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  • 1 ADM College for Women, Nagapattinam 611 001, India
  • | 2 EGS Pillay Engineering College, Nagapattinam 611 002, India
  • | 3 Department of Chemistry, University of Guelph, Guelph, ON, Canada
  • | 4 Department of Chemical Technologies and Environment, Faculty of Industrial Technologies, Trenčín University of A. Dubček, 020 32, Púchov, Slovakia
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Abstract

Single crystal of bisthiourea iron(II) sulphate was grown by slow evaporation technique at 303 K. The structural properties of the grown crystals were characterized by FTIR spectroscopy, UV spectroscopy and powder X-ray diffraction. FTIR and UV spectra provide information about the presence of functional groups. Thermal analysis confirms the crystal is thermally stable up to 167.02 °C.

  • 1. Sweta, M, Tanusree, K 2007 Growth and characterization of nonlinear optical crystal zinc tris (thiourea) sulphate in presence of l-arginine. Opt Mater 30:508512 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 2. Ezhilvizhi, R, Kalainathan, S, Bagavannarayana, G 2008 Structural and microhardness studies of purea and thiourea doped glycine phosphate single crystal. Cryst Res Technol 43:778782 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 3. Meera, K, Muralidharan, R, Tripathi, AK, Dhanasekaran, R 2004 Growth of thiourea-doped TGS crystals and their characterization. J Cryst Growth 260:414421 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 4. Selvakumar, S, Ravikumar, M, Rajarajan, K 2006 Growth and characterization of a novel organometallic nonlinear optical crystal: bis (thiourea) cadmium formate. J Cryst Growth Design 11:26072610 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 5. Jayalakshmi, D, Kumar, J 2006 Growth and characterization of bis thiourea zinc acetate. Cryst Res Technol 41:3740 .

  • 6. Sunil, V, Sing, MK, Wadhavan, VK 2000 Growth morphology of zinc tris (thiourea) sulphate crystals. Pramana 54:879888 .

  • 7. Ambujam, K, Thomas, PC, Aruna, S 2006 Growth and characterization of dichloro tetrakis thiourea nickel single crystals. Cryst Res Technol 41:10821088 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 8. Meenakshisundaram, S, Parthiban, S, Sarathi, N, Kalavathy, R, Bhagavannarayana, G 2006 Effect of organic dopants on ZTS single crystals. J Cryst Growth 293:376381 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 9. Ushasree, PM, Muralidharan, R, Jayavel, R, Ramasamy, P 2000 Metastable zone width, induction period and interfacial energy of zinc tris(thiourea)sulfate. J Cryst Growth 210:741745 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 10. Madhurambal, G, Mojumdar, SC, Hariharan, S, Ramasamy, P 2004 TG, DTC, FT-IR and Raman spectral analysis of Zna/Mgb ammonium sulfate mixed crystals. J Therm Anal Calorim 78:125133 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 11. Ushasree, PM, Jayavel, R, Ramasamy, P 1999 Growth and characterization of phosphate mixed ZTS single crystals. Mater Sci Eng B 65:153158 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 12. Gupte, SS, Desai, CF 1999 Vickers hardness anisotropy and slip system in zinc(tris)thioureasulphate crystals. Cryst Res Technol 34:13291332 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 13. Arunmozhi, G EM De Gomes Ganesamoorthy, S 2004 Growth kinetics of zinc (tris) thiourea sulphate (ZTS) crystals. Cryst Res Technol 39:408413 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 14. Meenakshisundarm, SP, Parthiban, S, Madhurambal, G, Mojumdar, SC 2008 Effect of chelating agent (1,10-phenanthroline) on potassium hydrogen phthalate crystals. J Therm Anal Calorim 94:2125 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 15. Skorsepa, JS, Gyoryova, K, Melnik, M 1995 Preparation, identification and thermal properties of (CH3CH2COO)2Zn·2L·H2O (-L = thiourea, nicotinamide, caffeine or theorbromine). J Therm Anal 44:169177 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 16. Mojumdar, SC, Raki, L 2006 Preparation, thermal, spectral and microscopic studies of calcium silicate hydrate-poly(acrylic acid) nanocomposite materials. J Therm Anal Calorim 85:99105 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 17. Sawant, SY, Verenkar, VMS, Mojumdar, SC 2007 Preparation, thermal, XRD, chemical and FT-IR spectral analysis of NiMn2O4 nanoparticles and respective precursor. J Therm Anal Calorim 90:669672 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 18. Porob, RA, Khan, SZ, Mojumdar, SC, Verenkar, VMS 2006 Synthesis, TG, SDC and infrared spectral study of NiMn2(C4H4O4)3·6N2H4: a precursor for NiMn2O4 nanoparticles. J Therm Anal Calorim 86:605608 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 19. Mojumdar, SC, Varshney, KG, Agrawal, A 2006 Hybrid fibrous ion exchange materials: past, present and future. Res J Chem Environ 10:89103.

