loduhová Department of Chemical Technologies and Environment, Faculty of Industrial Technologies, Trenčín University of A. Dubček, SK-020 32, Púchov, Slovakia

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V. Pavlík Institute of Inorganic Chemistry, Slovak Academy of Scienties, 842 36, Bratislava, Slovakia

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J. Pagáčová Department of Chemical Technologies and Environment, Faculty of Industrial Technologies, Trenčín University of A. Dubček, SK-020 32, Púchov, Slovakia

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S. C. Mojumdar Department of Chemical Technologies and Environment, Faculty of Industrial Technologies, Trenčín University of A. Dubček, SK-020 32, Púchov, Slovakia
Department of Chemistry, University of Guelph, Guelph, ON, Canada

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Abstract

A criterion based on the length of induction period of crystallization was used to evaluate the thermal stability of M2O·SiO2 (M = Li, Na) glasses against crystallization. It was founded out that the stability of studied glasses against crystallization is Li2O·SiO2 < Na2O·SiO2. The results coincide with the order determined by stability criteria based on temperatures and the values of activation energy. A criterion based on the length of induction period enables to discriminate among the thermal stabilities of the silicate glass systems.

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  • 2. Bih, L, Nadiri, A, Aride, J 2002 Thermal study of A2O–(MoO3)2–P2O5 (A = Li, Na) glasses. J Therm Anal Calorim 68:965972 .

  • 3. Sridarane, R, Raje, G, Shanmukaraj, D, Kalaiselvi, BJ, Santhi, M, Subramanian, S, Mohan, S, Palanivel, B, Murugan, R 2004 Investigations on temperature dependent structural evolution of NaPO3 glass. J Therm Anal Calorim 75:169178 .

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  • 4. Jóna, E, Nemčeková, K, Plško, A, Ondrušová, D, Šimon, P 2004 Thermal properties of oxide glasses. Part I. Verification of various criteria of thermal stability vs. crystallization. J Therm Anal Calorim 76:8590 .

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  • 5. Jóna, E, Šimon, P, Nemčeková, K, Pavlík, V, Rudinská, G, Rudinská, E 2006 Thermal properties of oxide glasses. Part II. Activation energy as a criterion of thermal stability of Li2O 2SiO2 nTiO2 glass systems against crystallization. J Therm Anal Calorim 84:673677 .

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  • 6. Cheng, K 1999 A criterion for evaluating the thermal stability of glasses. J Therm Anal Calorim 103:82728276.

  • 7. Hrubý, A 1972 Evaluation of glass-forming tendency by means of DTA. Czechoslov J Phys B22:11871193 .

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  • 9. Novaes de Oliveira, AP, Alarcon, OE, Manfredini, T, Pellacani, GC, Siligardi, C 2000 Crystallization kinetics of a 2, 3 Li2O. 1, 1 ZrO2. 6 SiO2 glass. Phys Chem Glass 41:100103.

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  • 10. Mojumdar, SC, Raki, L 2006 Preparation, thermal, spectral and microscopic studies of calcium silicate hydrate-poly(acrylic acid) nanocomposite materials. J Therm Anal Calorim 85:99105 .

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  • 11. Sawant, SY, Verenkar, VMS, Mojumdar, SC 2007 Preparation, thermal, XRD, chemical and FT-IR spectral analysis of NiMn2O4 nanoparticles and respective precursor. J Therm Anal Calorim 90:669672 .

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  • 12. Porob, RA, Khan, SZ, Mojumdar, SC, Verenkar, VMS 2006 Synthesis, TG, SDC and infrared spectral study of NiMn2(C4H4O4)3·6N2H4—a precursor for NiMn2O4 nanoparticles. J Therm Anal Calorim 86:605608 .

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  • 13. Mojumdar, SC, Varshney, KG, Agrawal, A 2006 Hybrid fibrous ion exchange materials: past, present and future. Res J Chem Environ 10:89103.

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  • 14. Doval, M, Palou, M, Mojumdar, SC 2006 Hydration behaviour of C2S and C2AS nanomaterials, synthesized by sol–gel method. J Therm Anal Calorim 86:595599 .

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  • 15. Mojumdar, SC, Moresoli, C, Simon, LC, Legge, RL 2011 Edible wheat gluten (WG) protein films: preparation, thermal, mechanical and spectral Properties. J Therm Anal Calorim 104:929936 .

