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  • 1 School of Chemistry and Chemical Engineering, Guangxi University, Nanning 530004, China
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Abstract

The MnV2O6·4H2O with rod-like morphologies was synthesized by solid-state reaction at low heat using MnSO4·H2O and NH4VO3 as raw materials. XRD analysis showed that MnV2O6·4H2O was a compound with monoclinic structure. Magnetic characterization indicated that MnV2O6·4H2O and its calcined products behaved weak magnetic properties. The thermal process of MnV2O6·4H2O experienced three steps, which involves the dehydration of the two waters of crystallization at first, and then dehydration of other two waters of crystallization, and at last melting of MnV2O6. In the DSC curve, the three endothermic peaks were corresponding to the two steps thermal decomposition of MnV2O6·4H2O and melting of MnV2O6, respectively. Based on the Kissinger equation, the average values of the activation energies associated with the thermal decomposition of MnV2O6·4H2O were determined to be 55.27 and 98.30 kJ mol−1 for the first and second dehydration steps, respectively. Besides, the thermodynamic function of transition state complexes (ΔH, ΔG, and ΔS) of the decomposition reaction of MnV2O6·4H2O were determined.

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  • Impact Factor (2019): 2.731
  • Scimago Journal Rank (2019): 0.415
  • SJR Hirsch-Index (2019): 87
  • SJR Quartile Score (2019): Q3 Condensed Matter Physics
  • SJR Quartile Score (2019): Q3 Physical and Theoretical Chemistry
  • Impact Factor (2018): 2.471
  • Scimago Journal Rank (2018): 0.634
  • SJR Hirsch-Index (2018): 78
  • SJR Quartile Score (2018): Q2 Condensed Matter Physics
  • SJR Quartile Score (2018): Q2 Physical and Theoretical Chemistry

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
4
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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