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  • 1 Department of General and Coordination Chemistry, Maria Curie-Skłodowska University, M. C. Skłodowskiej SQ 2, 20–031, Lublin, Poland
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Abstract

Pyridine-2,4-dicarboxylic acid (lutidinic acid) is next one after pyridine-2,5-dicarboxylic acid of the six isomers which lanthanide complexes were studied thermally and spectrally. New complexes synthesized with light lanthanides (III) with general formula Ln2L3·nH2O, where n = 7.5; 8; 8.5; 9, were obtained. Sodium salt was obtained as hexahydrated compound. Hydrated complexes of La(III), Ce(III), Pr(III), Nd(III), Sm(III), Eu(III), and Gd(III) are thermally stable up to 303–313 K. Dehydration process run for all compounds in one stage, anhydrous compounds decompose through appropriate light lanthanides (III) oxalates, oxocarbonates, carbonates to metal oxides. Theoretical IR and Raman studies were carried out in order to identify precisely characteristic group bands vibrations present on IR and Raman spectra.

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  • Scimago Journal Rank (2019): 0.415
  • SJR Hirsch-Index (2019): 87
  • SJR Quartile Score (2019): Q3 Condensed Matter Physics
  • SJR Quartile Score (2019): Q3 Physical and Theoretical Chemistry
  • Impact Factor (2018): 2.471
  • Scimago Journal Rank (2018): 0.634
  • SJR Hirsch-Index (2018): 78
  • SJR Quartile Score (2018): Q2 Condensed Matter Physics
  • SJR Quartile Score (2018): Q2 Physical and Theoretical Chemistry

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
4
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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