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  • 16. Varshney, G, Agrawal, A, Mojumdar, SC 2007 Pyridine based cerium(IV) phosphate hybrid fibrous ion exchanger: synthesis, characterization and thermal behaviour. J Therm Anal Calorim 90:731734 .

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  • 17. Mojumdar, SC, Melnik, M, Jona, E 2000 Thermal and spectral properties of Mg(II) and Cu(II) complexes with heterocyclic N-donor ligands. J Anal Appl Pyrolysis 53:149160 .

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  • 18. Mošner, P, Vosejpková, K, Koudelka, L, Beneš, L 2012 Thermal studies of ZnO–B2O3–P2O5–TeO2 glasses. J Therm Anal Calorim 107:11291135 .

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  • 19. Mojumdar, SC, Sain, M, Prasad, RC, Sun, L, Venart, JES 2007 Selected thermoanalytical methods and their applications from medicine to construction. J Therm Anal Calorim 60:653662 .

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  • 20. Meenakshisundarm, SP, Parthiban, S, Madhurambal, G, Mojumdar, SC 2008 Effect of chelating agent (1,10-phenanthroline) on potassium hydrogen phthalate crystals. J Therm Anal Calorim 94:2125 .

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  • 21. Rejitha, KS, Mathew, S 2010 Investigations on the thermal behavior of hexaamminenickel(II) sulphate using TG-MS and TR-XRD. Glob J Anal Chem 1 1 100108.

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  • 22. Pajtášová, M, Ondrušová, D, Jóna, E, Mojumdar, SC, L'alíková, S, Bazyláková, T, Gregor, M 2010 Spectral and thermal characteristics of copper(II) carboxylates with fatty acid chains and their benzothiazole adducts. J Therm Anal Calorim 100:769777 .

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  • 23. Madhurambal, G, Ramasamy, P, Anbusrinivasan, P, Vasudevan, G, Kavitha, S, Mojumdar, SC 2008 Growth and characterization studies of 2-bromo-4′-chloro-acetophenone (BCAP) crystals. J Therm Anal Calorim 94:5962 .

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  • 24. Gonsalves, LR, Mojumdar, SC, Verenkar, VMS 2011 Synthesis and Characterisation of Co0.8Zn0.2Fe2O4 Nanoparticles. J Therm Anal Calorim 104:869873 .

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  • 25. Raileanu, M, Todan, L, Crisan, M, Braileanu, A, Rusu, A, Bradu, C, Carpov, A, Zaharescu, M 2010 Sol–gel materials with pesticide delivery properties. J Environ Protect 1:302313 .

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  • 26. Varshney, KG, Agrawal, A, Mojumdar, SC 2005 Pectin based cerium(IV) and thorium(IV) phosphates as novel hybrid fibrous ion exchangers synthesis, characterization and thermal behaviour. J Therm Anal Calorim 81:183189 .

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  • 27. Mojumdar, SC, Šimon, P, Krutošíková, A 2009 [1]Benzofuro[3,2-c]pyridine: synthesis and coordination reactions. J Therm Anal Calorim 96:103109 .

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  • 28. Moricová, K, Jóna, E, Plško, A, Mojumdar, SC 2010 Thermal stability of Li2O–SiO2–TiO2 gels evaluated by the induction period of crystallization. J Therm Anal Calorim 100:817820 .

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  • 29. Mojumdar, SC, Miklovic, J, Krutosikova, A, Valigura, D, Stewart, JM 2005 Furopyridines and furopyridine-Ni(II) complexes—synthesis, thermal and spectral characterization. J Therm Anal Calorim 81:211215 .

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  • 30. Vasudevan, G, AnbuSrinivasan, P, Madhurambal, G, Mojumdar, SC 2009 Thermal analysis, effect of dopants, spectral characterisation and growth aspects of KAP crystals. J Therm Anal Calorim 96:99102 .

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  • 31. Šimon, P, Nemčeková, K, Jóna, E, Plško, A, Ondrušová, D 2005 Thermal stability of glass evaluated by the induction period of crystallization. Thermochim Acta 428:1114 .

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  • 32. Šimon, P 2004 Isoconversional methods: fundamentals, meaning and application. J Therm Anal Calorim 76:123132 .

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
1
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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