    • Search Google Scholar
    • Export Citation
  • 20. Doval, M, Palou, M, Mojumdar, SC 2006 Hydration behaviour of C2S and C2AS nanomaterials, synthesized by sol–gel method. J Therm Anal Calorim 86:595599 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 21. Mojumdar, SC, Moresoli, C, Simon, LC, Legge, RL 2011 Edible wheat gluten (WG) protein films: preparation, thermal, mechanical and spectral properties. J Therm Anal Calorim 104:929936 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 22. Varshney, G, Agrawal, A, Mojumdar, SC 2007 Pyridine based cerium(IV) phosphate hybrid fibrous ion exchanger: synthesis, characterization and thermal behaviour. J Therm Anal Calorim 90:731734 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 23. Mojumdar, SC, Melnik, M, Jona, E 2000 Thermal and spectral properties of Mg(II) and Cu(II) complexes with heterocyclic N-donor ligands. J Anal Appl Pyrol 53:149160 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 24. Borah, B, Wood, JL 1976 Complex hydrogen bonded cations. The benzimidazole benzimidazolium cation. Canad J Chem 50:24702481 .

  • 25. Mojumdar, SC, Sain, M, Prasad, RC, Sun, L, Venart, JES 2007 Selected thermoanalytical methods and their applications from medicine to construction. J Therm Anal Calorim 60:653662 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 26. Meenakshisundarm, SP, Parthiban, S, Madhurambal, G, Mojumdar, SC 2008 Effect of chelating agent (1,10-phenanthroline) on potassium hydrogen phthalate crystals. J Therm Anal Calorim 94:2125 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 27. Rejitha, KS, Mathew, S 2010 Investigations on the thermal behavior of hexaamminenickel(II) sulphate using TG–MS and TR–XRD. Glob J Anal Chem 1 1 100108.

    • Search Google Scholar
    • Export Citation
  • 28. Pajtášová, M, Ondrušová, D, Jóna, E, Mojumdar, SC, Ľalíková, S, Bazyláková, T, Gregor, M 2010 Spectral and thermal characteristics of copper(II) carboxylates with fatty acid chains and their benzothiazole adducts. J Therm Anal Calorim 100:769777 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 29. Madhurambal, G, Ramasamy, P, Anbusrinivasan, P, Vasudevan, G, Kavitha, S, Mojumdar, SC 2008 Growth and characterization studies of 2-bromo-4′-chloro-acetophenone (BCAP) crystals. J Therm Anal Calorim 94:5962 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 30. Gonsalves, LR, Mojumdar, SC, Verenkar, VMS 2011 Synthesis and characterisation of Co0.8Zn0.2Fe2O4 nanoparticles. J Therm Anal Calorim 104:869873 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 31. Raileanu, M, Todan, L, Crisan, M, Braileanu, A, Rusu, A, Bradu, C, Carpov, A, Zaharescu, M 2010 Sol–gel materials with pesticide delivery properties. J Environ Protect 1:302313 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 32. Varshney, KG, Agrawal, A, Mojumdar, SC 2005 Pectin based cerium(IV) and thorium(IV) phosphates as novel hybrid fibrous ion exchangers synthesis, characterization and thermal behaviour. J Therm Anal Calorim 81:183189 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 33. Mojumdar, SC, Šimon, P, Krutošíková, A 2009 [1]Benzofuro[3,2-c]pyridine: synthesis and coordination reactions. J Therm Anal Calorim 96:103109 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 34. Moricová, K, Jóna, E, Plško, A, Mojumdar, SC 2010 Thermal stability of Li2O–SiO2–TiO2 gels evaluated by the induction period of crystallization. J Therm Anal Calorim 100:817820 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 35. Mojumdar, SC, Miklovic, J, Krutosikova, A, Valigura, D, Stewart, JM 2005 Furopyridines and furopyridine–Ni(II) complexes: synthesis, thermal and spectral characterization. J Therm Anal Calorim 81:211215 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 36. Vasudevan, G, AnbuSrinivasan, P, Madhurambal, G, Mojumdar, SC 2009 Thermal analysis, effect of dopants, spectral characterisation and growth aspects of KAP crystals. J Therm Anal Calorim 96:99102 .

    • Crossref
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    • Export Citation

Manuscript Submission: HERE

  • Impact Factor (2019): 2.731
  • Scimago Journal Rank (2019): 0.415
  • SJR Hirsch-Index (2019): 87
  • SJR Quartile Score (2019): Q3 Condensed Matter Physics
  • SJR Quartile Score (2019): Q3 Physical and Theoretical Chemistry
  • Impact Factor (2018): 2.471
  • Scimago Journal Rank (2018): 0.634
  • SJR Hirsch-Index (2018): 78
  • SJR Quartile Score (2018): Q2 Condensed Matter Physics
  • SJR Quartile Score (2018): Q2 Physical and Theoretical Chemistry

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
4
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)