Authors:
M. R. Bissengaliyeva Institute of Complex Development of Mineral Resources, Karaganda, Kazakhstan

Search for other papers by M. R. Bissengaliyeva in
Current site
Google Scholar
PubMed
Close
,
L. P. Ogorodova Geological Department of M.V. Lomonosov Moscow State University, Moscow, Russia

Search for other papers by L. P. Ogorodova in
Current site
Google Scholar
PubMed
Close
,
L. V. Mel'chakova Geological Department of M.V. Lomonosov Moscow State University, Moscow, Russia

Search for other papers by L. V. Mel'chakova in
Current site
Google Scholar
PubMed
Close
, and
M. F. Vigasina Geological Department of M.V. Lomonosov Moscow State University, Moscow, Russia

Search for other papers by M. F. Vigasina in
Current site
Google Scholar
PubMed
Close
Restricted access

Abstract

Thermal and thermochemical investigations of natural hydroxyl-bearing copper sulfate Cu3SO4(OH)4—antlerite have been carried out. The stages of its thermal decomposition have been studied employing the Fourier-transform IR spectroscopy. The enthalpy of formation of antlerite from the elements ΔfHmo (298.15 K) = (−1750 ± 10) kJ mol−1 has been determined by the method of oxide melt solution calorimetry. Using value of Smo (298.15 K), equal to (263.46 ± 0.47) J K−1mol−1, obtained earlier by the method of adiabatic calorimetry, the Gibbs energy value of ΔfGmo (298.15 K) = (−1467 ± 10) kJ mol−1 has been calculated.

  • 1. Lin'ko, IV, Kulikov, AB, Venskovskii, NU, Lobanov, NN, Rudnitskaya, OV 2001 Synthesis and thermal study of antlerite. Russ J Inorg Chem 46:14691471.

    • Search Google Scholar
    • Export Citation
  • 2. Koga, N, Mako, A, Kimizu, T, Tanaka, Y 2008 Thermal decomposition of synthetic antlerite prepared by microwave-assisted hydrothermal method. Thermochim Acta 467:1119 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 3. Ramamurthy, P, Secco, EA 1970 Studies on metal hydroxyl compounds. XII. Thermal analyses, decomposition kinetics, and infrared spectra of copper basic oxysalts. Can J Chem 48:35103519 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 4. Vilminot, S, Richard-Plouet, M, Andre, G, Swierczynski, D, Guillot, M, Bouree-Vigneron, F, Drillon, M 2003 Magnetic structure and properties of Cu3(OH)4SO4 made of triple chains of spins s = 1/2. J Solid State Chem 170:255264 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 5. Pollard, AM, Thomas, RG, Williams, PA 1992 The stabilities of antlerite and Cu3SO4(OH)4·2H2O: their formation and relationships to other copper (II) sulfate minerals. Miner Mag 56:359365 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 6. Silman JFB . The Stabilities of some oxidized copper minerals in aqueous solutions at 25 °C and 1 atmosphere totel pressure. Unpublished Ph.D. Thesis, Harvard University, 1958 (according to Pollard et al. [5]).

    • Search Google Scholar
    • Export Citation
  • 7. Kiseleva, IA, Ogorodova, LP, Topor, ND, Chigareva, OG 1979 Thermochemical investigation of system CaO–MgO–SiO2. Geokhimiya 12:18111825 (in Russian).

    • Search Google Scholar
    • Export Citation
  • 8. Robie RA , Hemingway BS. Thermodynamic properties of minerals and related substances at 298.15 K and 1 bar (105 pascals) pressure and at higher temperatures. US Geol Surv Bull. 1995; No. 2131.

    • Search Google Scholar
    • Export Citation
  • 9. Moenke, HH 1962 Mineralspektren Akad. Verlag Berlin.

  • 10. Peng, Venshi 1982 Infrared spectra of minerals Science Beijing(in Chinese).

  • 11. Secco, EA 1988 Specroscopic properties of SO4 (and OH) in different molecular and crystalline environments. I. Infrared spectra of Cu4(OH)6SO4, Cu4(OH)4OSO4, and Cu3(OH)4SO4. Can J Chem 66:329336 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 12. Kiseleva, IA, Ogorodova, LP, Melchakova, LV, Bissengalieva, MR, Becturganov, NS 1992 Thermodynamic properties of copper carbonates—malachite Cu2(OH)2CO3 and azurite Cu3(OH)2(CO3)2. Phys Chem Miner 19:322333 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 13. Kotel'nikov, AR, YuK, Kabalov, Zezyulya, TN, Melchakova, LV, Ogorodova, LP 2000 Experimental study of solid solution celestine–barite. Geokhimiya 12:12861293 (in Russian).

    • Search Google Scholar
    • Export Citation
  • 14. Kiseleva, IA, Ogorodova, LP 1983 About using of high-temperature calorimetry of solution for determination of enthalpy formation of hydroxyl-bearing minerals (by the example of talc and tremolite). Geokhimiya 12:1174511755 (in Russian).

    • Search Google Scholar
    • Export Citation
  • 15. Bissengalieva, MR, Bespyatov, MA, Gogol, DB, Taimasova, ST, Tazhibayeva, SD 2010 Low-temperatute heat capacity and thermodynamic functions of antlerite Cu3SO4(OH)4 over the range of 5–320 K. Teplofiz Aerodin 17:815820 (in Russian).

    • Search Google Scholar
    • Export Citation
  • Collapse
  • Expand

To see the editorial board, please visit the website of Springer Nature.

Manuscript Submission: HERE

For subscription options, please visit the website of Springer Nature.

Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
1
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

Monthly Content Usage

Abstract Views Full Text Views PDF Downloads
Jun 2024 11 0 0
Jul 2024 26 0 0
Aug 2024 18 0 0
Sep 2024 16 0 0
Oct 2024 102 0 0
Nov 2024 30 0 0
Dec 2024 6 0 0